二(甲基环戊二烯)钐氯化物合成和晶体结构研究

作者以 Sm Cl3 与 (CH3 Cp) Na反应分离得到了三价稀土有机配合物 [(CH3 Cp) 2 Sm Cl·THF]2 的单晶 ,X-射线四圆衍射测定 ,该配合物属正交晶系 ,Pbna空间群 ,晶胞参数 a=9.6 6 2 (2 ) ,b=16 .4 76 (9) ,c=2 0 .582 (9) ;α=β=γ=90°,Z=4。并分析比较 [(CH3 Cp) 2 Sm Cl· THF]2 与其他三价稀土一氯化物的结构特点     

Analysis of Dynamic Characteristics of Submarine Free Spanning Pipelines by Complex Damping Method

Considering the effect of the internal flowing fluid and the external marine environmental condition, the differential equation for the vortex-induced vibration (V1V) of the free spanning pipeline is derived and is discretized by the Hermit interpolation function. The free vibration equation with the damping term is solved by the complex damping method for the natural frequency, and then the effect of fluid damping on the natural frequency of the free spanning pipeline is analyzed.The results show that fluid damping has a significant influence on the damped natural frequency of the free spanning pipeline in the lock-in state, while it has little influence when the pipeline is out of the lock-in state. In the meantime,the change of the free span length has the same effect on the damped natural frequency and the undamped natural frequency.     

胶南构造混杂岩带中糜棱岩的显微形变特征与古构造环境——来自榴辉岩围岩的构造信息

以胶南构造混杂岩带中榴辉岩的围岩——套程度不同的糜棱岩化岩石为研究对象,重点研究了其显微形变的结构特征及环境意义、石英组构特征及动力学信息,并讨论其形成的古构造环境和构造机制。     

苏北盐城凹陷复合含油气系统

苏北盐城凹陷含油气系统可划分为上、下2个复合含油气系统。上复合含油气系统，即Pz、K2p、K2t(生)-K2t、E1f1(储)一E1f1 E1f2(盖)，古生界、中生界浦口组和泰州组为烃源岩层，泰州组和阜宁组一段为储集层，阜宁组一段顶部至二段暗色泥岩为区域盖层，油气沿深大断裂运移，油气成藏关键时刻在古近纪晚期至新近纪早期，有利勘探区在深大断裂附近的中、新生界发育地区；下复合含油气系统，即Pz、K2p(生)-Pz、K2p(储)-K2p3 K2p4(盖)，油气通过断层或不整合运移，油气大量生成的关键时刻为古近纪早期，该系统中气藏分布在古生界被中生界覆盖地区。     

复合酶法制备鯷鱼活性寡肽的研究

探讨了用复合酶法制备鱼是鱼活性寡肽及其氨基酸组成和相对分子质量分布情况。应用正交试验法研究了酶量、酶解温度、酶解时间对鱼是鱼蛋白质水解度和酶解液苦味的影响。结果表明,最佳酶解作用条件是:酶量为100u/mL;酶解温度为50℃;酶解时间为4h。此时的酶解液苦味较低,水解度可达62.81%。应用氨基酸分析仪和凝胶排阻高效液相色谱分析了该寡肽的氨基酸组成和相对分子质量的分布范围,其十肽以下的小肽占67.77%,氨基酸组成平衡,必需氨基酸含量丰富。鱼是鱼活性寡肽有望成为保健食品、医药等领域的新型高品质原料。     

白云凹陷地球物理场及深部结构特征

珠江口盆地白云凹陷是南海最具代表性的第三系深水陆坡沉积区。以穿过白云凹陷中部的一条深反射地震剖面(14s)为研究基础，采用综合地球物理研究方法分析了该区地球物理场特征，根据重力异常平面等值线勾画了白云凹陷的形态，并提取该测线相对应的重磁剖面数据，利用重磁资料和地震剖面进行了综合反演。以深剖面地震资料建立了地质模型，利用所得的重力数据进行了研究深部结构的正演拟合，实测与计算值拟合较好，支持中生代俯冲洋壳存在的观点；同时结合地震资料对深部结构进行了分析，该区莫霍面由陆向海抬升，呈阶梯状变化，地壳厚度逐渐减薄，具有大陆边缘陆壳向洋壳过渡的特征。根据地质模型还进行了变密度综合反演拟合来分析基底岩性特征，该区基底主要为中酸性岩浆岩，部分为变质岩和基性火山岩，岩石密度由陆向洋逐渐减小，磁性体分布不均。     

灰色关联分析法在海洋环境质量评价中的应用

介绍了灰色关联分析法的原理,说明了其评价步骤。以青岛某海区海水水质评价为例阐明了该方法在海洋环境评价中的应用,并将评价结果与模糊综合评价结果加以比较,结果表明,两种评价方法的评价结果有着较明显的差别,分析了原因。本文还提出了海水污染防治措施,为海洋环境保护提供依据。     

渭河下游河道调整过程中的复杂响应现象

应用系统复杂响应的原理研究三门峡水库上游渭河河道调整过程,表明上游河道河床形态对基面上升所作出的响应是复杂的,弯曲系数的变化为先减小而后增大,宽深比的变化是先增大后减小,比降由先减小而后增大,最后均趋于稳定.     

THE INTRINSIC ACIDITY CONSTANTS AND SPECIFIC SURFACE AREA OF MARINE SOLID PARTICLESII. THE RELATIONSHIP BETWEEN THE INTRINSIC ACIDITY CONSTANT AND THE TERNARY SURFACE COMPLEX

This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.     

Mechanism of Secondary Pore Formation and Prediction of Favorable Reservoir of Paleogene in Jiyang Sag,Eastern China

Jiyang (济阳) sag is an oil rich basin,consisting of Huimin (惠民),Dongying (东营),Zhanhua (沾化),and Chezhen (车镇) depressions.The elastic rock of Paleogene has undergone early and middle diagenetic stages and now the main clastic reservoir is in the middle diagenetic stage.Primary and secondary pores are developed in Paleogene sandstone,the latter is generated from the dissolution of feldspar and calcite cement in rocks owing to the organic acid from the maturated source rock,but the materials dissolved are different in different depressions.The reservoir secondary pores of Dongying depression are generated from the dissolution of calcite cement,the ones of Zhanhua and Huimin depressions from the dissolution of feldspar,the secondary pores of Chezhen depression from the dissolution of feldspar in upper section,and the dissolution of calcite cement in the lower section of Paleogene,respectively.The secondary pores are developed in two depths and the depth goes down from west to east,from south to north in Jiyang sag.The major controlling factors for secondary pore development are maturity and location of source rock.Lastly,the favorable reservoirs are evaluated according to reservoir buried depth,sedimentation,and diagenesis.The reservoir with high quality is located in the northern and central parts in Dongying depression; there are some good reservoirs in Gndao (孤岛),Gudong (孤东),and Gunan (孤南) areas in Zhanhua depression,and the favorable reservoirs are located in the north steep slope and the south gentle slope of Chezhen depression and central uplift,south gentle slope of Huimin depression.