城市旅游竞争潜力时空格局演化及其结构合理性评价——以长江三角洲地区为例

选取资源产品竞争力、市场服务竞争力、旅游保障竞争力三大指标体系,采用熵值法赋予权重,对长三角城市旅游竞争潜力进行横向上的测度,引入SSM模型,纵向测算1998～2008年城市旅游竞争潜力指标要素的结构偏离分量和竞争力偏离分量,在此基础上,评价指标要素的结构效果指数和竞争力效果指数。结果表明:长三角城市旅游竞争潜力时空格局上存在显著差异,表现为以上海、南京、杭州、苏州为中心的城市旅游竞争潜力较高,始终处于区域的高值状态,形成四强鼎立的空间格局,城市间旅游竞争潜力差异呈现扩大化,指标要素的结构上存在不合理,与之相对应的旅游竞争潜力并不完全匹配。通过横向纵向两方面清晰的对比反映不同城市旅游竞争潜力指标的弱项和缺陷,客观准确地表现不同城市旅游竞争潜力大小,为长三角地区不同城市提升旅游竞争潜力提供定量依据与理论参考。     

Sorption of phenanthrene on the complexes of kaolinite and different organic component

Sorption of hydrophobic organic chemicals by various components influences their behavior and fate in environment. In the natural environment, mineral components, organic matter and microorganism didn＇t exist alone. They combined or reacted one another and formed the mineral-humic, mineral-microorganic and mineral- humic- microorganic complexes. A clear understanding of the sorption of organic chemicals by the complexes of mineral and humic acid and/or microorganism will help to determine their sorptive mechanisms in environment. In this paper, the sorption patterns of phenanthrene on the complexes of kaolinite and different organic component （humic acid and microorganism） have been carried on. The results show that the combination of HA and kaolinite not only changed the structure of HA, but also modified the surface chemistry of clay mineral. Interaction between HA and kaolinite is presumably ascribable to coulombic interactions and ligand exchange between the -COOH groups of HA and OH groups at the kaolinite surface. During the sorption on mineral surface, aliphatic fractions of HA were preferentially sored by kaolinite while aromatic fractions were left in the solution. More linear isotherms and higher Koc values were observed for kaolinite-HA complex in comparison of the pure HA. The sorption capacity of kaolinite-HA complex increased with increasing ionic strength and pH, and showed more nonlinear character. Kaolinite, microorganism and kaolinite-microorganism complex can all sorb phenanthrene, but the sorption capacity significantly differed. Bacterial cell sorbed more phenanthrene than kaolinite. The biofllm coating of kaolinite affected its sorption to phenanthrene. Kaolinite with biolfilm coating sorbed more phenanthrene than that without biofilm coating. The sorption capacity of kaolinite-microorganism complex decreased with increasing ionic strength and decreasing pH, but showed more nonlinear character. Both HA and microorganism can alter the nature of kaolinite sorbing phenanthrene respectively.     

Sorption of Zr~(4+) and Hf~(4+) onto Hydrous Ferric Oxide and Their Fractionation Behaviors:An experimental Study

1 Introduction Coherent element pairs (Y3+-Ho3+, Zr4+-Hf4+, Nb5+-Ta5+ and Sr2+-Eu2+) have the same valences and very similar ionic radii. They are seldom fractionated during silicate mineral/melt interaction systems because the partitioning of these element pairs between melts and minerals is tightly controlled by charge valence and crystal structure (lattice site size) or ionic radius. The concentration ratios of these pairs in igneous rocks are close to the chondritic values (Y/Ho=28, Zr…     

流动注射在线置换吸附预富集与火焰原子吸收联用分析地质样品中痕量银

介绍了应用编结反应器为吸附介质,流动注射在线置换吸附预富集消除Fe、Ca、Mn、Pb等共存金属离子的影响,与火焰原子吸收联用分析痕量银的方法,Ag(Ⅰ)吸收信号峰高比直喷时增感26倍,检出限为0.60μg/g。方法用于国家一级地质标准物质中Ag的测定,结果与标准值相符,5次测定的RSD≤4.8%。     

INFLUENTIAL FACTORS COMBINATION AND COMPETITIVE ADVANTAGES IN STAGES OF URBAN COMPETITIVENESS ——Case Study of Suzhou in China

The urban competitive advantages rely on the combination and interaction of influential factors. As a dynamic progressive process, the city at different time has different competition influential factors combination. Because of this, the urban competitive advantages take on time-series characteristics. Stages of urban competition can be summed up into three ones, the basic factor-driven, the investment-driven and the innovation-driven. The finding of the study on the stages of urban competitive advantages in Suzhou is that in the current stage of Suzhou its competitive advantage is the investment-driven. The investment, especially FDI, plays remarkable functions for Suzhou competition with other cities.     

Unbiased identification of nonlinear sorption characteristics by soil column breakthrough experiments

Accurate identification of interactions of reactive solutes with porous media constituents is necessary for reliable risk assessment studies and the development of efficient sanitation strategies. Standard parameter estimation procedures bear a number of unsolved problems with respect to uniqueness and identifiability. This paper presents a new approach for the identification of nonlinear interaction parameters of column outflow experiments. The procedure requires no a priori assumptions on the shape of the underlying interaction process functions. Employing experimental data sets on cadmium and anthracene breakthrough as case studies, possible applications of the new approach will be shown, and its features will be discussed. Error analysis based on singular value decomposition of the sensitivity matrix quantifies the identification error. Identification procedures without a priori shape information are superior to fixed parametrizations in diagnostic investigations, especially in cases without reliable a priori knowledge on the sorptive interactions.     

Sorption of Eu<Superscript>3+</Superscript>onto nano-size silica-water interfaces

The sorption of Eu species onto nano-size silica-water interfaces is investigated at pH range of 1―8.5 and the initial Eu concentrations (C_Eu) of 2×10⁻⁵, 2×10⁻⁴ and 2×10⁻³ M using fluorescence spectroscopy. The sorption rate of Eu is initially low, but significantly increases at pH > 4. For the initial C_Eu of 2×10⁻⁵, 2×10⁻⁴ and 2×10⁻³ M, the dissolved Eu species are completely sorbed onto silica-water interfaces at pH = 4.75, −5.8 and 6.6, respectively, with the respective sorption densities of −1.58×10⁻⁸, 1.58×10⁻⁷ and 1.58×10⁻⁶ mol/m². The sorbed Eu species at pH < 6 is aquo Eu³⁺, which is sorbed onto silica-water interfaces as an outer-sphere complex at pH < 5, but may be sorbed as an inner-sphere bidentate complex at 5 < pH < 6, due to the decrease of the N_H2O to −6 at pH = 6. At pH = 6 – 8, Eu(OH)²⁺, Eu(CO₃)⁺and Eu(CO₃)₂ ⁻ form in the solutions, and Eu(CO₃)⁺is dominant at pH = −7.5. These ions may be sorbed onto silica-water interfaces as inner-sphere bidentate complexes or multi-nuclear pre-cipitates.     

ON ICE FORMING NUCLEI

Cloud condensation nuclei(CCN)constitute a reservoir of latent ice-forming nuclei(IFN)active by condensation-followed-by-freezing and by sorption.Two classes of aerosol particles active as IFN by sorption werefound.The first produces IFN concentrations which are dependent on temperature only.The IFN concen-tration consecutively increases with lowering of temperature and does not respond to the increasing partialwater vapor pressure.The second produces IFN concentrations which are dependent on partial water vaporpressure only,The IFN concentration consecutively decreases with decreasing of the partial water vapor pres-sure that takes place with the lowering temperature.Sulfates(mostly ammonium sulfate)constitute an integral part of IFN active by condensation-followed-by-freezing and by sorption.Backward isentropic air parcel trajectories linked polluted air rich in sulfates andclean air with high and low concentrations of IFN active by condensation-followed-by-freezing at-19.7℃ andS_w=0.1%.The experiments were performed in a dynamic filter processing chamber with aerosol particles collectedon membrane filters.     

Pb (II) Sorption with Calcite: A Radiotracer Study

A ²¹⁰Pb radiotracer was used to monitor Pb solid-aqueousphase partitioning in sorption experiments at ambient temperature, pH = 8.2, and atmospheric PCO₂ in 0.15 M NaNO₃ solutions. A 24 h isotherm is linear up to Pb concentrations of 4 × 10^-6 M, above which an increase in slope suggests precipitation. The effect of Pb concentration, calcite loading, and ionic strength on Pb sorption with time was monitored. Sorption kinetics are rapid, followed by a slower sorption step.At a constant calcite loading500 mg L^-1,fractional sorptiondecreases with increasing initialPb concentration. The reverse isobserved for surface coverage, with0.6, 5.6 and 40.2% of availableCa²⁺sites occupied at10^-8,10^-7 and10^-6 MPb after 96 h. At a constant Pb concentration of10^-6 M,fractional sorption increases with increasing particleloading, however surface coverage decrease with72.5 and 22.1%Ca²⁺sites occupied at 100 and200 mg L^-1calcite after 96 h.The adsorption coefficient (K_d) is approximately 10³,increases with initial Pb concentration, but remains unaffected by variable calcite loading. Absence of an ionic strength effect on Pb sorption is interpreted as the dominance of inner-sphere complexation. For desorption experiments conducted over a range of initial sorption times, an average desorption index > 0.8 but < 1 indicates that sorption is largely reversible, but is accompanied by slight incorporation. Solid-solution formation increases with time, as observed by slower initial desorption rates for samples with longer sorption times. These findings indicate that Pb may be effectively sequestered by calcite; however re-release via desorption is likely as Pb does not become significantly incorporated into the mineral structure.