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91.
The Stø Formation is the most important reservoir interval in the Norwegian Barents Sea, however the reservoir quality can be highly affected by the detrimental effects of quartz cement where there have been extensive post depositional burial. Core plug data from well 7219/8-2 in the Southwestern Barents Sea shows abnormally high porosity and permeability values in certain units of the deeply buried and otherwise highly quartz cemented Stø Formation. The amount of quartz cement in the samples is inversely proportional to the porosity. Samples with high and low porosities are similar texturally and mineralogically, but the high porosity samples have a layer of illitic clay coating the majority of the detrital quartz grains. Illitic clay coating present at grain contacts can result in a lowered IGV given they aid in the dissolution of quartz at interfaces, also creating a source of dissolved silica. Clay induced dissolution means that silica saturation is not a limiting factor in quartz cementation in these samples. The results show that the illitic clay coating is capable of limiting the amount of authigenic quartz overgrowth from 20 to 23% in samples with negligible grain coating to 5–11% in the intervals with high coating coverage. The illitic clay coating inhibits quartz overgrowth by limiting the surface area available for nucleation on detrital grains. The Stø Formation comprises mainly shallow marine deposits of highly reworked clean sandstone. Abnormally high porosities appear to be linked to settings where sediments of a more proximal location are preserved without extensive reworking. The grain coating clay is illitic and most likely originates from clay infiltration processes prior to final deposition. The difference in extent of clay coating in similar facies can mostly be correlated with varying amount of post depositional reworking. This study suggests that there is a potential for considerable porosity and permeability to be preserved in deeply buried sandstones in the Barents Sea. This study could be important in the future exploration activity of deeply buried structures in the area.  相似文献   
92.
深部地质钻探过程中,复杂的井下工况对钻具的钻探性能以及可靠性提出了苛刻的要求。钻具钢体表面涂覆具有耐磨耐蚀性的非晶涂层可以有效提高其服役寿命。其中Fe基非晶合金涂层因其优异的耐腐蚀抗磨损性能、较强的非晶形成能力等优势,具有重要的应用价值和较好的经济效益。本文通过大气等离子喷涂技术(Air Plasma Spray, APS)在35CrMo基体上制备得到成分为Fe48Cr15Mo14C15B6Y2 (at.%)的非晶合金涂层,并对其进行不同温度的真空热处理,探究了不同温度热处理对涂层基本性能和磨损失效机制的影响。结果表明:涂层经过真空热处理之后,生成的大量硬质相和成分均匀化使得涂层抗磨损性能提高;且随着热处理温度的提高,涂层磨损率逐渐减小。与未经热处理和750 ℃热处理的涂层相比,经过850 ℃热处理之后的涂层具有最佳的抗磨损性能,磨损率仅为未经热处理的Fe基非晶涂层的16.7%。热处理前后涂层的失效机制均为粘着磨损、磨粒磨损、疲劳磨损和氧化磨损。  相似文献   
93.
The surface of ZrO2 nanoparticles was modified by styrene coupling grafting method to improve the dispersion and interaction of the nanoparticles with the epoxy coating in which the modified ZrO2 nanoparticles were used as an additive. The grafting performance and microstructure of the nano- ZrO2/epoxy coating were analyzed by Fourier transformation infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. The corrosion behavior of the nano-ZrO2/epoxy coating on mild steel was evaluated in neutral 3.5 wt% NaC1 solution using electrochemical impedance spectroscopy (EIS). Both the coating capacitance and coating resistance fitted by the equivalent circuit from EIS were used to evaluate the protective performance of the coating towards the mild steel. The results show a superior stability and efficient corrosion protection by the modified ZrO2 nanoparticles. The epoxy coating containing 2 wt% modified ZrO2 nanoparticles exhibited the best corrosion performance among all the coating specimens. This research may provide an insight into the protection of mild steel using modified epoxy coatings.  相似文献   
94.
新型固相微萃取装置的研制及在有机磷农药检测中的应用   总被引:2,自引:2,他引:0  
使用有机磷农药引起的环境污染问题日益严重,建立针对水体中有机磷农药的快速、灵敏、准确的检测方法,具有重要意义。文章采用溶胶-凝胶法自制一种有机-无机杂化涂层固相微萃取(SPME)探头,探头涂层呈多孔状。同时取用廉价易得的气相色谱进样针,设计了一种新的SPME装置。研究了SPME-GC/MS同时测定环境水样中甲拌磷、乙拌磷、甲基对硫磷、对硫磷、水胺硫磷5种有机磷农药的分析方法。方法检出限为1.2~3.9 μg/L,相对标准偏差(RSD, n=6)为0.8%~7.4%。通过对实际样品的分析,方法加标回收率为93%~112%。建立的分析方法适合于环境水样中痕量有机磷农药的快速分析,具有一定的实用价值和应用前景。自制的有机-无机杂化涂层探头能重复使用达100余次,性能优于商用聚丙烯酸脂和聚二甲基硅氧烷涂层的萃取效果,通过更换探头,装置可重复使用。  相似文献   
95.
正Introduction The amount of the total dissolved salts(TDS)in most of the salt brines on northern Tibet is relatively lower.So the effective brine concentration technique is needed for lithium,boron and potassium extraction from these brine  相似文献   
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