柴北缘—东昆仑地区造山型金矿床的流体包裹体研究

柴达木盆地北缘(以下简称柴北缘)—东昆仑地区已经勘查发现了一批造山型金矿,它们是加里东和晚华力西—印支复合造山作用的产物。通过柴北缘—东昆仑地区12处造山型金矿中流体包裹体研究发现,该区造山型金矿中发育两种不同的成矿流体:低盐度的H2O-CO2-NaCl-CH4流体和低盐度的H2O-CO2-NaCl±CH4。前者的XCH4、XCO2和XH2O分别为0.14～0.34(平均值0.24)、0.11～0.59(平均值0.34)和0.64～0.31(平均值0.42),温度变化为180～270℃,压力为180～560Mpa,是晚加里东期碰撞造山作用的产物,主要沿加里东碰撞造山带边界的上地壳底部-中地壳上部的塑性变形带大规模流动,并在本区形成了广泛的金矿化;后者的XCH4、XCO2和XH2O分别为0～0.12(平均值0.06)、0.18～0.25(平均值0.21)和0.79～0.69(平均值0.73),温度变化为280～449℃(主要在280～360℃),压力为80～230Mpa,主要与晚华力西—印支期碰撞造山作用有关,其中不少矿床还受侵入岩浆作用的影响,其沿晚华力西—印支期碰撞造山带边界的上地壳大规模流动,导致了本区造山型金矿的最终定位。上述两期成矿流体的盐度相差不大,总体变化在1.4%～11.4%(NaCl)(大部分集中于2.7%～9.1%)。压力-深度换算结果显示,本区晚华力西—印支期碰撞造山作用表现出地壳强烈隆升过程,其最大隆升幅度达12km。这说明该区大规模的造山型金成矿作用发生在地壳隆升的背景之下。     

利用储层流体包裹体确定鄂尔多斯盆地塔巴庙区块上古生界油气充注期次和时期

流体包裹体是保存在储层中的微小流体样品,包含有丰富的地质信息。通过对鄂尔多斯盆地塔巴庙区块18口井的62块流体包裹体样品进行荧光观察和显微测温,认为该区上古生界地层共发生过6期流体活动,均与油气成藏有关,并以第二期—第六期的天然气充注为主。结合埋藏史分析可知,油气成藏分别发生在距今190～150Ma的早侏罗世中期—中侏罗世晚期,150～124Ma的中侏罗世晚期—早白垩世早期,124～101Ma的早白垩世早期—早白垩世中期,101～86Ma的早白垩世中期—早白垩世中末期和86～70Ma的早白垩世中末期—早白垩世末期。其中,早侏罗世中期—中侏罗世晚期为油气充注的初始阶段,中侏罗世晚期—早白垩世早期为轻质油的主要成藏时期,中侏罗世晚期至早白垩世末为研究区内目的层天然气的主要成藏时期。     

On the origin of oriented rutile needles in garnet from UHP eclogites

Although oriented rutile needles in garnet have been reported from several ultrahigh‐pressure (UHP) rocks and considered to be important UHP indicators, their crystallographic features including growth habit and lattice correspondences with garnet host have never been properly characterized. This paper presents a detailed analytical electron microscopic (AEM) study on evenly distributed oriented rutile needles in garnet of two eclogitic rocks from Sulu. Some garnet in one UHP diamondiferous quartzofeldspathic rock from the Saxonian Erzgebirge, and in one high‐pressure (HP) felsic granulite from Bohemia also contain a few unevenly distributed oriented rutile needles. They have also been studied for the purpose of comparison. Despite different distribution patterns, AEM revealed that all rutile needles are oriented along the 〈111〉 directions of garnet with their lateral sides surrounded by the {110} planes of garnet, and that the growth directions of most needles are close to the normal of the {101} planes of rutile. No other specific crystallographic orientation relationships between rutile and garnet host were observed, and there is no pyroxene associated with rutile, as necessitated by the precipitation reaction of rutile in garnet as previously proposed. A simple solid‐state precipitation scenario for the formation of the rutile needles in garnet in these two eclogitic rocks is not justified. Three alternative mechanisms are considered for the formation of oriented rutile needles: (i) the rutile needles may be inherited from precursor minerals; (ii) the rutile needles may be formed by a dissolution–reprecipitation mechanism; and (iii) the rutile needles may be formed by cleaving and healing of garnet with rutile deposition. None of these mechanisms can fully explain the observations, although the first one is less likely and the third one is preferred. This study presents an example where the presence of oriented/aligned inclusions in minerals does not necessarily imply a precipitation origin.     

新疆西天山阿希金矿床流体包裹体地球化学特征

本文在系统总结前人关于矿床地质特征和流体成矿作用研究成果的基础上,补充开展了热液成矿期石英-碳酸盐阶段石英、方解石和重晶石中流体包裹体的均一法和冷冻法测温,并对石英样品进行了气相色谱测量,对石英流体包裹体中的稀土和微量元素进行了测试。结果表明,矿床具有典型的浅成低温热液金矿的特点,成矿流体总体上盐度很低,多数都集中于0.53～1.57wt%NaCl。成矿流体的主要成分为H_2O、CO_2和CH_4。流体包裹体微量元素与容矿围岩具有继承性,流体中Cu、Ni、Co、Mo、Zn、Pb、V、Sb和Li等的含量较高,可能说明了Cu、Zn、Co、Ni、Bi和Ba等元素在水岩反应过程中更容易进入流体当中。石英流体包裹体中∑REE为13825×10~(-12)～149935×10~(-12),LREE/HREE为2.63～50.83,δEu为0.70～0.91,表现为Eu的弱亏损。成矿流体的REE配分型式与火山岩具有相同的Eu亏损和右倾配分曲线,表明成矿流体在演化过程中可能继承了早期火山岩的REE特征;但成矿流体的LREE/HREE值比火山岩大,前者的REE配分曲线比后者更加右陡倾斜,这可能与后期变质水和大气降水的混入引起的成矿流体物质组分发生有关。     

四川甘洛赤普铅锌矿床流体包裹体特征及成矿机制初步探讨

赤普铅锌矿床位于扬子地台西南缘川滇黔成矿区内,是川滇黔地区重要的铅锌矿床之一.通过野外和显微镜下观察,将成矿期形成的石英划分为Ⅰ、Ⅱ、Ⅲ三个阶段.本次选取了21件样品进行研究,对保存于石英、闪锌矿及硅化白云石中的原生包裹体进行的详细研究,赤普铅锌矿床中包裹体类型相对较为单一,以气液包裹体为主.Ⅰ、Ⅱ、Ⅲ阶段石英中流体包裹体均一温度和盐度范围分别为:230℃～270℃和2.74～19.68wt%(NaCl),150℃～200℃和3.71～16.99wt%(NaCI)和180℃～220℃和0.70～16.15wt%(NaCl)三个区间.主成矿阶段的闪锌矿流体包裹体的均一温度和盐度范围为127℃～210℃和4.34%～22.17%(NaCl).该矿床成矿流体均一温度和盐度范围主要在130℃～200℃和8.5%～17.0%(NaCl)之间,属于低温、中等盐度铅锌矿床.成矿流体为H2O-NaCl-CaCl2体系;成矿过程中成矿流体始终处于相对还原环境.成矿物质来源于上地壳,成矿流体主要来自围岩地层;成矿机制可能为含金属和舍还原硫流体混合成矿.该矿床应归属于密西西比型铅锌矿床.     

槽隆与台向斜构造对比的流体包裹体研究

对槽隆与台向斜这两个不同构造单元的早古生代沉积地层进行了系统的流体包裹体对比研究,阐述了其各自的流体包裹体类型,测定了均一温度,进而探讨了流体包裹体特征所显示的两大构造单元的古地理环境。     

凡口铅锌矿床海底热泉喷溢成矿的物理化学环境

凡口铅锌矿是发育于碳酸盐岩建造中的海底喷溢沉积矿床 ,以“一大二富三集中”的特点和典型的地质地球化学特征吸引着中外矿床地质工作者。叠层状矿体发育于同沉积断裂的旁侧 ,矿层与灰岩呈沉积接触关系。矿石具沉积碎屑组构 ,黄铁矿、闪锌矿具外生特征。稀土元素组成和硫同位素组成反映矿床与同生作用有关。铅同位素组成具有壳源和下地壳来源铅的特征。矿区主要矿层经历海底热泉喷溢沉积—成岩的演化     

胜利油田火山岩单个包裹体碳同位素

近年来,在我国东部陆续发现了一些二氧化碳气藏,对其成因,不少学者有过讨论, 得出许多重要认识^①。     

scattering and refracting of plane strain wave by a cylindrical inclusion in fluidsaturated soils

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Ca, Al-rich inclusions in Yamato 791717 (CO3) carbonaceous chondrite: Formation and alteration

In three polished thin sections of Yamato 791717 (CO3). fifty-five Ca, Al-rich inclusions were found, which include two hibonite-bearing, eight melilite-rich and forty-five spinel-pyroxene inclusions. Based on the petrography and mineral chemistry of the inclusions, it is proposed that the melilite-rich inclusions and spinel-pyroxene inclusions condensed in the solar nebula, and the hibonite-bearing inclusions crystallized from melts. The heavy alteration of the inclusions in Yamato 791717, which probably took place under a very oxidizing condition in the solar nebular, is also confirmed. Project supported by the National Natural Science Foundation of China (Grant No. 49673200). and by the Japanese Society for Promotion of Sciences (JSPS).