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811.
812.
Analyses of trace elements of the Lower Palaeozoic carbonate rock strata in Beijing show that the contents of As, Hg, F increase from primary carbonate rocks to weathered carbonate rocks and from primary carbonate rocks to the soil coexisting with carbonate rocks, but the distribution regularity of S is not obvious. In the whole weathered stages, the sorption of As is mainly affected by Fe2O3. In soil Fe2O3 is also the main affecting factor of Hg enrichment. The main existing forms of Hg in primary carbonate rocks should simply be physical adsorption, coprecipitation and false isomorphous form between surface of carbonate rock and Hg. In soil the enrichment of F has little relationship with sul-fides and Fe2O3. In primary carbonate rocks, F is mainly absorbed by sulfides and clay minerals, etc. Weathered samples have closer genetic relationships with primary carbonate rocks. This also implies that weathered carbonate rocks have the close existing forms to that of primary carbonate rocks. In primary carbonate rocks FeS2 and FeS are the main forms of S, and sulfides have fixation effect on some heavy metals, whereas in weathered carbonate rocks and soil the fixation effect is weakened. 相似文献
813.
Abstract Detailed geologic examination of the Eocene accretionary complex (Hyuga Group) of the Shimanto terrane in southeastern Kyushu revealed that the oceanic plate was composed of Paleocene to Lower Eocene mudstone and siliceous mudstone, lower Middle Eocene red mudstone, and mid-Middle Eocene trench-fill turbidite with siltstone breccia, successively overlying the pre-Eocene oceanic plate. This oceanic plate sequence was overlain by Upper Eocene siltstone. Deposition of the lower Middle Eocene red mudstone was accompanied by basalt flows and it is interbedded with continental felsic tuff, which indicates that the basalt and red mudstone were deposited near the trench just before accretion. The Hyuga Group has very similar geological structure to that of the chert–clastic complexes found in the Jurassic accretionary complexes in Japan: that is, a decollement fault formed in the middle of an oceanic plate sequence, and an imbricate structure formed only in the upper part of the sequence. Thus, it appears that the Hyuga Group was formed by the same accretionary process as the Jurassic accretionary complexes. No accretion occurred before the Middle Eocene, and the rapid accretion of the Hyuga Group was commenced by the supply of coarse terrigenous sediments in the mid-Middle Eocene, when the direction of movement of the Pacific Plate changed. The pre-Eocene oceanic basement and lower Middle Eocene volcanic activity suggest that the oceanic plate partly preserved in the Hyuga Group was very similar to the northern part of the present West Philippine Sea Plate. 相似文献
814.
辽西北票上园镇四合屯地区义县组沉积层是热河生物群珍稀化石的重要产出层位之一, 其中蕴含丰富的地壳演化和古地理环境演化信息.分析了四合屯剖面上12m厚的含鸟化石沉积岩层的50件样品的微量元素组成和其中10件样品的主量元素组成.结合前人已发表数据, 得出以下认识: (1) 该套沉积岩具有与下伏火山岩类似的地球化学特征: Mg#值较高, 大离子亲石元素含量较高.稀土元素的分异程度较高, 在微量元素分布蛛网图中表现为明显的Nb负异常和Pb正异常等.因此我们认为义县组高镁火山岩构成了该沉积岩的主要源区之一; (2) 样品的Eu/Eu*=0.48~1.81, 其中大部分样品具负Eu异常.正的Eu异常(7件样品) 主要由于含有长石造成; (3) 通过微量元素Th-Co-Zr/10沉积构造环境判别图解对区域构造环境进行分析, 结果表明该沉积岩物源区具有大陆岛弧和活动大陆边缘物源特征. 相似文献
815.
816.
817.
贵州高原复杂地形下月平均日最高气温分布式模拟 总被引:4,自引:1,他引:3
在前人研究的基础上,对以前的模型进行改进,考虑了坡度、坡向和地形相互遮蔽作用对复杂地形下天文辐射的影响,基于数字高程模型(DEM)数据,建立以天文辐射为起始数据的复杂地形下月平均日最高气温的分布式模型,在模型中考虑了海拔高度、复杂地形下太阳总辐射、日照百分率对月平均日最高气温的影响.以贵州高原为例.应用100m×100m分辨率的DEM数据.1960-2000年贵州省及周边102个气象站常规气象要素观测资料以及NOAA-AVHRR观测资料,10个气象站的太阳辐射量资料,计算了贵州高原各月及年平均日最高气温精细空间分布.结果表明:(1)坡度、坡向、地形遮蔽对月平均日最高气温的影响较大,由于局地地形因子的影响,复杂地形下月平均日最高气温的空间分布具有明显的地域分布特征,局地地形对月平均日最高气温的影响是不容忽视的.(2)季节不同,局地地形因子对复杂地形下月平均日最高气温空间分布的影响不同,冬半年大于夏半年.月平均日最高气温随海拔高度的增加而降低.南坡随坡度的增大而升高:北坡随坡度的增大而降低.在坡向影响上,1-5月、10-12月偏北坡月平均日最高气温偏低,偏南坡月平均日最高气温偏高;7-8月因太阳高度较高,因此出现相反的情况.北坡高于南坡. 相似文献
818.
贵州锦丰(烂泥沟)金矿床含砷黄铁矿和脉石英及其包裹体的微量元素特征 总被引:5,自引:0,他引:5
贵州锦丰(烂泥沟)金矿是滇黔桂“金三角”目前已探明最大的卡林型金矿床。含砷黄铁矿是该矿床最主要的载金矿物,硅化及石英脉是最显著的热液蚀变类型。本文采用高精度电感耦合等离子质谱(ICP-MS)对含砷黄铁矿和脉石英及其包裹体的微量元素进行了测试,结果表明含砷黄铁矿富亲硫元素,并相对于围岩和上部地壳均强烈富集;亏损V,Sr 及高场强元素。同生黄铁矿也具有类似的特征。脉石英除亲石元素含量高以外,还表现为亲硫元素以及Mo,Bi 含量较高。但与上部地壳相比,绝大部分元素贫化。相应包裹体的微量元素含量普遍低于单矿物,但变化特征一致。结合矿物和包裹体的稀土元素分析,发现脉石英和含砷黄铁矿及其包裹体均表现为HFSE明显亏损,Th/La,Nb/La 比值小于1,说明成矿流体为富Cl 的流体。含砷黄铁矿及其包裹体中Co/Ni 比值远小于1,反映成矿温度较低,推测成矿流体主要来源于以沉积建造水为主的盆地流体。 相似文献
819.
Geochemical changes across the Ordovician-Silurian transition on the Yangtze Platform,South China 总被引:1,自引:0,他引:1
The trace element and rare earth element (REE) variations across the Ordovician-Silurian succession are presented from two
outcrop sections on the Yangtze Platform: the Nanbazi section, Guizhou Province, deposited in a shallow platform interior
setting, and the Wangjiawan section, Hubei Province, deposited in a deeper basinal environment. Geochemical analysis of closely
spaced samples through three intervals, the Wufeng, Guanyinqiao and Longmaxi, revealed vast palaeoceanographic changes. Some
geochemical proxies, including Th/U, Ni/Co, V/Cr, and V/(V+Ni) ratios, together with sedimentary facies and biotic data, indicate
that an anoxic condition on the most of the Yangtze Platform during the Wufeng and Longmaxi intervals, but an oxic condition
during the Guanyinqiao time. The shift of the anoxic to the oxic environment during the Guanyinqiao time coincided with a
global sea-level lowstand, in parallel with the global glaciation. The Longmaxian anoxic environment was a result of a global
sea-level rise, which may be synchronized with a mainly catastrophic event in the latest Ordovician. Although the two sections
generally show similar variation patterns of trace and REE concentrations and some element ratios, a minor difference occurs
between the Wangjiawan and Nanbazi sections, likely reflecting a difference in depositional setting during the accumulation.
Such an oceanic oxygen-level variation may add a useful constraint to the current arguments on the cause and consequence of
the latest Ordovician mass extinction.
Supported by National Basic Research Program of China (Grant No. 2005CB422101) 相似文献
820.
Nobuhiko Nakano Yasuhito Osanai Masaaki Owada Yasutaka Hayasaka Tran Ngoc Nam 《Island Arc》2009,18(1):126-143
The Kontum Massif in central Vietnam is composed of various metamorphic complexes including a high-temperature southern part (Kannak and Ngoc Linh complexes) and a low- to medium-temperature northern part (Kham Duc complex). The Kham Duc complex exhibits Barrovian-type medium-pressure metamorphism evidenced by kyanite- and/or staurolite-bearing metapelites. The garnet–gedrite–kyanite gneiss, which is the focus of the present study, preserves several mineral parageneses formed during a prograde and retrograde metamorphic history: staurolite + quartz in gedrite, garnet + gedrite + kyanite in the matrix, and spinel + cordierite symplectite between gedrite and sillimanite. The calculated semiquantitative petrogenetic grid reveals peak pressure conditions of 620–650°C at 1.1–1.2 GPa and peak temperature conditions of 730–750°C at 0.7–0.8 GPa. The monazite U–Th–Pb electron microprobe ages of the garnet–gedrite–kyanite gneiss and associated gneisses yield 246 ± 3 Ma for the Kham Duc complex, which is similar to the age of the high- to ultrahigh-temperature metamorphism in the adjacent Kannak and Ngoc Linh complexes of the southern Kontum Massif. The present results indicate that both the Barrovian-type and ultrahigh-temperature metamorphism occurred simultaneously in the Kontum Massif during an event strongly related to Permo–Triassic microcontinental collision tectonics in Asia. 相似文献