Characteristics of Mineralizing Fluids of the Darreh‐Zerreshk and Ali‐Abad Porphyry Copper Deposits,Central Iran,Determined by Fluid Inclusion Microthermometry

The Darreh‐Zereshk (DZ) and Ali‐Abad (AB) porphyry copper deposits are located in southwest of the Yazd city, central Iran. These deposits occur in granitoid intrusions, ranging in composition from quartz monzodiorite through granodiorite to granite. The ore‐hosting intrusions exhibit intense hydrofracturing that lead to the formation of quartz‐sulfide veinlets. Fluid inclusions in hydrothermal quartz in these deposits are classified as a mono‐phase vapor type (Type I), liquid‐rich two phase (liquid + vapor) type (Type IIA), vapor‐rich two phase (vapor + liquid) type (Type IIB), and multi‐phase (liquid + vapor + halite + sylvite + hematite + chalcopyrite and pyrite) type (Types III). Homogenization temperatures (Th) and salinity data are presented for fluid inclusions from hydrothermal quartz veinlets associated with potassic alteration and other varieties of hypogene mineralization. Ore precipitation occurred between 150° to >600°C from low to very high salinity (1.1–73.9 wt% NaCl equivalent) aqueous fluids. Two stages of hydrothermal activity characterized are recognized; one which shows relatively high Th and lower salinity fluid (Type IIIa; Th_(L‐V) > Tm_(NaCl)); and one which shows lower Th and higher salinity (Type IIIb; Th_(L‐V) < Tm_(NaCl)). The high Th_(L‐V) and salinities of Type IIIa inclusions are interpreted to represent the initial existence of a dense fluid of magmatic origin. The coexistence of Type IIIb, Type I and Type IIB fluid inclusions suggest that these inclusions resulted either from trapping of boiling fluids and/or represent two immiscible fluids. These processes probably occurred as the result of pressure fluctuations from lithostatic to hydrostatic conditions under a pressure of 200 to 300 bar. Dilution of these early fluids by meteoritic water resulted in lower temperatures and low to moderate salinity (<20 wt% NaCl equiv.) fluids (Type IIA). Fluid inclusion analysis reveals that the hydrothermal fluid, which formed mineralized quartz veinlets in the rocks with potassic alteration, had temperatures of ～500°C and salinity ～50 wt% NaCl equiv. Cryogenic SEM‐EDS analyses of frozen and decrepitated ore‐bearing fluids trapped in the inclusions indicate the fluids were dominated with NaCl, and KCl with minor CaCl₂.     

Origin of fluids in the Hetaoping Pb–Zn deposit,Baoshan–Narong–Dongzhi block metallogenic belt,Yunnan Province,SW China

The Hetaoping skarn type Pb–Zn deposit is located in the Baoshan–Narong–Dongzhi block metallogenic belt (BND belt), a belt between the Tengchong terrane and the Lanping basin. The deposit is hosted by marble of the upper Cambrian Hetaoping Formation and there are no outcrops of plutonic rocks present. This deposit is one of two large Pb–Zn deposits recently discovered in the BND belt. The Hetaoping deposit is a high Mn skarn. Four types of fluid inclusions were recognized in quartz from the deposit: vapor-rich inclusions (Type I), liquid-rich inclusions (Type II), pure vapor inclusions (Type III), and pure fluid inclusions (Type IV). The coexistence of Type I and Type III inclusions in Stage I (pre-ore stage) and Stage II (main ore stage) shows evidence of fluid boiling. Quartz-hosted fluid inclusions (Stage I and Stage II) display high homogenization temperatures and salinities (134–315 °C; 3.7–18.6 wt% NaCl equivalent) but calcite-hosted fluid inclusions in Stage III (post-ore stage) record lower homogenization temperatures and salinities (85–214 °C; 0.5–5.4 wt% NaCl equivalent). These data suggest a possible mixing between primary magmatic water and meteoric water. Based on chromatography data, the fluid inclusions in quartz contain abundant CO₂ and O₂ and subordinate CO, CH₄ and C₂H₂ + C₂H₄, suggesting an oxidizing environment. Based on their Na/K and Cl/SO₄ ratios, fluids contained in fluid inclusions are similar to volcanic spring waters. The low Na/K ratios (0.40–1.34) of the ore-forming fluids may have resulted from interaction with a deep alkaline intermediate-acid intrusion. Hydrogen and oxygen isotope determinations on quartz from different ore stages show low δ¹⁸O and δD values relative to VSMOW (−4.3‰ to 2.3‰; −109‰ to −91‰), indicating that the ore-forming fluids were diluted by external fluid sources as the skarn system cooled. Overall, geological and geochemical interpretations suggest that the Hetaoping deposit is a distal manganese skarn Pb–Zn deposit related to concealed intrusions.     

鄂尔多斯盆地陇东地区延长组低渗透油藏成藏期次研究

主要对陇东地区延长组流体包裹体特征进行了研究,结合烃源岩生烃史、原油成熟度,综合分析研究区的成藏期次。流体包裹体镜下观察与荧光特征显示陇东地区延长组存在两期油气包裹体：第一期油气包裹体在单偏光下呈灰褐色或深褐色的液烃包裹体,丰度较低,盐水包裹体均一温度主峰为75~95 ℃;第二期油气包裹体以气液烃包裹体为主,液烃表现为无色或淡黄色的单偏光特征与浅黄色至蓝绿色的荧光特征,丰度较高,盐水包裹体均一温度主峰为75~95 ℃与100~120 ℃。结合烃源岩生烃史与原油成熟度认为,陇东地区延长组存在三期成藏：距今约为140~130 Ma的早期低熟油小规模充注时期;发生于120~100 Ma,与烃源岩生烃高峰期相对应的中期成熟度大规模成藏期;距今约为100~40 Ma的晚白垩世构造抬升调整成藏时期。     

云南麻栗坡南秧田白钨矿床流体包裹体、稳定同位素特征及其成矿意义

对南秧田层状矽卡岩型白钨矿石中石榴石及电气石石英脉型白钨矿石中石英流体包裹体岩相学特征研究表明,与成矿有关的包裹体主要有富液相、富气相和含子晶的流体包裹体3种类型.矽卡岩型矿石中石榴石及共生石英的包裹体均一温度为128～250℃,盐度w(NaCl) =0.7％ ～8.1％;电气石石英脉型白钨矿石中石英的流体包裹体均一温度范围为181～ 325℃,盐度w(NaCl)=1.57％ ～ 15.76％.两种类型矿石成矿溶液密度为0.75～0.95g/cm3,表明形成这两种类型矿石的成矿流体均属于中温、中-低盐度、低密度的流体.氢氧同位素结果显示其主要来源于地层水(变质水),后期受到了岩浆水的叠加改造作用.硫同位素落入沉积岩、变质岩及蒸发硫酸盐的硫同位素组成范围内.     

Evolution and prospect of financial inclusion research in China from the perspective of financial geography北大核心CSCD

普惠金融对降低贫困和促进发展成果分享具有重要意义,是国际金融地理学的重要研究议题。论文基于2005—2021年中国知网CNKI数据库3421篇核心期刊论文,利用知识图谱可视化技术分析了中国普惠金融研究的基本特征和热点演化,结果表明:(1)学术成果经历缓慢增长、快速增长、加速增长3个阶段,研究热点经由金融排斥、普惠金融到数字普惠金融的演化,其中农村、区域差异、空间格局及发展效应是各阶段的共同关注;(2)国内普惠金融研究具有学科交叉性、包容性、开放性,多学科的参与推动着普惠金融研究的蓬勃发展,在学科交叉融合过程中,不同学科又有各自的关注点;(3)基于金融地理学视角,提出普惠金融发展的空间过程、地方普惠金融发展的文化经济因素与关系网络、普惠金融的发展效应、金融科技的空间性及其潜在影响等未来研究议题。     

H-V加筋饱和砂土性状的三轴试验研究

进行了H-V（水平-竖向）加筋饱和砂土固结不排水三轴试验。加筋材料采用镀锌铁皮和有机玻璃两种不同材料,在不同竖筋高度、不同围压下共进行了44组试验,研究了加筋饱和砂土的应力-应变关系、孔压-应变关系、强度特性及破坏形态,探讨了不同加筋高度、不同围压及不同筋材对加筋饱和砂土强度的影响,同时比较了立体加筋与土工格室加筋的异同,对饱和紧砂的空化现象及其影响进行了分析。试验结果表明,相对于无筋土及传统的水平加筋土而言,其抗剪强度均有大幅度提高;尤其是镀锌铁皮加筋,不仅提高了饱和砂土的有效黏聚力,也提高了有效内摩擦角,同时改善了砂土的延性。     

内蒙古额尔古纳市虎拉林金矿床成矿流体包裹体研究

通过矿床流体包裹体岩相学、显微测温学和激光拉曼光谱成分分析,研究成矿流体性质,探讨了矿床成因类型.研究结果表明,流体包裹体以气液两相包裹体为主,少量含CO₂三相、含子矿物三相和纯气相包裹体等.成矿流体均一温度为320~360℃,盐度为19.2%~21.8%,密度为0.73~0.90 g/cm³,估算成矿压力为92.1~129.1 MPa,成矿深度为3.07~4.3km.成矿流体气相成分以H₂O为主,其次为CO₂、CH₄和N₂,微量的C₆H₆、C₂H₆和C₃H₈等,总体属H₂O-CO₂-NaCl体系.成矿流体是一种不混溶流体,主要来源于深部岩浆,并可能有幔源组分参与.金主要是以金氯配合物的形式迁移.矿床的地质-地球化学特征与隐爆角砾岩型金矿类似,应属隐爆角砾岩型金矿床.     

Trace-element compositions of single fluid inclusions in the Kofu granite, Japan: Implications for compositions of granite-derived fluids

Fluid inclusions in quartz from miarolitic cavities, pegmatites, and quartz veins in Miocene biotite-granite plutons, Kofu, Japan, were analyzed by particle-induced X-ray emission to examine chemistries and behaviors of granite-derived fluids in island-arc granite. Most inclusions are aqueous two-phase inclusions, and halite-bearing polyphase inclusions are also observed in quartz veins in the upper part of the plutons. From element contents of fluid inclusions in the miarolitic cavities, the original fluid released from the granite plutons during solidification is inferred to have concentrations of Mn, Fe, Cu, Zn, Ge, Br, Rb, Pb, and Ba of several tens to hundreds of parts per million by weight (ppm) and a salinity of about 10 wt% NaCl equivalent. We estimated the formation conditions of the fluid to have been at about 1.3–1.9 kb and 530–600°C on the basis of the homogenization temperatures of the inclusions and the solidification conditions of the plutons. The polyphase inclusions probably originated from hypersaline fluid by boiling of part of the released fluid during its ascent in the plutons. The polyphase inclusions contain several hundreds to tens of thousands of ppm of Fe and Mn, and tens to several hundreds of ppm of Cu, Zn, Br, Rb, and Pb. The salinities are about 35 wt% NaCl equivalent. Compositional variations in two-phase inclusions from the miarolitic cavities and quartz veins are primarily explained by mineral precipitation with dilution by surface water exerting a secondary influence. Thus, chemistries and behaviors of the granite-derived fluids in the plutons can be explained by mineral precipitation, boiling, and dilution of the originally released fluid.     

加拿大Abitibi 绿岩带Donalda金矿近水平含金石英脉的显微构造分析及其对成矿流体动力学的指示

位于加拿大Abitibi 绿岩带南部的Donalda 金矿床主要由近水平的、与剪切带近垂直的含金石英脉组成,矿脉厚度0.3~0.5 m,含大量与脉壁平行的条带,指示多期次裂隙扩张和矿物沉淀。原生石英 c轴方位测量显示石英生长方向垂直于脉壁,指示断裂属张性,矿物沉淀属空间充填。显微裂隙、细脉及流体包裹体面 (FIPs) 的方位测量指示原生矿物受到了近直立的最大主压应力(σ1) 作用,与区域性的、近水平的南北向挤压应力不符。这一矛盾现象可用流体压力在超静岩和静水压力之间周期性变化及近水平断裂的周期性张开与闭合来解释。当流体压力大于静岩压力时,断裂张开,原生矿物沉淀,而当流体压力减小时,断裂上盘往下垮,两盘突出的矿物碰撞、碾压形成与脉壁平行的变形条带。由于断裂两盘岩石不是沿整条断裂都互相接触,两盘相顶部分承受的垂直应力大于水平方向的挤压应力, 这就解释了为什么显微构造指示近直立的最大主压应力(σ1)。这个流体构造模式支持断层阀模式,并且无须改变区域应力场就可解释脉体内局部主压应力的变化。     

川滇黔接壤区拉一木玄武岩铜矿流体包裹体

扬子地台西南缘形成的大面积自然铜矿化是峨眉地幔柱成矿系统的重要组成部分。以四川省昭觉县拉一木玄武岩铜矿流体包裹体为研究对象,通过与自然铜矿共生的石英和方解石中各类型包裹体测定,将该自然铜矿成矿过程划分为两个阶段,其中早阶段成矿流体具有中-低温、高盐度的盆地热卤水与有机流体的混合作用特征,流体组成为H₂O,含少量甲烷、烃类及沥青,液态烃以荧光性强的芳烃为主,包裹体均一温度140~306 ℃,w(NaCl)值分布在3%~10%、11%~14%、21%~24%三个区间,平均盐度为8.6%;晚阶段流体表现为低温低盐度特征,均一温度80~190 ℃,w(NaCl)值0.2%~8%,平均值4.8%,表明流体是由地表下渗的大气降水经水岩反应后转变而成。研究区自然铜矿流体包裹体与滇东北昭通地区玄武岩铜矿流体包裹体特征基本一致。无机物与有机物反应、地幔流体促成不同类型流体与其混合以及缺硫条件和有机质的还原作用是导致本区自然铜沉淀富集成矿的主要机制。