萤石典型产品国际贸易竞争格局演变

萤石作为一种重要的非金属战略性矿产资源,受到各国(地区)的高度重视。由于全球萤石资源储量有限、分布不均,萤石产品的供需矛盾不断增强,激化了萤石资源进出口之间的竞争。本文主要研究了萤石资源国际贸易,以无机氟化工产业链为切入点,选取酸级萤石、电子级氢氟酸、六氟磷酸锂为研究对象,运用复杂网络方法,构建了2000—2020年全球萤石产品进口竞争网络,分析其格局、演变特征,国家(地区)间竞争特点以及中国萤石产品的竞争状况。结果发现:全球萤石产品之间的竞争越来越激烈,各阶段的累积度分布都遵循幂律分布。竞争强度占比前20%的国家(地区)显示出更直观的集中化趋势。近20年来美国一直是酸级萤石进口竞争的矛盾中心。电子级氢氟酸和六氟磷酸锂的进口竞争网络的核心国家(地区)是不断演变的。建议中国等萤石资源储量丰富的国家(地区),合理规划萤石产业,优化萤石资源供需格局、促进萤石产业健康可持续发展。     

Geometric selection in two-dimensional crystal aggregates

The simultaneous growth of randomly oriented crystals nucleated at a surface rapidly produces a coarsely crystalline radial or columnar aggregate possessing a strong preferred shape and lattice orientation. Such textures are common in natural crystalline aggregates and are considered to arise because those crystals having their fastest growth direction normal to the initial substrate outdistance and eventually eliminate their less favorably oriented neighbors. In its simplest form the process of elimination is a purely geometric phenomenon. Detailed analysis and computer simulation of textural changes accompanying geometric selection in random two dimensional needlelike crystal aggregates demonstrate that selection initially proceeds exceedingly rapidly but slows drastically once roughly 90 percent of the crystals originally present are eliminated. Subsequent decrease in crystal density is inversely proportional to the square root of the distance from the initial substrate. Increases in crystal size larger than one or two orders of magnitude are thus unlikely to arise in natural crystalline aggregates in which only simple geometric selection is involved.     

基于城市竞争力的资源型城市空间布局研究

在总结已有的界定原则基础上,对中国资源型城市进行了界定和划分,确定了51个地级市及以上资源型城市,并从地理空间和城市竞争力的角度分析了这些城市的在空间位置上的分布规律。研究发现,我国资源型城市大多分布在中西部和偏北地区,而城市竞争力排名靠前的城市,无论在资源类型还是地理区位条件上都有着很明显的共性。可见地理区位因素隐藏在资源禀赋背后,对城市发展有着显著的影响。     

Moisture sorption behaviour of salt mixtures in porous stone

Moisture in stone material is the key factor for all stone deterioration processes and also in weathering of cultural heritage. With additional presence of salts in the material the situation gets even more critical. While the properties of pure salts with moisture are well known, knowledge about the interaction of salt mixtures with moisture is still poor. In different approaches the reactions of salt-contaminated stone material on changing moisture were tested in the laboratory. Experiments with different solutions in the Na-Mg-SO₄-NO₃-H₂O system revealed interesting new results on the moisture behaviour of salt-contaminated samples. Theoretical considerations and computer simulations are helpful to interpret the data obtained, but are not yet sufficient to explain the real processes acting on site at the monuments. More encouraging to this fact are complementary studies on visible efflorescences in the same salt system. It is shown how by experimental approaches the understanding on salt-induced stone deterioration is strongly complemented.     

基于文献计量方法的国际地理科学研究机构竞争力分析

本文利用2000-2015年WOS（Web of Science）的原始数据,以科研产出为视角,基于文献计量法,运用信息检索技术和TDA等引文分析工具,对遴选出的13个国际上具代表性的地理科学研究机构（中国科学院地理科学与资源研究所、北京大学城市与环境学院、北京师范大学地理与遥感学院、牛津大学地理与环境学院、剑桥大学地理系、伦敦大学联邦、加州大学系统、马里兰大学系统、杜伦大学地理系、伯明翰大学地理地球与环境科学学院、布里斯托大学地理科学学院、英属哥伦比亚大学地理系、国际应用系统分析研究所）的科研生产力、影响力、学科结构、国际合作力、重要成果等方面的发展现状进行了统计分析,结果显示,马里兰大学系统地理系总体学科影响力相对较强。中国科学院地理科学与资源研究所SCI&SSCI论文总数以绝对优势占居领先地位,但被引用情况却不尽人意,这也从一个侧面反映出学术影响力提升空间较大;与此同时,随着国际合作范围的扩展和国际合作能力的不断提升,该研究所的前沿开拓与创新发展力逐步走强。     

南黄海沉积物中活性铁氧化物对有机碳的保存作用

土壤和沉积物中活性铁对有机质的吸附对有机质具有长期稳定和保存作用,从而在地质时间尺度上缓冲大气CO₂浓度。本文利用连二亚硫酸钠还原性溶解提取活性铁氧化物（FeR）及与之结合的有机碳（Fe-OC）,定量研究了南黄海沉积物中FeR与OC之间的结合方式以及FeR对OC的保存作用,讨论了深度增加对二者相互作用的影响。结果表明,南黄海沉积物中Fe-OC占沉积物总有机碳的份数（f_Fe-OC）为（13.2±7.47）%,即活性铁对OC的年吸附量为0.72 Mt,占全球边缘海沉积物TOC年埋藏通量的0.44%。Fe-OC的平均OC:Fe为4.50±2.61,表明共沉淀作用对有机质的保存起重要作用,且其比值随海源有机质含量增加而增加。Fe-OC稳定碳同位素（δ13C_Fe-OC）结果表明,FeR优先保存活性有机质,但这种选择性随OC:Fe增大而减弱。随深度增加,f_Fe-OC和δ13C_Fe-OC均未表现出显著变化,这与该海域沉积物中有机质活性较低、铁还原作用较弱有关。     

环境因子对菲在黄河口沉积物上吸附的影响

为研究多环芳烃从河口到近海的环境归趋行为与生态风险,考察了沉积物质量浓度、溶解性有机质、温度、盐度4种典型环境因子对菲在黄河口沉积物上吸附的影响,比较了黄河口与近海两种沉积物对菲的吸附性能。研究结果表明,沉积物质量浓度越低,单位质量颗粒物的菲吸附量越高;共存的溶解性有机质对菲的吸附具有增促作用,且腐殖酸比黄腐酸的作用更显著;温度的升高不利于菲的吸附,而盐度的增加有利于菲的吸附。菲在沉积物上的吸附是分配作用与表面吸附两种行为的耦合,其中黄河口沉积物以表面吸附为主,而近海沉积物以分配作用为主。近海沉积物菲吸附量显著高于黄河口沉积物菲吸附量。基于此,菲从河口到近海的迁移过程中,更易于在沉积物表面发生吸附沉降,从而可能降低水相中的生态危害,但对近海底栖生物具有潜在的健康生态风险。     

Microbial activity promotes the enrichment of cobalt over nickel on hydrogenetic ferromanganese crusts

The different mineral phases of the ferromanganese (Fe–Mn) crusts stem from the interaction of biotic and abiotic components. It is therefore vital to study the activity of these components to decipher their contribution to the enrichment/depletion of metals in the crust. Thus, the present study examined sorption and release of Co and Ni by Fe-Mn crusts with associated microbial communities in the presence and absence of the metabolic poison sodium azide (15?mM). The study was conducted in the presence (G⁺) and absence (G^?) of added glucose (0.1%) at temperatures of 4?±?1°C and 28?±?2°C. Results showed that the microbial community had maximal sorption of Co of 66.12?µg?g^?1 at 4?±?1°C in the absence of added glucose and 479.75?µg?g^?1 at 28?±?2°C in the presence of added glucose. Maximum sorption of Ni in the absence of added glucose was 1.89?µg?g^?1 at 4?±?1°C and release of Ni was 51.28?µg?g^?1 in the presence of added glucose. Under abiotic conditions with 15?mM sodium azide as a metabolic inhibitor, significant amounts of Co and Ni were released in the G⁺ medium. Total cell counts on the Fe-Mn crust in the presence of added glucose increased by an order of magnitude from 10⁶ to 10⁷ cells g^?1 and in the absence of added glucose remained within the order of 10⁶ cells?g^?1 irrespective of temperature of incubation. Microscopic observation of the samples from biotic incubations showed numerous bacterial cells, exopolysaccharides, and structures resembling secondary minerals formed by bacteria. The results indicate that bacteria promote the enrichment of Co and Ni on the hydrogenetic Fe-Mn crusts by sorption processes and release of Ni by reductive dissolution of the oxides. The higher enrichment of Co than Ni is attributed to the way in which microbes interact with the metals.     

煤岩吸附二氧化碳气体的CT实验研究

利用工业CT技术及应变测量研究不同气压下煤岩的二氧化碳气体吸附性质。研究发现：煤样的应变随吸附时间和气体压力的增加而增加,且在不同方向是不同的,吸附气体导致煤样孔隙率增加;煤样CT图像的灰度均值和灰度标准差随吸附时间和气体压力的增长都表现出增加的趋势。结果表明：吸附二氧化碳导致煤样总体发生膨胀变形,这为吸附提供更多的孔隙表面积而使吸附气体量增加,含气煤样的密度也因此而增大;气体吸附导致的煤样密度均值增加的效应大于体积膨胀导致的煤样密度均值减小的效应;吸附使煤样内部物质分布不均匀程度增加。     

中国民航客运(国内)空间格局与竞争态势分析

利用统计分析和可视化方法,综合考虑行政、经济、人口和旅游吸引指标,采取抽样方法选择了60个具有代表性的国内大中城市,以近期发布的中国民航班期数据为基础,研究了构成中国民航运输网络的9家民航公司的通航城市和航线网络特征,并分析了各公司相互问的竞争关系。结果表明,三大航空集团和海航的航线呈多中心网状分布,而其他5家航空公司航线呈明显的单中心/双中心放射状分布;在运营中,三大航空集团和海航具有明显的垄断优势。而它们之间也存在明显的竞争关系。其他航空公司在构成中国民航运输网络骨架的大中城市航线运营中处于明显的竞争劣势。研究成果对航空公司航线、航班调整、代码共享和民航政策制订具有参考作用。