Detecting subtle hydrochemical anomalies with multivariate statistics: an example from ‘homogeneous’ groundwaters in the Great Artesian Basin,Australia

The major ion composition of Great Artesian Basin groundwater in the lower Namoi River valley is relatively homogeneous in chemical composition. Traditional graphical techniques have been combined with multivariate statistical methods to determine whether subtle differences in the chemical composition of these waters can be delineated. Hierarchical cluster analysis and principal components analysis were successful in delineating minor variations within the groundwaters of the study area that were not visually identified in the graphical techniques applied. Hydrochemical interpretation allowed geochemical processes to be identified in each statistically defined water type and illustrated how these groundwaters differ from one another. Three main geochemical processes were identified in the groundwaters: ion exchange, precipitation, and mixing between waters from different sources. Both statistical methods delineated an anomalous sample suspected of being influenced by magmatic CO₂ input. The use of statistical methods to complement traditional graphical techniques for waters appearing homogeneous is emphasized for all investigations of this type. Copyright © 2006 John Wiley & Sons, Ltd.     

Kinetics of phosphate adsorption by iron oxyhydroxides in aqueous systems

The rate of uptake of phosphate onto synthetic Fe(III)- and Fe(II)-derived oxyhydroxides has been studied using reaction conditions similar to those encountered in natural waters. Kinetic analyses were carried out on the adsorption profiles and both first-order and second-order conditional rate constants were obtained. The temperature dependence of some of the rate constants was investigated and corresponding apparent activation energies calculated. Similar experiments and analyses were undertaken using Fe from natural sources and in general the conditional rate constants obtained in seawater were in agreement with the synthetic ones. The results of this study are of value when comparing the time scales of adsorption processes in natural waters with the time scales of mixing and advection.     

Low-frequency sea-level fluctuations along the coasts of Namibia and South Africa

Summary. Sea-level records at nine ports along the coasts of Namibia and South Africa are used to establish the existence of coastal trapped disturbances in sea-level as a response to the passage of synoptic weather systems. Using spectral analysis the characteristics and spatial variability of the sea-level fluctuations are identified. The results of cross-correlation analyses performed on sea-level data at adjacent ports for two periods during 1982 are discussed in detail to examine the propagation of coastal trapped waves round the coast.     

Chlorinated hydrocarbons in the seawater and surface sediments of Blanca Bay,Argentina

In order to characterize our study area and to provide reference values to be used in the future to measure the changes produced by an increase in contamination, the concentrations of chlorinated hydrocarbons have been investigated in fifty-one samples of seawater, taken at four different depths: air-sea interface, surface, one metre and bottom waters, and in twenty-three samples of surface sediments from Blanca Bay, Argentina. Of eleven organochlorine compounds we were looking for (α BHC, lindane, heptachlor, δ BHC. aldrin, heptachlor epoxide, dieldrin, o-p′DDD, p-p′DDD, o-p′DDT and p-p′DDT), seven could be detected in seawater and three in surface sediments with the following mean concentrations: α-BHC=48·2 ng l^?1; lindane=54·2 ng l^?1; heptachlor=45·0 ng l^?1; δ BHC=12·5 ng l^?1; aldrin=61·8 ng l^?1 and ΣDDT=67·0 ng l^?1; and δ BHC=3·2 ng g^?1; lindane=4·2 ng g^?1 and heptachlor=1·0 ng g^?1 for seawater, regarding the surface waters, and sediment samples, respectively.Concentration factors among the different water layers were also studied to see if there was any correlation between chlorinated hydrocarbon contents and the water depths from which the samples were taken. As a mean value, the air-sea interface water contains 18 times more of these compounds than that of the water near the bottom. A comparison of the values corresponding to seawater and surface sediments from our study area with those levels measured in samples from other geographic locations is also presented.With the purpose to detect a relationship between chlorinated hydrocarbon concentrations and the contents of particulate matter (PM) on the one hand, and particulate organic material (POM) on the other hand, four groups of samples containing different amounts of PM and POM, respectively were formed. From a comparison of the results obtained, lindane, heptachlor and δ BHC showed a tendency to lower concentrations in those samples containing little PM whereas α BHC and aldrin remained without important changes. No significant correlation was found between organochlorine levels and contents of POM.     

The hydrogeothermal basin of Sofia graben (Bulgaria)

Abstract In the Mesozoic basement and Neogene filling of Sofia tectonic graben a non-homogenous system of thermal water reservoirs connected to a united hydrogeothermal basin occurred. The basin contains and reproduces five types of low mineralized thermal waters and four types of mineralized thermal waters with exotic composition. The water temperatures are 30–80(90) ^°C. The total potential of the basin is assessed at 500 l/s thermal waters and 48 MWt thermal power. The utilization of thermal waters in the area of the Bulgarian capital has its roots and traditions in antiquity, and a promising future. The new town plan of Sofia provides construction of 35 centers for developing a versatile and prosperous hydrothermal business.     

New geomorphic evidence for anticlinal growth driven by blind-thrust faulting along the northern Marche coastal belt (central Italy)

The Northern Marche coastal belt is characterised by a series of NW-SE trending, NE verging folds forming the easternmost edge of the Apennines thrust front. Several geomorphic features suggest that the folds are still growing and hence that the thrust front is active. The occurrence of several historical and instrumental earthquakes (e.g. 1672, 1690, 1786, 1875, 1916, 1930, 1972, all having M_e 5.2) suggests that the thrust faults are also seismogenic.We performed a geomorphological analysis to identify and characterise the faults driving the active folds. Our approach assumes that anomalous drainage patterns and deformed Middle-Late Pleistocene alluvial and coastal terraces are indicators of the vertical component of tectonic strain. We identified, mapped and correlated with sea-level fluctuations a sequence of alluvial and coastal terraces. Longitudinal profiles of six rivers (Conca, Foglia, Metauro, Cesano, Misa, and Esino) show that terraces (1) consistently converge downstream, suggesting that they result from regional uplift that dies out near the coast, and (2) some are slightly warped where they cross anticline axes. We interpreted as coastal terraces several land-surface remnants arranged parallel to the present coastline. Lower remnants clearly top off gently landward-tilted coastal deposits. Reconstructed coastal terraces also seem to be tectonically warped.Our results help characterise the geometry and segmentation of a system that generated the largest earthquakes of the region and suggest the loci of potential seismic gaps. We conclude that the earthquake potential of the densely populated northern Marche coastal belt may be substantially higher than currently estimated.     

沿海港口自然灾害风险评价

以多灾种复合为背景,选取沿海城市中重要的基础设施——港口为研究区域,包括大连港、天津港、青岛港、上海港、宁波—舟山港、厦门港、深圳港、广州港,从危险性、暴露性和脆弱性等方面选取指标,探讨构建了沿海港口自然灾害风险评价指标体系与评估模型:评价结果为:沿海港口的灾害风险指数相差较大,风险值在空间上表现出长江三角洲沿岸>珠江三角洲沿岸>环渤海沿岸:评价结果可以为沿海港口防灾减灾提供理论依据。     

Observations on decadal sandbar behaviour along a large-scale curved shoreline

Nearshore sandbars are characteristic features of sandy surf zones and have been observed with a variety of geometries in cross-shore (e.g. location) and longshore direction (e.g. planform). Although the behaviour of sandbars has been studied extensively on spatial scales up to kilometres and timescales up to years, it remains challenging to observe and explain their behaviour on larger spatial and temporal scales, especially in locations where coastline curvature can be prominent. In this paper, we study a data set with 38 years of coastal profiles, collected with alongshore intervals of 50 m, along the 34 km-long curved sandy shoreline of Sylt island, Germany. Sylt's shoreline has an orientation difference of ~20° between the northern and southern half of the island. We found that the decadal coastal profiles on the southern half show features of a low-tide terrace and a sandbar located further from the shoreline (~441 m). On the nothern half, the sandbar was located closer to the shoreline (~267 m) and was less pronounced, while the profiles show transverse bar and rip features. The alongshore planform also differed systematically and significantly along the two island sides. The sandbar on the southern island half, with alongshore periodicity on a larger length scale (~2240 m), was coupled out-of-phase to the shoreline, while no phase coupling was observed for the sandbar with periodicity on a shorter length scale (~670 m) on the northern half. We related the observed geometric differences of the sandbars to the difference in the local wave climate along Sylt, imposed by the shoreline shape. Our observations imply that small alongshore variations in wave climate, due to the increasing shoreline curvature on larger spatial scales, can lead to significant alongshore differences in the decadal evolution of coastal profiles, sandbars and shorelines. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

地震活动性参数b值和年发生率的一种取值方法

介绍了一种将历史地震与现代小震统计结果相协调,去不可靠或不稳定数据段确定地震活动性参数ｂ值,以及通过不同震级下限地震频度的时间滑动分析,选取现今与历史相近,且具较高震级下限的统计结果,推算４级以上地震年发生度ｖ４的方法。计算给出了东南沿海地震带及其南带,北带的ｂ值和ｖ４值。