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951.
贵州主要城市地表松散沉积物中微量元素与土壤环境 总被引:2,自引:0,他引:2
通过贵阳等九个城市地表土壤和水系沉积物中的微量元素地球化学分析表明,城市环境不同程度地遭受有微量元素污染.在自然作用和人为作用过程中,微量元素造成城市的大气污染、水土污染、元素异常、环境灾变等环境问题,笔者认为,贵州城市地表土壤和沉积物中的生命有害元素污染,可能对长江和珠江流域造成不良影响,应尽快开展多目标生态环境地球化学调查,科学准确的划分地表环境的安全、隐患及污染区,并对已遭受微量元素污染的地区制定出有效的修复方案和治理措施. 相似文献
952.
953.
954.
Metamorphic zircon formation by solid-state recrystallization of protolith igneous zircon 总被引:162,自引:0,他引:162
Protolith zircon in high‐grade metagranitoids from Queensland, Australia, partially recrystallized during granulite‐grade metamorphism. We describe the zircon in detail using integrated cathodoluminescence, U–Pb isotope, trace element and electron backscatter diffraction pattern (EBSP) analyses. Primary igneous oscillatory zoning is partially modified or obliterated in areas within single crystals, but is well preserved in other areas. A variety of secondary internal structures are observed, with large areas of transgressive recrystallized zircon usually dominant. Associated with these areas are recrystallization margins, interpreted to be recrystallization fronts, that have conformable boundaries with transgressive recrystallized areas, but contrasting cathodoluminescence and trace element chemistry. Trace element analyses of primary and secondary structures provide compelling evidence for closed‐system solid‐state recrystallization. By this process, trace elements in the protolith zircon are purged during recrystallization and partitioned between the enriched recrystallization front and depleted recrystallized areas. However, recrystallization is not always efficient, often leaving a ‘memory’ of the protolith trace element and isotopic composition. This results in the measurement of ‘mixed’ U–Pb isotope ages. Nonetheless, the age of metamorphism has been determined. A correlation between apparent age and Th/U ratio is indicative of incomplete re‐setting by partial recrystallization. Recrystallization is shown to probably not significantly affect Lu–Hf ages. Recrystallization has been determined by textural and trace element analysis and EBSP data not to have proceeded by sub‐grain rotation or local dissolution/re‐precipitation, but probably by grain‐boundary migration and defect diffusion. The formation of metamorphic zircon by solid‐state recrystallization is probably common to high‐grade terranes worldwide. The recognition of this process of formation is essential for correct interpretation of zircon‐derived U–Pb ages and subsequent tectonic models. 相似文献
955.
Emelie Axelsson Jonas Pape Jasper Berndt Fernando Corfu Klaus Mezger Michael M. Raith 《Geostandards and Geoanalytical Research》2018,42(3):319-338
A new natural rutile reference material is presented, suitable for U‐Pb dating and Zr‐in‐rutile thermometry by microbeam methods. U‐Pb dating of rutile R632 using laser ablation ICP‐MS with both magnetic sector field and quadrupole instruments as well as isotope dilution‐thermal ionisation mass spectrometry yielded a concordia age of 496 ± 2 Ma. The high U content (> 300 μg g?1) enabled measurement of high‐precision U‐Pb ages despite its young age. The sample was found to have a Zr content of 4294 ± 196 μg g?1, which makes it an excellent complementary reference material for Zr‐in‐rutile thermometry. Individual rutile grains have homogeneous compositions of a number of other trace elements including V, Cr, Fe, Nb, Mo, Sn, Sb, Hf, Ta and W. This newly characterised material significantly expands the range of available rutile reference materials relevant for age and temperature determinations. 相似文献
956.
鲁西金矿成矿组分的聚集与演化 总被引:1,自引:2,他引:1
在地质研究的基础上, 以统计分析为主要手段, 通过对鲁西隆起区太古宙地层、中生代岩体以及不同时代金矿床化学组成的研究, 探索了成矿组分的可能来源、演化和聚集趋势, 提出了矿源层(岩) 中元素成矿活度的概念及定量计算方法.研究表明: (1) 在鲁西隆起区, 金的初始矿源是太古宙绿岩带, 金在其中具有双成分分布; (2) 从太古宙至中生代, 虽然成矿时代不同, 成矿作用各异, 但各类金矿床在成矿组分上对含矿建造具有明显的继承性; (3) 含矿建造中成矿组分超量点群与其背景点群的比例以及超量点群中成矿组分的平均质量分数在很大程度上决定了其后生热液矿床的成矿特征. 相似文献
957.
镇江石马杂岩体中岩石包体的成因研究 总被引:2,自引:0,他引:2
石马杂岩体,为南京—镇江地区出露面积较大的燕山期花岗质杂岩体,具大量暗色、细粒辉石闪长质-石英闪长质岩石包体,岩浆动力学理论的应用和详细的岩相学,岩石地球化学研究表明,该杂岩体中的岩石包体是不同成分岩浆大规模对流、不均一混合机制驱动下形成的,在成因类型上属淬冷包体. 相似文献
958.
Abstract. The Meng'entaolegai In-rich Ag-Pb-Zn deposit is located in the eastern part of Inner Mongolia. It is one of the In-richest deposits in China. Large amounts of quartz and sulfide minerals constitute a hydrothermal quartz-sulfide vein deposit within a Hercynian acidic granite massif, which occupies an area of about 400 km2 . Thirty-six orebodies, controlled strictly by the E-W trend faults, are found in the orefield of 6 km in length from east to west and 200 to 1,000 m in width from south to north. The ore minerals are mainly galena, sphalerite and pyrite, and subordinate chalcopyrite, arsenopyrite, cassiterite and stannite with many Ag-minerals. The gangue minerals are mainly quartz, calcite, sericite and chlorite. Economic components of the deposit are dominated by Pb andZn (reserves of Pb and Zn are 0.17 Mt and 0.37 Mt, and their grades are 1 % and 2.3 %, respectively), with Ag, Sn, In and Cd (1,800 t Ag, >2,000 t Sn, >500 t In and 1,800 t Cd) as by-products. Indium is highly enriched in ores and its contents are 9 to 295 ppm in ores and 85 to 2,660 ppm in sphalerite. Analytical results show that the ore-forming fluid of this deposit contains 0.8–3.5 ppm In and 4–36 ppm Sn, and the two elements show a very good positive correlation with a correlation coefficient of 0.8672, while the correlation between In and Zn in the ore-forming fluids, with a correlation coefficient of 0.5723, is not as good as that between In and Sn. This indicates that indium has an affinity with tin in the ore-forming fluids. The authors think that this is probably the main reason why those In-rich deposits spread over the world are simultaneously enriched in tin. 相似文献
959.
960.
Janet M. Hergt L. Paul Bédard Etienne Deloule Kathryn L. Linge Paul J. Sylvester Michael Wiedenbeck Jon D. Woodhead 《Geostandards and Geoanalytical Research》2005,29(1):5-52
The articles that comprise this critical review serve to draw attention to research papers published in specific fields of interest during 2003, provide critical comment on the relevance and importance of individual publications in these fields, and offer an overview of the comparative importance of advances in particular areas. In this way, these articles aim to assist experts in the field by keeping them informed of relevant recent publications, as well as providing an important resource for students or early career researchers who are embarking on studies in an area new to them. This year, five papers provide summaries of developments in bulk sample determinations employing (1) ICP-AES and ICP-MS (trace elements), (2) XRF and atomic absorption spectrometry and INAA, (3) isotope ratio measurements (TIMS, MC-ICP-MS, ICP-MS, ToF), as well as in situ measurements conducted using (4) secondary ion mass spectrometry and (5) laser ablation ICP-MS (trace element and isotope ratio determinations). 相似文献