地铁施工对济南白泉泉群流量的影响

为研究地铁建设对济南白泉泉群的影响，在综合分析白泉泉域地质、水文地质条件的基础上，假定研究区岩溶强径流带位置及水力性质，利用FEFLOW软件建立地下水流数值模型。以规划地铁M1号线为研究对象，分析了济南东站、梁王站、梁王东站分别施工及3个站同时施工4种情景下，采用施工降水或施工降水+人工回灌两种施工方式对白泉泉群流量的影响。结果表明：单独采用施工降水的施工方式使得白泉泉群流量衰减，其中3个站同时施工对泉流量的影响最大，泉流量最大衰减达5.48%；各站分别施工时，济南东站对泉流量影响最大，泉流量较未施工时减少了0.043×10⁴ m³/d。采用施工降水+人工回灌的施工方式，能够有效缓解泉流量的衰减，各车站施工时的泉流量衰减由仅施工降水时的2.26%~5.48%降低至0.08%~1.21%。岩溶强径流带有利于地下水形成优势径流，促进白泉泉群补给，一定程度上缓解因地铁施工引起的泉流量衰减。     

Organic contaminants and characteristics of sediments from Oso Bay,south Texas,USA

The Oso Bay, Texas, sediments from nine sites were analyzed by GC-MS for organics to measure contamination in the bay. In most of the sites sediments contained tetrachloroethene (87–1433 g/kg), bis (2-ethylhexyl)phthalate (40–193 g/kg), and aliphatic hydrocarbons, C₈-C₁₃ (720–2491 g/kg). Sources of these contaminants include a landfill, military facilities, and municipal and industrial discharges. Size analysis of the sediments indicates they contain a high percentage of muddy sand (50–75 percent), which suggests that Oso Bay consists of common bay margin sediments.     

Environmental impacts from mining at Taojiang Mn ore deposit, central Hunan, China

The Taojiang Mn ore deposit was exploited in the early 1960s, and waste rocks were developed since then. Because the Mn ores were hosted within the metal-enriched black shales （Peng et al., 2004）, the continuous mining has led to the exposure of an immense quality of black shales, which might cause serious impacts on environments. The present study deals with this environmental issue with samples from the waste rocks, and from the surrounding soils and surface water. The mineralogy of the waste rock was studied using EMPA, then a large number of elements in all waste rock, soil, and water samples were analyzed at a wide range of concentrations with high accuracy using an Elan6000 ICP-MS machine at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences. The waste rock is composed mostly of black shales, with minor Mn carbonates. Both black shales and Mn carbonates of the waste rock contain many sulfide minerals, mainly pyrite, with minor galena, sphalerite, chalcopyrite, and others. The waste rocks are enriched in many metals including Sc, V, Cr, Co, Ni, Fe, Mn, Cu, Zn, Pb, Th, U, Mo, Sb, Sn, Tl, and others, and the metals are mostly hosted within the sulfides. Weathering of waste rocks might cause emission of the following metals： V, Cd, Ni, Th, U, Mo, Sb, Tl, Sc, Cr, Cu, Zn, Sn, and minor Co, and Pb. The surrounding soils are highly enriched in Cr, Co, Cu, Zn, Mn, Mo, Cd, Tl, and Pb, with the enrichment factors of 2.67.3.8, 7.26, 7.27, 8.2, 5.7, 13, and 5.4, respectively. The element ratios （Rb/Cs, Fe/Mn, Nb/Zr, Hf/Zr, and Ba/Sr） and REE distribution patterns of the soils are similar to those of the waste rocks and bedrocks.     

Studies on environment protection of vanadium exploitation in open air

Vanadium, improving mechanism and jointing capacity of steel products, is a kind of excellent additive during steel-making and its industry gets support from national industry policy. On account of shallow buried depth and low technique request of exploitation, there is much exploitation by local people lacking system management and technique guidance in area rich in vanadium since years ago, which damages regional environment dramatically. Accordingly, taking stone coal-vanadium as an example, the paper focuses on environment impact on water environment and eco-environment caused by exploitation in open air. Impact of exploitation on surface water mainly includes mining drainage and eluviated water of stock yard. According to civilian exploitation in the area, the rock suffers man-made disturbance, therefore, water quality indicators of mining drainage like heavy metal, permanganate, CI, SO4^2-, F are able to be analogies of ground water quantity in the region since the primary component of drainage is surrounding rock ground water. Water monitoring result of local well shows as follows： pH 6.68, SO4^2- 5.76 mg/L, F- 0.005 mg/L, Fe 0.025 mg/L, Mo 8.08 μg/L, Ni 5.91 μg/L, Co 0.61 μg/L, and all of them reach corresponding standard of water quality. Ground water turns into acid mine water by oxygenation after it discharges and with the help of sulfur the acid water contains nocuous elements which permeate in groundwater and surface water arousing pollution. The value of pH in the range of standard indicates that the acidification of mine water is relatively weak in the diggings. Eco-environment damage is another aspect that cannot be ignored, it acts as： （1） peeling work and establishment construction destroy landform; （2） stack of waste soil and rock occupies amounts of land; （3） various exploitation activities like vegetation peeling, landform change will enlarge the scope or enhance the intensity of soil erosion, which destroys eco-environment by leading water and soil loss;     

Mobility of heavy metals from tailings to stream waters in local zinc smelting activities contaminated site

It has been found that stream waters were severely contaminated with wastes from a long-time smelting factory in Hezhang, Guizhou, China. The main sources of contamination are the smelting wastes stored in the open air and abandoned in the vicinity of stream. A method of lead isotope was adopted in order to identify relations between tailings and water contamination. Representative samples of tailings and stream sediments were collected. Mineralogical characterizations were conducted using XRD and TEM/SEM, while acid digestion was carried out for determining metal contents. BCR sequential leaching tests were performed in order to assess metal mobility. The tremendous ‘actual＇ and ‘potential＇ mobility of heavy metals indicates that the smelting waste and stream sediments present a considerable threat to the environment. Besides the chemical remobilization of heavy metals from the sediments and the reworking of riverbed sediments act as a secondary source of pollution. Also groundwater and stream water were sampled in specific locations and were measured.     

Permeable Reactive Barrier for the treatment of contaminated surface water in Katedan industrial development area, Hyderabad, India

Permeable Reactive Barrier （PRB） is an emplacement of inert material （s） in the subsurface, designed to intercept a contaminated plume, provides a preferential flow path through the reactive media, and transforms the contaminant into environmentally acceptable forms to attain concentration remediation goals at the discharge of the barrier. The phenomena, which help in remediation within PRB, are adsorption/sorption, precipitation, oxidation/reduction and biodegradation. Various materials like zero-valent iron, zero-valent bi-metals, natural zeolites, organic carbon, fly ash, zeolites, limestone, activated alumina, apatites, etc. have been tried by many researchers to remove organic and inorganic contaminants. In USA, Canada, and many European countries commercial full-scale and pilot scale PRBs are successfully working. The design and installation of full scale PRBs needs laboratory treatability and dynamic flow column experiments？ The concept of PRB is being applied to treat contaminated surface water in the Katedan industrial area, Hyderabad, India. National Geophysical Research Institute （NGRI）, Hyderabad, India, conducted systematic studies in collaboration with Norwegian Geotechnical Institute （NGI）, Norway, to develop PRB technique to decontaminate the surface water pollution due to industrial effluent. A site assessment study in the Katedan Industrial Area, were carried out and water, soil and sediment from the lakes of the area were found to be polluted with high concentrations of heavy metals like As, Pb, Cr, Cd, Ni, etc. Adsorption studies at NGRI with synthetic samples and in-situ industrial effluent using different reactive media for removing contaminants like arsenic, chromium, cadmium, copper, nickel, lead and zinc have been carried out and yielded satisfactory results. The performance of zero-valent iron and limestone is encouraging in removing As,     

Is the spring water responsible for the fossilization of faunal remains at Florisbad, South Africa?

It is has been suggested that faunal remains at Florisbad were fossilized in a spring context due to the mineralized spring water. However, the environment conducive to the precipitation of CaCO₃ and other authigenic minerals was formed largely through the salinization of the organic layers and clay, and the mineralization of the groundwater. Factors contributing to this favorable environment include: CaCO₃ saturation, pH, the decomposition of halophytes, Eh, rainfall, biomineralization, and aeolian deposition. With the exception of pH, none of the above factors feature in a spring context, with evidence suggesting that the spring water may historically never have carried sufficient minerals for fossilization, and that contact with the spring water may actually have resulted in the demineralization of previously fossilized material. In light of this evidence, it is concluded that the fossilization of faunal remains at Florisbad took place in a sedimentary organic matter and clay environment and could not have taken place in the spring vents where there is an undersaturation of Ca.     

Study of geothermal water intrusion due to groundwater exploitation in the Puebla Valley aquifer system, Mexico

Significant intrusion of geothermal water into fresh groundwater takes place in the Puebla Valley aquifer system, Mexico. The decline in the potentiometric surface due to the overexploitation of the groundwater induces this intrusion. This hydrological system comprises three aquifers located in Plio-Quaternary volcanic sediments and Mesozoic calcareous rocks. The hydraulic balance of the aquifer shows that the annual output exceeds the natural inputs by 12 million m³. Between 1973 and 2002, a drop in the potentiometric surface, with an 80 m cone of depression, was identified in a 5-km-wide area located southwest of the city of Puebla. Chemical analyses performed on water samples since 1990 have shown an increase in total dissolved solids (TDS) of more than 500 mg/L, coinciding with the region showing a cone of depression in the potentiometric surface. A three-dimensional flow and transport model, based on the hydrogeological and geophysical studies, was computed by using the MODFLOW and MT3D software. This model reproduces the evolution of the aquifer system during the last 30 years and predicts for 2010 an additional drawdown in the potentiometric surface of 15 m, and an increase in the geothermal water intrusion.     

Characterization of water bursting and discharge into underground mines with multilayered groundwater flow systems in the North China coal basin

A conceptual framework for characterization of water bursting and discharge into underground mines with multilayered groundwater flow systems is presented, based on the features of the site conditions and analyses of the water bursting and mine inundation events of the North China coal basin. Comprehensive analyses of the hydrogeological conditions for establishment of the three-dimensional groundwater flow systems of the North China coal basin revealed different vertical hydraulic connection paths or channels. These connections include karst collapse columns, fault or fracture zones, buried weathering zones, and fracture networks in aquitards, within the multilayered groundwater flow systems. Also examined, was the effect of the primary features of the flow system and those different connection paths on water bursting and discharge into the underground coal mines. It was demonstrated that appropriately identifying and adequately understanding the three-dimensional multilayered groundwater flow systems and those various vertical hydraulic connection mechanisms are critical for appropriately preventing water bursting hazards and predicting water discharge into underground mines. A valuable guideline is presented on characterization of water bursting and discharge into underground mines with multilayered groundwater flow systems.

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Resumen Un cadre de travail conceptuel pour la caractérisation du jaillissement et de la vidange des eaux dans les mines à plusieurs niveaux d'écoulement est présenté, basé sur les conditions et l'analyse sur site du jaillissement des eaux et des inondations dans les bassins charbonneux du Nord de la Chine. L'analyse compréhensive des conditions hydrogéologiques des systèmes d'écoulement tridimensionnel de ces bassins, révèle des trajets ou des chenaux qui sont autant de connections hydrauliques verticales. Ces connections comprennent des effondrement karstiques en colonne, des zones de fractures et de failles, des zones d'altération, des réseaux de fractures dans les aquitards, dans le système hydrogéologique multicouche. L'influence des caractéristiques primaires du système d'écoulement et de ces différentes connections sur le jaillissement et la vidange dans les mines, est également examiné. Il a été démontré que l'identification appropriée et la compréhension adéquate du système d'écoulement souterrain multicouche et tridimensionnel, et des mécanismes variés de connection hydraulique verticale est critiquée pour prévenir de manière appropriée les risques de jaillissement et de vidange dans les mines. Des guidelines valorisables sont présentées, pour la caractérisation du jaillissement et de la vidange dans de tels systèmes.

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Résumé Se presenta un marco conceptual para la de caracterización de la despresurización y descarga de agua a minas subterráneas con sistemas de acuíferos de múltiples niveles, el cual se basa en las condiciones del sitio, análisis de la despresurización de agua e inundaciones de minas en la cuenca de carbón del norte de la China.Un análisis comprehensivo de las condiciones hidrogeológicas para el establecimiento de los sistemas de flujo de agua de tri-dimensionales en la cuenca de carbón del norte de la China ha revelado diferentes canales hidráulicos verticales. Estas conexiones incluyen columnas de karst colapsadas, fallas o zonas de fracturas, zonas de regalita hundida y redes de fracturas en zonas de poca permeabilidad dentro de los sistemas de flujo de múltiples niveles.También se investigó el efecto de los rasgos primarios del sistema de flujo y los diferentes canales conectivos sobre la despresurización y descarga de agua a minas subterráneas. Se demostró que el entendimiento e identificación adecuada de los sistemas de acuíferos de múltiples niveles en tres dimensiones es crítico para prevenir apropiadamente la despresurización y descarga de agua a minas subterráneas. Se presentan lineamientos valiosos en relación con la despresurización y descarga de agua a minas subterráneas en sistemas de flujo de múltiple nivel.

     

Damage Survey of Water Supply Systems and Fragility Curve of PVC Water Pipelines in the Chi–Chi Taiwan Earthquake

Substantial damage to water supply systems, including water delivery pipelines, water treatment plants, reservoirs, and water storage tanks, was reported after the 1999 Chi–Chi Taiwan Earthquake. This paper first summarizes the damage survey and then presents the results of seismic fragility analysis for underground pipelines. Construction blueprints of the water delivery pipelines and repair work orders of 11 townships and cities in the disastrous area were digitized into a Geographical Information System (GIS) for analysis and assessment. With the aid of the GIS system, we found that PVC pipes made up 86% of water delivery pipelines while steel, cast iron, ductile iron, PE and others took the rest. Therefore, this paper focuses on the fragility analysis of PVC pipes. Three different methods were applied to derive the fragility relations between the PVC water pipes having nominal diameters (approximately inner diameters) greater than or equal to 65 mm and earthquake intensity parameters such as peak ground acceleration and peak ground velocity. The results were then examined with those of other countries. The discrepancy between our results and the empirical equation used by HAZUS, an earthquake loss estimation software developed by the Federal Emergency Management Agency was not significant.