数据同化的南海台风浪后报模式

将基于最优插值(OI)的同化并行模块植入第三代海浪模式WAVEWATCH III version3.14, 建立数据同化的台风海浪模式预报系统。该系统的强迫风场采用模型台风风场与台风来前海区背景风场混成的风场。以模式后报2010 年7 月严重影响南海北部的“康森”和“灿都”台风引起的海浪场为例, 首先对所构造的混合风场的台风海面风场结构进行定性检验, 并用高度计沿轨风速对混合风场精度进行定量验证。在此基础上, 海浪模式在混合风场强迫下边积分边同化。同化数据采用上述台风过境南海期间Jason-2 卫星高度计沿轨有效波高 (SWH)。值得指出的是, 同化时只取SWH 沿轨数据的一部分用于同化计算, 而另一部分沿轨数据则用于对同化分析结果进行检验。先后同化了4 条轨道上的SWH数据。将SWH 的同化分析与无同化的对照组结果分别与高度计测量SWH 比较, 发现同化较无同化可使均方根误差获得50%以上的明显改进。以同化分析场作为初始场, 同化影响预报(这里是后报)的时效性约在48 h 以内。本研究目的是通过同化高度计SWH 数据进一步提升台风海浪模式预报的准确度。     

UV-Vis spectrophotometric and XAFS studies of ferric chloride complexes in hyper-saline LiCl solutions at 25-90 °C

The speciation and thermodynamic properties of ferric chloride complexes in hydrothermal solutions and hypersaline brines are still poorly understood, despite the importance of this element as a micronutrient and ore-component. Available experimental data are limited to room temperature and relatively low chloride concentrations. This paper reports results of UV-Vis spectrophotometric and synchrotron XAFS experiments of ferric chloride complexes in chloride concentrations up to 15 m and at temperatures of 25-90 °C. Qualitative interpretation of the UV-Vis spectra shows that FeCl²⁺, FeCl₂⁺, FeCl_3(aq) and FeCl₄⁻ were present in the experimental solutions. As chloride concentrations increase, higher ligand number complexes become important with FeCl₄⁻ predominating in solutions containing more than 10 m at 25 °C. The predominance fields of FeCl_3(aq) and FeCl₄⁻ expand to lower Cl concentrations with increasing T. Both XANES and UV-Vis spectra reveal a major change in the geometry of the complex between FeCl₂⁺ and FeCl_3(aq). EXAFS data confirm that the number of chloride ligands increases with increasing chloride concentration and show that Fe³⁺, FeCl²⁺ and FeCl₂⁺ share an octahedral geometry. FeCl_3(aq) could be either tetrahedral or trigonal dipyramidal, while FeCl₄⁻ is expected to be tetrahedral. EXAFS data support a tetrahedral geometry for FeCl₄⁻, especially at 90 °C, but do not allow to distinguish between a tetrahedral or trigonal dipyramidal geometry for FeCl_3(aq) because of similar Fe-Cl distances. At room temperature, EXAFS data suggest that FeCl_3(aq) may be a mixture of octahedral and tetrahedral or trigonal dipyramidal forms.The room temperature formation constants for three ferric chloride complexes (FeCl₂⁺, FeCl_3(aq) and FeCl₄⁻) determined from the UV data are generally in good agreement with previous studies. Calculations based on the properties extrapolated to 300 °C show that hematite solubility is much higher than previously estimated, and that the high orders complexes FeCl_3(aq) and FeCl₄⁻ are important at high temperatures even in solutions with low chloride concentrations. The accuracy of these properties is limited by a poor understanding of activity-composition relationships in concentrated electrolytes, and by limitations in the available experimental techniques and extrapolation algorithms; however, the inclusion of higher order complexes in numerical models of ore transport and deposition allows for a more accurate qualitative prediction of Fe behaviour in hydrothermal and hypersaline systems.     

兰坪盆地水泄铜(钴)矿床石英的40Ar-39Ar快中子活化年龄

选取水泄铜(钴)矿床主成矿阶段的石英样品进行⁴⁰Ar-³⁹快中子活化法同位素地质年龄测定,获得坪年龄59.2±0.8Ma,对应的等时年龄为59.8±0.5Ma,反等时线年龄为59.9±0.1Ma,三者在误差范围内完全一致,都可代表矿石的形成年龄。该年龄与兰坪盆地铜多金属矿集区的矿床形成时代一致,反映包括水泄铜(钴)矿床在内的区域矿床形成于喜马拉雅造山运动早期统一的构造地质背景之下,受同一期构造—热演化事件的制约。     

Elemental abundance analyses with DAO spectrograms: XXX. The middle B through early A stars ξ2 Ceti (B9 III), 21 Aquilae (B8 II‐III), ι Aquilae (B5 III), and ι Delphini (A2V)

This series of high quality elemental abundance analyses of mostly main‐sequence band normal and peculiar B, A, and F stars defines their properties and provides data for the comparison with the analyses of somewhat similar stars and with theoretical predictions. Most use high dispersion and high S/N (≥ 200) spectrograms obtained with CCD detectors at the long camera of the Coudé spectrograph of the 1.22‐m Dominion Astrophysical Observatory telescope. Here we reanalyze 21 Aql with better quality spectra and increase the number of stars consistently analyzed in the spectral range B5 to A2 by analyzing three new stars for this series. In the early A stars the normal and non‐mCP stars have abundances with overlapping ranges. But more stars are needed especially in the B5 to B9 range. ξ² Cet on average has a solar composition with a few abundances outside the solar range while both 21 Aql and ι Aql have abundances marginally less than solar. The abundances of ι Del are greater than solar with a few elements such as Ca being less than solar. It is an Am star (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Photochemical activity and characterization of the complex of humic acids with iron(III)

This study examined the effects of humic acids (HA) and Fe(III)–HA complex on the photodegradation of atrazine, one of the most widely used herbicides. It was shown that the photolysis of atrazine proceeded via first-order reaction kinetics and that atrazine photodegradation was inhibited by the presence of HA, whereas the rate for atrazine photolysis was promoted in solutions containing both HA and Fe(III). Interactions of Fe(III) with HA were characterized by SEM, EDX, UV–Vis and FTIR, revealing that Fe(III)–HA complex was formed by ligand exchange between oxygen groups of HA and Fe(III). Using fluorescence spectrometry the stability constant (K_c) and the fraction of fluorophores available for complexation (f) were obtained as log K_c = 4.28 and f = 74%. Photoformed Fe(II) by ligand-to-metal charge-transfer (LMCT) within the Fe(III)–HA complex was the most important factor involved in photolysis of atrazine, since Fe(II) was the reactant to generate hydroxyl radical. Thus, the rate of atrazine photodegradation in natural sunlit waters is dependent on both the amount of iron present and the interaction between HA and iron.     

驼路沟喷气沉积型钴(金)矿床的地质-地球化学

驼路沟矿床是容矿于震旦－寒武纪富钠火山－沉积岩系中的钴（金）矿床。矿床地质－地球化学特征,矿体的产态,矿石结构构造以及金属矿物的标型表明,驼路沟钴（金）矿床主要与震旦－－寒武纪海底喷气沉积成矿作用有关,在加里东和晚华力西－印支碰撞造山过程中,喷气沉积型矿体被构造改造,并导致金在局部地段进一步富集。元素地球化学研究揭示,Au,As,Pb,Cu,Zn,Mo,Co是圈定含矿层的化探异常元素组合,而Co-Ni-Au-Pb-Mo-As组合异常可以指示矿体。建议在矿床勘查的初期注意可能出现于喷气沉积成矿中心附近的铜钴矿。     

WAVEWATCHIII 同化模块的建立和检验

将基于最优插值 (OI) 的同化并行模块植入全谱空间的第三代海浪模式WAVEWATCH III version3.14,建立数据同化的海浪模式预报系统, 并通过实际的预报个例对同化系统进行检验。个例实验是以5°S 以北的印度洋海域为目标计算区域, 海面风场强迫采用业务单位的中尺度天气预报模式WRF(weather research and forecast) 提供的逐时海面风场预报产品。模式积分过程中连续同化2010 年12 月15 日、16 日和17 日过境北印度洋的Jason-2 卫星高度计沿轨有效波高 (SWH) 数据 (需要指出的是, 每次同化得到新的SWH 分析场后需重构相应的二维海浪谱用于谱模式)。SWH 同化分析值和无同化的对照组分别与高度计沿轨观测数据比较发现, 就日平均统计来看, 同化较无同化使SWH分析值的均方根误差减小约25%～50%。以SWH 同化分析场作为初始场的预报表明, 同化对预报影响的时效性可延长至48～60 h。本研究目的是通过将高度计测量的SWH 数据同化到海浪模式进一步提升海浪数值预报的准确度。     

铜钴矿样品X荧光快速测定技术的初步研究

使用基于Si-PIN探测器和嵌入式计算机的便携式高能量分辨率X荧光(XRF)分析仪,对采自刚果(金)的铜钴矿样品进行测量。通过对实测数据的处理与分析,分含量段建立目标元素的工作曲线,同时求出相应的基体效应校正模型,并编制到仪器内置X荧光分析应用软件中。实现仪器根据实测多道微分谱线中相关元素的特征X射线计数率,自动切换工作曲线与基体效应修正模型,快速输出Cu和Co的含量的测定结果。通过与化学分析结果比较,快速测定结果精确度较高。     

钴的迁移形式成矿机理初探

通过对钴有关化合物的形成条件和理化性质,钴矿床矿物流体包裹体的化学成分、代表性钴矿物的化学成分、共、伴生矿物组合的探究,结合钴成矿地质背景和环境研究认为,钴的氢化物、合金氢化物、羰基化合物、羰基氢化物是内生钴的主要迁移形式。它们形成于地球深部高压、高温、富氢、富CO的强还原环境,通过断裂、裂隙随岩浆、热液迁移至地壳浅部,由于压力、温度骤降,氧逸度渐增、H2和CO逃逸、氧化,上述钴的化合物分解、氧化、硫化、砷化,沉淀富集形成内生钴矿床,并在以后地质事件中进一步叠加富集,形成更富更大的钴矿床。