下地壳及壳幔过渡带化学不均一性──河北汉诺坝地区深源捕虏体元素地球化学证据

河北汉诺坝玄武岩中长英质麻粒岩、镁铁质麻粒岩和辉石岩捕虏体的主量元素和微量元素特征,反映了下地壳及壳幔过渡带组成具有高度化学不均一性。不相容元素原始地幔标准化曲线特征的差异表明捕虏体成因复杂。MgO与不相容元素无或仅有很弱的相关性,与相容元素的相关性则相对较明显。这些特征反映了下地壳及壳幔过渡带存在较强和多元的混合作用。捕虏体的加权平均值比基于麻粒岩地体资料估算的下地壳平均组成偏基性,揭示了二者可能的成因差异。     

香草坪花岗岩体年代学和地球化学特征

香草坪岩体主要岩性为中粗粒斑状黑云母花岗岩,SHRIMP锆石U-Pb法年龄为211±2Ma,属于印支期岩浆作用产物。岩石地球化学特征研究表明,其ACNK,微量元素模式图曲线形态总体向右倾,以及轻稀土富集、Eu明显亏损的稀土配分模式曲线特征,与华南S型花岗岩的地球化学特征相似。该岩体高(87Sr/86Sr)i和低εNd(t)的特点,表明其可能是前寒武系中等成熟度的基底岩石经部分熔融形成的。该区基底岩石较高的铀含量,可为香草坪岩体提供充足的铀元素,形成铀元素的初始富集。     

Lu–Hf and U–Pb isotope systematics of zircons from the Storgangen intrusion, Rogaland Intrusive Complex, SW Norway: implications for the composition and evolution of Precambrian lower crust in the Baltic Shield

The Storgangen orebody is a concordantly layered, sill-like body of ilmenite-rich norite, intruding anorthosites of the Rogaland Intrusive Complex (RIC), SW Norway. 17 zircon grains were separated from ca. 5 kg of sand-size flotation waste collected from the on-site repository from ilmenite mining. These zircons were analysed for major and trace elements by electron microprobe, and for U–Pb and Lu–Hf isotopes by laser ablation microprobe plasma source mass spectrometry. Eight of the zircons define a well-constrained (MSWD=0.37) concordant population with an age of 949±7 Ma, which is significantly older than the 920–930 Ma ages previously reported for zircon inclusions in orthopyroxene megacrysts from the RIC. The remaining zircons, interpreted as inherited grains, show a range of ²⁰⁷Pb/²⁰⁶Pb ages up to 1407±14 Ma, with an upper intercept age at ca. 1520 Ma. The concordant zircons have similar trace element patterns, and a mean initial Hf isotope composition of ¹⁷⁶Hf/¹⁷⁷Hf_{949 Ma}=0.28223±5 (_Hf=+2±2). This is similar to the Hf-isotope composition of zircons in a range of post-tectonic Sveconorwegian granites from South Norway, and slightly more radiogenic than expected for mid-Proterozoic juvenile crust. The older, inherited zircons show Lu–Hf crustal residence ages in the range 1.85–2.04 Ga. One (undated) zircon plots well within the field of Hf isotope evolution of Paleoproterozoic rocks of the Baltic Shield. These findings indicate the presence of Paleoproterozoic components in the deep crust of the Rogaland area, but do not demonstrate that such rocks, or a Sveconorwegian mantle-derived component, contributed significantly to the petrogenesis of the RIC. If the parent magma was derived from a homogeneous, lower crustal mafic granulite source, the lower crustal protolith must be at least 1.5 Ga old, and it must have an elevated Rb/Sr ratio. This component would be indistinguishable in Sr, Nd and Hf isotopes from some intermediate mixtures between Sveconorwegian mantle and Paleoprotoerzoic felsic crust, but it cannot account for the initial ¹⁴³Nd/¹⁴⁴Nd of the most primitive, late Sveconorwegian granite in the region, without the addition of mantle-derived material.     

Temperature of the Icelandic crust: Inferred from electrical conductivity, temperature surface gradient, and maximum depth of earthquakes

Two different models of the structure of the Icelandic crust have been presented. One is the thin-crust model with a 10–15 km thick crust beneath the axial rift zones, with an intermediate layer of partially molten basalt at the base of the crust and on the top of an up-domed asthenosphere. The thick-crust model assumes a 40 km thick and relatively cold crust beneath central Iceland. The most important and crucial parameter to distinguish between these different models is the temperature distribution with depth. Three methods are used to estimate the temperature distribution with depth. First, the surface temperature gradient measured in shallow wells drilled outside geothermal areas. Second, the thickness of the seismogenic zone which is associated with a 750 °C isothermal surface. Third, the depth to a layer with high electrical conductivity which is associated with partially molten basalt with temperature around 1100 °C at the base of the crust. Combination of these data shows that the temperature gradient can be assumed to be nearly linear from the surface down to the base of the crust. These results are strongly in favour of the thin-crust model. The scattered deep seismic reflectors interpreted as Moho in the thick-crust model could be caused by phase transitions or reflections from melt pockets in the mantle.     

斜坡非饱和带低渗透岩石结构体风化前锋扩展过程

非饱和带低渗透岩石结构体风化前锋扩展是斜坡灾害孕育过程中的关键环节之一。到目前为止,化学风化领域的研究成果主要集中在高水-岩比的饱和环境下单矿物及矿物成分单一的碳酸盐岩的风化动力学方面,非饱和环境下的岩石风化研究还主要限于风化产物的特性描述方面。斜坡非饱和带低渗透岩石结构体风化前锋扩展是一种高度复杂的THMC过程。由于在溶解对象、溶解液及溶解过程的水动力-水化学环境等方面存在的显著差异,既有的地质材料风化动力学成果为探索这一复杂过程提供了理论储备,但还不能阐明其核心机理。斜坡非饱和带低渗透岩石结构体风化前锋的扩展过程研究不仅可以加深人们对斜坡灾害孕育的理解,为灾害预报-预警及其控制提供理论依据,同时可以促进岩石-岩体力学及浅表生水文地球化学等相关学科的交叉与发展。     

The mafic-ultramafic complex near Finero (Ivrea-Verbano Zone), I. Chemistry of MORB-like magmas

Geochemical data are presented for the meta-igneous, mafic-ultramafic complex near Finero. This complex is in contact with a phlogopite-bearing mantle peridotite and is subdivided into the Internal Gabbro unit, the Amphibole Peridotite unit, and the External Gabbro unit. The Internal Gabbro and the Amphibole Peridotite units consist of coarse-grained, chemically heterogeneous cumulates, whereas the External Gabbro unit is generally massive, chemically more uniform and approximately representative of the residual melt with MgO contents between 6.6 and 9.1% and Mg numbers between 38 and 58. Both whole-rock and mineral contents of Ni and Cr are significantly higher (at similar Mg numbers) in the Amphibole Peridotite unit than in the Internal Gabbro unit. The most straightforward interpretation of this is that the Amphibole Peridotite unit accumulated after the influx of fresh mafic (or ultramafic) magma into the magma chamber. Major-element chemical trends are continuous from the Amphibole Peridotite unit to the External Gabbro unit and are consistent with closed-system fractionation with no further addition of magma or contamination by wall or roof rock assimilation. In the External Gabbro unit, total FeO and TiO₂ contents are strongly correlated with each other (and with P₂O₅ and Zr) and reach values as high as 19 and 4%, respectively, indicating an advanced degree of crystal fractionation along a tholeftic trend. The External Gabbro samples have generally smooth normalized trace element patterns, which are consistent with being representative of a liquid composition. The residual nature of the External Gabbro magma is also indicated by negative Eu and Sr anomalies, clear evidence for prior feldspar fractionation. REE patterns are otherwise indistinguishable from N-type MORB, but Th and U are significantly more depleted than in MORB. This Th and U depletion is similar to that found in olivine basalts and picrites on Iceland and Hawaii; its origin is not well understood. No evidence is seen for any assimilation of crystal material, in sharp contrast with the situation of the igneous complex in Val Sesia near Balmuccia, where the magma composition is dominated by assimilation of crust. We suggest that the heat provided by at most two injections of magma near Finero was insufficient to induce crystal anatexis, in contrast with the excess heat supplied by multiple magma injections at Balmuccia.     

Early Miocene adakite-like volcanism in the Balkuyumcu region, central Anatolia, Turkey: Petrology and geochemistry

The Balkuyumcu region, located in the southwestern part of Ankara in the Izmir-Ankara suture zone (central Anatolia, Turkey), consists of basic andesitic, andesitic, dacitic and rhyolitic rocks extruded during the Early Miocene (20–22 Ma) as a result of post-collisional volcanism. Balkuyumcu volcanic rocks can be divided into two groups on the basis of their mineralogy and composition: The basic andesitic (BA) and andesitic, dacitic and rhyolitic (ADR) groups. The ADR and BA group of rocks have adakite-like and calc-alkaline characteristics, respectively. The ADR group has higher SiO₂ content, Sr/Y and La/Yb ratios and low MgO, Mg#, Y and Yb contents than the BA group. Both groups have nearly the same Sr, Nd isotopic compositions and display similar normalized multi-element patterns with enrichments in LILE and LREE, depletions in Nb, Ti, Zr, P and a lack of Eu anomalies. Major, trace element and Sr, Nd isotopic data indicate that both groups of rocks were derived from the same source but affected by different magmatic processes during ascent. The adakite-like rocks may have been produced by partial melting of thickened lower continental crust. Fractional crystallization also played a major role in their formation. However, the BA group rocks were derived from partial melting of lower continental crust that was probably delaminated. These rocks appear to have had limited interaction with mantle peridodite during ascent to the surface.     

中国海城地震区地壳与上地幔构造特征的研究

研究表明,海城地震区地壳与上地幔构造特征可以归纳为如下四点:1.震区所处的辽南地区,其地壳是由高速与低速相间的成层介质组成,地壳与上地幔结构不论纵向和横向都是不均匀的,且被深大断裂切割为若干块体;2.本区地壳按其界面分布特征可分为上层地壳、中层地壳和下层地壳;3.本区地壳介质在纵向及横向上均存在明显的不均一性;4.海城地震震源区位于耿庄——海城上地幔局部隆起东侧的中层地壳上部。     

湘南骑田岭矿集区的深部构造特征 及其对区域成矿的制约

湘南骑田岭矿集区是我国重要的有色金属基地之一,具有断裂构造异常发育,存在多期次岩浆活动、多类型矿床和矿种组合的特点。为了揭示深部地壳结构对区域成矿特征的制约,本文布置了穿越黄沙坪铅锌矿床和骑田岭花岗岩体的人工地震剖面,数据采集采用了直线多次叠加的技术方法,采取大炮和小炮相结合的激发方式进行实验工作,共完成物理点651个。实验结果表明,骑田岭矿集区深、中、浅部存在着比较明显的地震构造波组,莫霍面深度约为33~38km;在骑田岭岩体深部存在明显的莫霍面不连续性,呈现出类似于"逆断层"的构造特征和无反射波组或弱波组异常;反射速度反演结果也表明骑田岭岩体深部存在着下凹状低速度异常。这些深部构造特征说明区域存在幔源物质上涌和参与成岩成矿作用的通道,该构造通道可对应于茶陵-郴州-临武深大断裂带,暗示地幔物质的混入可能是湘南骑田岭矿集区发生大规模成矿作用的内在原因之一。而且,莫霍面"逆断层"构造特征显示区域上曾遭受较强烈的构造挤压作用,是区域中生代多次构造挤压作用的体现。这种构造挤压作用致使岩石圈增厚,发生较大规模的拆沉作用和深部岩浆上侵活动,为区域成矿作用提供必要的物质和能量。     

富钴结壳中贵金属元素的特征

对太平洋CL、CM海山调查时获取9个富钴结壳样品,采用化学处理及ICP-MS法进行分析。对贵金属元素含量分布特征、富集因子、标准化模式以及来源进行探讨和研究。结果表明：海山结壳中贵金属元素Ag、Au、Ru、Rh、Pd、Pt等的平均含量分别为： 1.05×10^-6、2.3×10^-6、15.6×10^-9、22.3×10^-9、2.39×10^-9和432×10^-9。与结核、洋壳及陆地矿石的Pd/（Pt+Pd）、Pt/（Pt+Pd）和Pd/Pt等贵金属元素的比值相比,大洋富钴结壳的 Pd/（Pt+Pd） 比值最低,为0.006;其次是结核,为0.06;洋壳为0.08;陆地矿石的Pd/（Pt+Pd）比值较大,为0.35～0.65。结壳的Pt/（Pt+Pd）比值最高,为0.99;其次是结核,为0.95;洋壳为0.93;陆地矿石的Pt/（Pt+Pd）比值相对较低,为0.33～0.65。统计分析显示了不同区域、不同环境中贵金属元素的特征参数变化,并且说明富钴结壳中富铂、金、钌、铑,而贫钯。贵金属元素标准化显示,海山富钴结壳均存在着Pt、Au正异常和Pd的负异常,其中Au异常幅度与结核的Au异常一致。