Hydrothermal studies in a new diamond anvil cell up to 10 GPa and from −190°C to 1200°C

The new hydrothermal diamond anvil cell (HDAC) has been designed for optical microscopy and X-ray diffraction at pressures up to 10 GPa and temperatures between –190°C and 1200°C. Laser light reffected from the top and bottom anvil faces and the top and bottom solid sample faces produce interference fringes that provide a very sensitive means of monitoring the volume of sample chamber and for observing volume and refractive index changes in solid samples due to transitions and reactions. Synchrotron radiation has been used to make X-ray diffraction patterns of samples under hydrothermal conditions. Individual heaters and individual thermocouples provide temperature control with an accuracy of ±0.5°C. Liquid nitrogen directly introduced into the HDAC has been used to reduce the sample temperature to –190°C. The - phase boundary of quartz has been used to calculate the transition pressures from measured transition temperatures. With this method we have redetermined 5 isochores of H₂O up to 850°C and 1.2 GPa at which the solution rate of the quartz became so rapid that the quartz dissolved completely before the - transition could be observed. When silica solutions were cooled, opal spherules and rods formed.     

Accuracy in measurements and the temperature and volume dependence of thermoelastic parameters

To obtain the temperatureT and volumeV (or pressureP) dependence of the Anderson-Grüneisen parameter _T , measurements with high sensitivity are required. We show two examples:P, V, T measurements of NaCl done with the piston cylinder and elasticity measurements of MgO using a resonance method. In both cases, the sensitivity of the measurements leads to results that provide information about _T (,T), where V/V ₀ andV ₀ is the volume at zero pressure. We demonstrate that determination of _T leads to understanding of the volume and temperature dependence ofq=( ln / lnV) _T over a broadV, T range, where is the Grüneisen ratio.     

Natural and anthropogenic budgets of a small watershed in the massif central (France): Chemical and strontium isotopic characterization of water and sediments

A small watershed (160 km²) located in the Massif Central (France) has been chemically, isotopically and hydrologically studied through its dissolved load, bed sediments and soils. This watershed is underlain by basaltic bedrock and associated soils in which the vegetation is dominated mainly by meadows.Dissolved concentrations of major ions (Cl, SO₄, NO₃, HCO₃, Ca, Na, Mg, K, Al and Si), trace elements (Rb and Sr) and strontium isotopes have been determined for two different hydrologic periods on the main stream of the Allanche river and its tributaries.The major objectives of this study were to characterize the chemical and isotopic signatures of each reservoir occurring in the watershed. Changes in chemical and isotopic signatures are interpreted in terms of fluctuations of the different components inputs: rainwater, weathering products, anthropogenic addition.Water quality may be influenced by natural inputs (rainwater, weathering processes) and anthropogenic additions (fertilizers, road salts, etc.). Precipitation serves as a major vehicle for dissolved chemical species in addition to the hydrosystem and, in order to constrain rain inputs, a systematic study of rainwaters is carried out over a one year period using an automatic collector. Corrections of rainwater addition using chloride as an atmospheric input reference were computed for selected elements and the Sr/Sr ratio. After such corrections, the geochemical budget of the watershed was determined and the role of anthropogenic additions evaluated through the relationship between strontium isotopes and major and trace element ratios. Thus, 10% of Ca and Na originate in rainwater input, 40 to 80% in fertilizer additions and 15 to 50% in rock weatheringThe cationic denudation rates for this watershed are around 0.3 g s^–1 km² during low water discharge and 0.6 g s^–1 km² in high water stage. This led to a chemical denudation rate of 5.3 mm/1000 years.For solid matter, the normalization of chemical species relative to parent rocks shows the depletion or enrichment in soils and sediments. The use of K and Ca as mobile reference illustrates the weathering state of soils and sediments relative to parent rocks. This weathering state for bed sediments range from 15 to 45% for the K normalization and from 2 to 50% for the Ca normalization. For the soils, the weathering state ranges from 15 to 57% for the K normalization and from 17 to 90% for the Ca normalization.     

遮放—宾川岩石圈剖面应力状态研究

选取遮放－宾川长３５０ｋｍ,深１２０ｋｍ剖面,建立不同模型,利用有限元法进行数值模拟,探讨该区地壳、上地幔的应力分布,计算表明：在线弹性介质中应力分布不仅爱断层结构的控制,而且还受物性参数的控制。壳内低速层和断面属物性软弱层,应力在其边缘或邻区较硬介质内较高,与地震一般发生在软弱层与软硬层交界处或软弱层周围物性较硬的部位的特点一致。故认为低速层和民层的作用可能是地震孕育的主要物性和结构环境因素之一     

Kalman filtering in groundwater flow modelling: problems and prospects

The popularity of applying filtering theory in the environmental and hydrological sciences passed its first climax in the 1970s. Like so many other new mathematical methods it was simply the fashion at the time. The study of groundwater systems was not immune to this fashion, but neither was it by any means a prominent area of application. The spatial-temporal characteristics of groundwater flow are customarily described by analytical or, more frequently, numerical, physics-based models. Consequently, the state-space representations associated with filtering must be of a high order, with an immediately apparent computational over-burden. And therein lies part of the reason for the but modest interest there has been in applying Kalman filtering to groundwater systems, as reviewed critically in this paper. Filtering theory may be used to address a variety of problems, such as: state estimation and reconstruction, parameter estimation (including the study of uncertainty and its propagation), combined state-parameter estimation, input estimation, estimation of the variance-covariance properties of stochastic disturbances, the design of observation networks, and the analysis of parameter identifiability. A large proportion of previous studies has dealt with the problem of parameter estimation in one form or another. This may well not remain the focus of attention in the future. Instead, filtering theory may find wider application in the context of data assimilation, that is, in reconstructing fields of flow and the migration of sub-surface contaminant plumes from relatively sparse observations. Received: October 27, 1997     

RESEARCH ON REBUILDING OZONE DYNAMIC SYSTEM OF ZONAL AVERAGE OVER THE TROPIC ZONE

The ozone data observed by TOMS in every 5°N are extended into the phase space to describe the characteristics of ozone with phase trace. First of all, the fractional dimension of the ozone layer is calculated. Then.the phase points are regarded as some discrete characteristics solution, and the parameters of mathematical model which describe the time variation of system state are retrieved, so that the nonlinear dynamic system which reflects the short-term variation of zonal average ozone layer over the tropics is rebuilt.     

The Internal Energy of a PV = RT Gas: A Univariable or Multivariable Function

Historically, the characterization of the internal energy of a simple gas is based on free expansion experiments and imprecise use of the word function, which is rigorously defined in mathematics. Univariable equations of state show that the internal energy of simple monatomic, diatomic, and polyatomic gases can be expressed as a function of temperature only. However, multivariable equations of state derived from composite functions confirm that the internal energy of these gases can in each situation also be expressed as a function of pressure and volume only. It is essential that the mathematical definition of the word function be adhered to in science because it is fundamental for the formulation of the calculus, a mathematical tool essential for solving a variety of thermodynamics problems.     

Causes of sinks near Tucson, Arizona, USA

 Land subsidence in the form of sinks has occurred on and near farmlands near Tucson, Pima County, Arizona, USA. The sinks occur in alluvial deposits along the flood plain of the Santa Cruz River, and have made farmlands dangerous and unsuitable for farming. More than 1700 sinks are confined to the flood plain of the Santa Cruz River and are grouped along two north-northwestward-trending bands that are approximately parallel to the river and other flood-plain drainages. An estimated 17,000 m³ of sediment have been removed in the formation of the sinks. Thirteen trenches were dug to depths of 4–6 m to characterize near-surface sediments in sink and nonsink areas. Sediments below about 2 m included a large percentage of dispersive clays in sink areas. Sediments in nonsink areas contain a large component of medium- to coarse-grained, moderately to well sorted sand that probably fills a paleochannel. Electromagnetic surveys support the association of silts and clays in sink areas that are highly electrically conductive relative to sand in nonsink areas. Sinks probably are caused by the near-surface process of subsurface erosion of dispersive sediments along pre-existing cracks in predominantly silt and clay sediments. The pre-existing cracks probably result from desiccation or tension that developed during periods of water-table decline and channel incision during the past 100 years or in earlier periods. Submitted, April 1997 · Revised, November 1997 · Accepted, April 1998     

吉林省前郭地区砂土强夯处理的效果研究

结合实际强夯工程资料,分析总结了强夯施工参数与强夯处理效果之间的关系,得出了一些有益的规律性认识和可供生产应用的经验数据。     

声波测井在碎屑岩沉积压实研究中的应用

通过对塔里木盆地北部阿克库勒地区 5口钻井泥质岩的声波时差及相应的孔隙度、古地层压力研究 ,求得本区的平均压实方程。认为本区 310 0～ 350 0 m属于正常压实层 ,其下属于欠压实层段。初步分析各时代流体的封闭时间和主要目的层欠压实异常类型。结合地震勘探资料 ,提出低速异常带中的更低异常区是找油领域之一。