钾霞石制备体系碱性滤液的利用技术

为处理钾长石水热制备钾霞石所产生的碱性滤液,本文采用水热法,考察了氢氧化铝溶解时间、晶化时间、晶化温度、水碱比对钾霞石产率和白度的影响,并对合成钾霞石物相进行了表征。结果表明,合成钾霞石的最佳条件为,氢氧化铝溶解时间为1.5 h,晶化时间为4 h,晶化温度280℃,水碱比为1.8。XRD结果表明,产物为钾霞石粉体。傅里叶变换红外光谱表明,Al(OH)₃中的Al在水热条件下进入到Si—O骨架中形成了Si—O—Al官能团,从而印证了钾霞石的合成。差热分析结果表明,合成钾霞石具有良好的热稳定性。氮气吸附结果表明,合成钾霞石比表面积为5.18 m²/g,平均孔径为32.98 nm。实现了钾长石水热制备钾霞石所剩碱性滤液的资源化利用,并为钾长石水热制备钾霞石提供了一种母液循环的思路,使水热制备钾霞石工业化成为一种可能。     

The mass accommodation coefficient of ammonia on water

The mass accommodation coefficient of ammonia gas on water has been determined by measuring the absorption rate of 50–200 ppm NH₃ in one atm of air or helium into a liquid jet of 97 µm diameter as function of the exposed jet length, and comparing the results with numerical simulations which treat as the only free parameter. The model considers in detail transport of NH₃ by molecular diffusion, penetration of the gas/water interface, hydrolysis in the acidified water, and transport of the solutes from the surface into the jet. A correction is applied for the time evolution of the jet surface speed, using literature data on the fluid mechanics of liquid jets. The result of nine sets of independent measurements is

Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients

A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO₃ (0.01), N₂O₅ (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.     

Geochemical evolution of the Capim River kaolin, Northern Brazil

The Capim River kaolin, located in the eastern Brazilian Amazon, constitutes one of the most important kaolin deposits in the world. Known for its high whiteness, its noble application is in the paper industry. Studies were carried out on samples from the six facies of the deposit (sand kaolin, soft kaolin, lower transition facies, ferruginous crust, upper transition facies and flint kaolin) in order to trace its geochemical evolution. The kaolin developed at the expense of Cretaceous sandy–clayey sediments of the Ipixuna Formation. Intense lateritic processes characterized by ferruginization and deferruginization mechanisms led to the distinction of the different facies.     

虚拟样机技术在地质工程机械领域的应用研究

基于对国内地质工程机械的研发现状的考虑，根据虚拟样机技术的特点，讨论了在地质工程机械领域实施虚拟样机技术的必要件，并提出了建立地质工程机械虚拟样机的策略。联合PRO／E、ANSYS及ADAMS建立了气动潜孔锤的虚拟样机模型，对气动潜孔锤虚拟样机进行了仿真，阐明了虚拟样机技术在地质工程机械领域的应用前景。     

Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.     

In situ time resolved synchrotron powder diffraction study of thaumasite

Structural changes during dehydration and subsequent decomposition in thaumasite Ca₃Si(SO₄)(CO₃)(OH)₆·12 H₂O were studied by in situ synchrotron powder diffraction between 303 and 1,098 K. Evolution of the crystal structure was observed through 28 structure refinements, by full profile Rietveld analysis performed in the P6₃ space group, between 300 and 417 K, whereupon the thaumasite structure was observed to breakdown. Within this temperature range, the cell parameters of thaumasite increased as a function of temperature in a nearly linear fashion up to about 393 K, at which temperature, a slight slope change was observed. Above 400 K, the thermogravimetric analysis revealed that the dehydration process proceeded very rapidly while the refined occupancy of water molecules dropped below a critical level, leading to instability in the thaumasite structure. At a same time, a remarkable change in the unit cell parameters occurring at about 417 K indicated that the crystal structure of thaumasite collapsed on losing the crystallization water and it turned amorphous. This result indicated that the dehydration/decomposition of thaumasite was induced by the departure of the crystallization water. At about 950 K, anhydrite and cristobalite crystallized from the thaumasite glass.     

人为土的概念、特征及其工程研究意义

本文提出了人为土的工程概念,从其成因的角度给出了人为土明确的科学定义,归纳和总结了人为土的基本特征,为人为土的工程分类体系建立、合理评价、工程利用和环境整治提供科学依据。     

滑坡及危岩(崩塌)防治工程措施选择与工程设置

滑坡和危岩（崩塌）治理工程措施较多，措施组合可变性大，每种工程措施都有其相应的应用条件，不宜性、适宜性和最佳配置组合。治理工程措施选择应充分考虑治理工程功能性的具体要求、在不同工况条件下的安全性及耐久性、工期要求和投资的经济性以及后期维护的要求、工程岩土体性质及其蓄水后的变化、场地条件、施工技术条件、地方材料资源等具体制约因素以及环境保护的要求。在三峡水库区二期地质灾害防治工程国家级验收总结的基础上，对滑坡与危岩（崩塌）常用防治工程措施（排水、削方减载、回填压脚、抗滑桩、重力式抗滑挡墙、预应力锚索、格构锚固、拦石墙等）的工程适用条件、工程设置及不宜性进行了详细的分析，并提出工程设置应考虑及注意的问题。     

浅析混凝土质量通病防治的措施

在混凝土工程施工时，经常会发现诸如蜂窝、麻面、孔洞、露筋、缝隙、夹层、缺棱掉角、表面不平整。混凝土强度不够，均质性差等质量通病。在分析产生混凝土施工质量问题原因的基础上，有针对性地提出了各种防治措施。