煤中干酪根的成熟度与菲的吸附行为间的关系

将云南先锋褐煤采用热模拟的实验方法制得一组成熟度不同的煤,并将煤中的干酪根用于对菲的吸附研究.结果表明:随着干酪根成熟度的增加,有机质结构变得紧密、刚硬,还原性和芳香性增强.不同成熟度干酪根的内部结构和性质与菲的吸附行为间存在一定的关系.随着干酪根内部结构的刚性和芳香性的增强,吸附等温线的非线性逐渐增强.对于成熟度相对较低的干酪根,随着成熟度的增加,吸附容量逐渐增大,而对于成熟度相对较高的干酪根,随着成熟度的增加,吸附容量却减小.     

Transverse Dispersion of a Kinetically Sorbing Solute

A recursion formulation for the transverse spreading of a solute is developed, and under conditions of steady flow in a stratified aquifer, the transport of a linearly sorbing solute undergoing nonequilibrium sorption is studied. The effect of spatial variability in the velocity field and the sorption kinetics are modeled to see the combined effect of the two processes on the spreading of the solute injected at a point in the aquifer. The main result of this work is a transport model based on a discrete formulation that includes local dispersion and leads to nonasymptotic behavior in the spreading of the plume in a direction normal to the mean flow velocity.     

Removal of Cadmium Ions from Aqueous Solution by Silicate-incorporated Hydroxyapatite

This article reports a preliminary research on silicate-incorporated hydroxyapatite as a new environmental mineral used to remove cadmium ions from aqueous solutions. The silicate-incorporated hydroxyapatite was prepared by coprecipitation and calcining, and silicate was incorporated into the crystal lattice of hydroxyapatite by partial substitution of phosphate. The amount of cadmium ions removed by silicate-incorporated hydroxyapatite was significantly elevated, which was 76% higher than that of pure hydroxyapatite. But the sorption behavior of cadmium ions on silicate-incorporated hydroxyapatite was similar to that of pure hydroxyapatite. Morphological study revealed that silicate incorporation confined the crystal growth and increased the specific surface area of hydroxyapatite, which were in favor of enhancing the cadmium ion sorption capacity of the samples. Incorporation of silicate into hydroxyapatite seems to be an effective approach to improve the environmental property of hydroxyapatite on removal of aqueous cadmium ions.     

治理地下水有机污染抽出处理技术影响因素分析

抽出处理技术是治理地下水有机污染简便易行的方法,文中的简要介绍抽出处理方法去除污染机制之后,着重分析了讨论了导致该方法去除地下水有机污染耗时及运行费用高昂的原因,在此基础上,对地下水有机污染抽出处理技术作出全面详尽的评述。     

Moisture content of natural stone: static and dynamic equilibrium with atmospheric humidity

Among hygric properties of stone material, the sorption behaviour is of essential importance because of the permanence of the processes involved. New results from static sorption experiments performed by standard techniques and by a new tool are reported for six different building stones. Furthermore, an example of dynamic sorption behaviour under continuously changing humidity is presented. For the static equilibrium sorption measurements a close relation to the stone type, its pore properties, such as specific inner surface, pore volume, pore size distribution as well as capillary water uptake and water saturation, is drawn. The comparison of the different data allows us to retrieve correlations between material features that are crucial for weathering processes. The sorption–desorption processes respond spontaneously on even small humidity changes as shown by the dynamic sorption experiment. A permanent breathing-process of the material is imposed.     

Effect of sorption intensities on dispersivity and macro-dispersion coefficient in a single fracture with matrix diffusion

Matrix diffusion and sorption are among the key processes impacting the efficiency of natural attenuation in the subsurface. While these processes have been studied extensively in fractured media, limited information exists on the sorption nonlinearity. To address this shortfall, a numerical model has been developed that couples matrix diffusion and nonlinear sorption at the scale of a single fracture using the dual-porosity concept. The study is limited to a constant continuous-solute-source boundary condition. The influence of sorption intensities on dispersivity and macro-dispersion coefficient is investigated using a method of spatial moments. Results suggest that mixing of solutes is significantly lowered by nonlinear sorptive behavior, with respect to the mixing caused by matrix diffusion for linearly sorbing solutes. Also, the magnitude of time dependent dispersivity during the pre-asymptotic regime is lower for nonlinearly sorbing solutes with respect to the linearly sorbing solutes. Reduced mixing is also observed for nonlinearly sorbing solutes under combined mechanisms of matrix diffusion and decay.

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Résumé Les phénomènes de diffusion et de sorption comptent parmi les processus clés qui influent sur l’atténuation naturelle en subsurface. Si ces processus ont été massivement étudiés en milieu fracturé, il existe en revanche peu d’informations sur la non-linéarité de la sorption. Afin de combler cette lacune, un modèle numérique a été développé ; il couple la diffusion dans la matrice et la sorption non-linéaire à l’échelle d’une fracture unitaire en utilisant le concept de double porosité. La seule condition aux limites fixée pour toute l’étude est une source de soluté constante et continue. L’influence de l’intensité de la sorption sur la dispersivité et sur le coefficient de macro-dispersion est étudié via une méthode utilisant les moments spatiaux. Les résultats suggèrent que les mélanges de solutés sont significativement réduits par les phénomènes de sorption non-linéaires, comparativement aux mélanges causés par la diffusion pour des solutés à sorption linéaire. C’est pourquoi la dispersivité, dépendante du temps, est plus faible pour les solutés à sorption non-linéaire que pour les solutés à sorption linéaire, lors du régime pré-asymptotique. Des mélanges réduits ont également été observés pour des solutés à sorption non-linéaire, sous les mécanismes combinés de diffusion dans la matrice et de dégradation.

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Resumen La difusión intersticial y la adsorción se encuentran entre los procesos clave que impactan la eficiencia de la atenuación natural en el subsuelo. Mientras que estos procesos se han estudiado extensamente en medios fracturados existe información limitada acerca de la no linealidad de la adsorción. Para abordar esta situación se ha desarrollado un modelo numérico que acopla la difusión intersticial y la adsorción no lineal a la escala de una sola fractura usando el concepto de porosidad doble. El estudio se restringe a condiciones limitantes de fuente de soluto constante y continuo. Se investiga la influencia de las intensidades de adsorción sobre el coeficiente de dispersión-macro y dispersividad usando un método de momentos espaciales. Los resultados sugieren que la mezcla de solutos disminuye significativamente mediante comportamiento de adsorción no lineal, en relación con la mezcla causada por difusión intersticial para solutos con adsorción lineal. Se observa que la magnitud de la dispersividad dependiente del tiempo durante el régimen pre-asintótico es más baja para solutos con adsorción no lineales en relación a los solutos con adsorción lineal. También se observa mezcla reducida para solutos con adsorción no lineal bajo mecanismos combinados de difusión intersticial y desintegración.

     

Organic matter of the liquid phase of peat and its hydrolyzates from the deposits of the Middle Amur basin

The liquid phase of peat from the deposits of the Middle Amur basin was investigated by scanning electron microscopy and energy dispersive analysis in order to estimate the possibility of obtaining new sorbents on its basis. It was shown that organic compounds with fractal forms and properties can be obtained on the basis of peat hydrolyzate. The concentration of carbon in them corresponds to the composition of the humic complexes extracted from peat deposits. The resulting high-molecular-weight compounds actively sorb small organic particles. The samples investigated can be used to develop a fundamentally new class of efficient petroleum sorbents.     

http://www.sciencedirect.com/science/article/pii/S1674987112000308

The Panguan Syncline contains abundant coal resources,which may be a potential source of coalbed methane.In order to evaluate the coalbed methane production potential in this area,we investigated the pore-fracture system of coalbed methane reservoirs,and analyzed the gas sorption and seepage capacities by using various analytical methods,including scanning electron microscopy（SEM）,optical microscopy,mercury-injection test,low-temperature N₂ isotherm adsorption/desorption analyses,lowfield nuclear magnetic resonance and methane isothermal adsorption measurements.The results show that the samples of the coal reservoirs in the Panguan Syncline have moderate gas sorption capacity.However, the coals in the study area have favorable seepage capacities,and are conductive for the coalbed methane production.The physical properties of the coalbed methane reservoirs in the Panguan Syncline are generally controlled by coal metamorphism:the low rank coal usually has low methane sorption capacity and its pore and microfractures are poorly developed;while the medium rank coal has better methane sorption capacity,and its seepage pores and microfractures are well developed,which are sufficient for the coalbed methane’s gathering and exploration.Therefore,the medium rank coals in the Panguan Syncline are the most prospective targets for the coalbed methane exploration and production.     

针铁矿和蒙脱石对菲的吸附解吸行为与热力学研究

采用批量振荡吸附平衡法设计针铁矿和蒙脱石对菲的吸附解吸试验,对比研究了针铁矿和蒙脱石对菲的吸附解吸行为,并考察了不同K＋浓度的溶液对蒙脱石吸附菲的影响,比较分析了线性吸附模型和Freundlich吸附模型描述矿物吸附等温线的准确性,并从吸附热力学角度探讨了矿物的吸附机理。结果表明：针铁矿和蒙脱石对菲的吸附解吸均表现出明显的非线性和解吸滞后现象;相对于线性吸附模型来说,针铁矿和蒙脱石对菲的吸附解吸更符合Freundiich吸附模型;与蒙脱石相比,针铁矿对菲的吸附更为显著,且具有更好的稳定性;溶液中软阳离子K＋的存在使蒙脱石对菲的吸附能力得到显著提高;菲在蒙脱石和针铁矿上的吸附过程是一个自发放热,同时伴随着熵值减小的过程;随着温度的升高,蒙脱石和针铁矿对菲的吸附能力均减弱。     

Uranium in Saline Lakes of Mongolia and Adjacent Areas

正1 Introduction Increasing demand for uranium raw materials for the nuclear industry has stimulated interest in non-traditional sources,including hydromineral ones[Qin,2009].Those are saline lakes located in the uranium ore districts.Accumulation of uranium in such lakes results from the leaching of uranium from the rocks by surface and ground