华北板块北缘活动带元古宙构造岩片

新的研究证实 ,华北板块北缘残存一条元古宙构造岩片堆集带 ,包括古元古代、中元古代、新元古代等多期构造岩片。并相伴有 180 0Ma±、140 0Ma±、10 0 0Ma±、6 5 0Ma±的花岗岩类的侵入活动和构造变质成矿等热事件的年代记录 ,并在华北板块北部金镶边带中保存了相一致的信息 ,揭示了它们是陆缘多期拼贴造山的产物。这为超大陆旋回 ,特别是元古宙两次超大陆的聚合与裂解及其构造演化过程的研究提供了良好的野外实验园地 ,并为元古宙、特别是古元古代大陆的增生及Rodinia超大陆在北半球的存在或构造响应提出新的课题。     

湘中锑(金)矿床成矿物质来源——Ⅰ.微量元素及其实验地球化学证据

为了查明湘中盆地中-低温梯（金）矿床的成矿物质来源，文章应用高分辨率ICP-MS、ICP-AES等方法对岩石与矿石进行了系统测定，并结合作者以往分析数据和实验地球化学结果，对该区盆地及周边基底地层与矿床中的微量元素分布特征及其水/岩反应效应进行了综合分析和系统研究。结果表明：Sb、Au等成矿元素在元古界基底碎屑岩中具有高的背景含量，在近似成矿条件下的水/岩反应实验中，成矿元素的淋出率达20%～90%，元古界基底碎屑岩中的金（锑、钨）矿床的周围蚀变围岩中出现明显的金负异常区。而盆地内泥盆系统地层中的高锑含量仅局限于锑矿床（化）及其蚀变围岩中；湘中锑（金）矿床中的矿石与基底碎屑岩具有相似的稀土元素球粒陨石标准化配分曲线特征，以上微量元素地球化学特征充分证明该区锑（金）矿床锑、金等成矿物质主要来源于元古界底碎屑岩。     

成矿流体演化与成矿物理化学

成矿流体是富含挥发分 (CO2 、CH4等 )是具有较高含盐度的特殊地质流体。本文讨论了在流体演化过程中挥发分的来源 ,指出主要来自水岩作用、有机质分解及地幔去气和岩浆 ;碱金属及卤素同样具有多来源的性质 ,以海水、含盐系淋滤、建造水为主要来源 ,含盐系重熔可以形成富含碱金属的成矿流体。流体演化过程中氢氧同位素、硫同位素的分馏主要与温度、水岩比值或硫源丰度有关。一个重要的结论是 ,成矿流体的形成主要与地质作用有关 ,而流体来源是次要的。海底热水流体的地球化学特征以高δ3 4 S值、中稀土富集及正铕异常为特征。本文总结了热水流体成矿物理化学条件 ,指出水热流体物相点 :1) 10 80℃ ,7.5× 10 8Pa水溶液与硅酸岩熔浆分熔点 ;2 )水溶液的第二个临界点是气水溶液的超临界点 (374.15℃ ,2 .2 1× 10 7Pa) ;3)水溶液的沸点 (≥ 10 0℃ ,≥ 1× 10 5Pa) ;4)水溶液的冰点 (≤ 0℃ ,1× 10 5Pa) ;5 )H2 O CO2 体系的不混溶温度点 (2 6 6℃ ,2 .15×10 8Pa[1 3 ] 等是重要的成矿相变点。     

Gold Occurrence and Ore Genesis,Yata Micro—Disseminated Gold Deposit,Guizhou,Southwest China

The mode of occurrence of gold in the Yata micro-disseminated gold deposit is ap-proached through chemical phase studies coupled with ore-dressing monitoring and micro-beam analysis.The results showed that gold occurred for the most part as ultra-microscopic particles adsorbed on the surfaces or fracture planes of pyrite and other sulphides.The proportions of gold of different occurrences were estimated solutions containing nanometer-sized gold particles were prepared following the hydrolysis-reduction procedure and the adsorption of nanometer-sized gold on ordinary sulphides and rocks was experimentally determined.It is evident that sulphides are good adsorbents of gold and this is consistent with geological observations.     

玛曲县格尔柯金矿床控矿地质条件及其矿床成因探讨

格尔柯金矿 (即大水金矿 )是产于西秦岭南带西倾山—迭山逆冲褶断带南缘的特大型金矿。矿床控矿地质条件为构造单元界断裂带、深源浅成花岗闪长斑岩小侵入体、下三叠统马热松多组 (T1m)碳酸盐岩沉积建造 ,与金矿关系密切的矿化蚀变有硅化、赤铁矿化、褐铁矿化和方解石化 ;矿床成因类型为层控—热水溶滤构造蚀变岩型。     

甘肃小柳沟钨多金属矿地质特征及成矿模式

小柳沟钨多金属矿于 90年代初发现 ,目前已具大型、超大型规模。共有 4个矿床。成矿主要与长城系朱龙关群和隐伏花岗岩有关。该矿床成矿物质来源具双重性 ,成矿温度为中高温 ,成矿流体为中等盐度 ,同位素计算模式年龄确定其成矿于加里东期。矿床成因属于火山喷发沉积—岩浆热液改造矿床。     

华北陆块北缘西段中元古代与裂谷作用有关的铁、稀土、多金属矿床特征及成因

华北陆块北缘西段狼山—白云鄂博裂谷系中元古代形成的大型多金属矿床 ,是我国重要的铁、稀土、铜、铅、锌矿产地。矿床为产于沉积岩中热水沉积型多金属矿床。其形成受地层、构造控制 ,与裂谷作用有着密切的关系。裂谷系内外分支的地质环境及矿床矿种不同 ,导致矿床特征及成因具有一定差异。白云鄂博铁、稀土矿床为钾、钠、磷等含量较高的热水沉积型 ,霍各乞铜、铅、锌多金属矿床为与中基性火山岩有关的过渡热水沉积型 ,东升庙和甲生盘等铅、锌多金属矿床为热水沉积型。文中将对上述矿床分别进行论述。     

Sulfur Content and Isotopic Ratio of Cambro-Ordovician Carbonate Rocks from South Korea: A Possible Source for Mesozoic Magmatic-hydrothermal Ore Sulfur

Abstract: Carbonate rocks of Cambrian (18 samples) and lower-middle Ordovician (11 samples) ages from South Korea were analyzed for sulfur contents of structurally substituted sulfate (SSS) and sulfides and their δ³⁴S values. The δ³⁴S values of SSS ranging from +25.9 to +45.2 permil, are averaged as +33.6 and +33.5 permil for the Cambrian and Ordovician rocks, respectively, which indicate high δ³⁴S values of the Cambro-Ordovician seawater. The SSS contents in the carbonate rocks are low being 2.9 to 17.3 ppm S (averaged as 7.0 ppm S). Sulfide sulfur, on the contrary, is much abundant containing 3 to 1,880 ppm S and the δ³⁴S values range widely between –17.6 and +31.1 permil. Sulfide sulfur of the studied rocks excluding impure carbonates has an average content of 187 ppm S and δ³⁴S value of +12.8 permil (n=24). The estimated δ³⁴S (sulfate–sulfide) values, which range from 13.8 to 25.4 permil in general with a few exceptions from 36.5 up to 52.3 permil for some impure carbonates, may provide evidence for the persistent oceanic anoxia with its temporary recovery during the Cambro-Ordovician time.
The SSS and sulfide sulfurs have often higher δ³⁴S values than the Mesozoic-Cenozoic ore sulfur (Ishihara et al., 2000). Since carbonate rocks are very reactive with circulating hydrothermal ore solution, high δ³⁴S values of the Korean ore deposits might be caused to some extent by ³⁴S enrichment from the host carbonates, resulting in the low SSS contents observed.     

Geochronology of Gold Deposits and Its Implication for Metallogenesis in the Fengxian-Lixian Area, Qinling Orogenic Belt, China

Abstract: A series of super large‐scale and large‐scale Pb and Zn, and Au deposits are distributed in the Qinling orogenic belt, China. Gold deposits were generally ascribed to Carlin‐type originated from circular meteoric water. Visible and coarse‐grained gold (up to over 3mm in grain size) was recently identified in some gold deposits in the Fengxian‐Lixian area, Qinling. Au‐bearing quartz lodes related to magmatism were discovered in the Xiaogouli gold deposit. Two types of Au‐bearing quartz veins, i.e., NW‐trending quartz veins and NE‐trending quartz veins cutting strata are widely present in the Baguamiao gold deposit. Both are spatially associated with each other. The former is generally snake–like, S‐shape or zigzag, which was resulted from plastic deformation by ductile shearing, being generally cut by the latter. The latter is generally linear with widely developed bleaching alteration zones in its adjacent wall rocks, which symbolizes the superimposition of brittle deformation and filling and metasomatism of magmatic hydrothermal solution in ductile shear zones after uplifting of the shear zones near the surface. The NW‐trending quartz veins contain Au of lower than 3ppm. The NE‐trending quartz veins contain Au of more than 3 ppm, so that NE‐trending quartz veins and the adjoining altered rocks are important ores. The NW‐trending Au–bearing quartz vein was dated as 210.61.26 to 232.581.59 Ma by ⁴⁰Ar–³⁹Ar method, i.e., late Indosinian epoch (Triassic). The NE‐trending Au–bearing quartz vein was dated as 131.910.89 to 197.451.13 Ma by ⁴⁰Ar–³⁹Ar method, i.e., Yanshanian epoch (Jurassic). The ⁴⁰Ar–³⁹Ar age of the NW‐trending Au–bearing quartz veins represents the age of the ductile shear formation. The isotope data of the NE‐trending quartz veins indicate that gold mineralization was closely related to Indosinian and Yanshanian granite intrusives not only in time and space, but also in origin.     

Three Alkali-Rich Intrusive Rock Belts Newly Discovered in the Mt. Kunlun-Mt. Altun Region, Xinjiang, China

The newly discovered three alkali-rich intrusive rock belts in the Mt. Kunlun Mt.Altun region of southern Xinjiang are the Lapeiquan-Yitunbulak alkali-rich intrusive rock belt,the Gez-Taxkorgan alkali-rich intrusive rock belt and the Beilisai-Abulash alkali-rich intrusive rock belt. The former two belts were formed during the Yanshanian period, and the third one was formed during the Himalayan period, which is the youngest alkali-rich intrusive rock belt in China. The discovery of the alkali-rich intrusive rock belts is of great significance in shedding light on the history of tectono-magmatic activities in this region.