注入CO2提高煤层气产能的可行性研究

根据煤储层吸附一解吸机理,首次采用“解吸一注气一解吸”的实验方法,分别进行CH4,CO2的吸附一解吸和CO2注入置换煤层CH4实验,模拟了煤层气井“排采一注气一排采”的增产途径和效果。结果表明：在CH4和CO2二元体系的竞争吸附中,CO2组分的吸附速率是先快后慢,而CH4组分的吸附速率先慢后快,解吸时则相反,反映出CO2在竞争吸附中占据优势;注入CO2气体的数量越大和相对浓度越高,单位压降CH4解吸率和CO2吸附率就越高。实验结论对工业规模的煤层气开发试验具有指导意义。     

彬长矿区水文地质特征及其对煤层气的控制作用

对彬长矿区水文地质特征进行了详细的论述,结合煤层实测含气性特征,探讨了水文地质条件对该区煤层气成藏的控制作用。研究表明:研究区构造简单,延安组煤系含水层与其他含水层不具明显水力联系,有利于煤层气富集成藏,同时使得煤系含水层地下水补给只能来源于区外侧向径流补给;矿区划分为3个水动力强弱不同的区域:侧向径流补给区、弱径流区和相对滞流区,其中位于矿区东南部的相对滞流区,也是水势低洼带煤层气汇集区,有利于煤层的富集成藏。同时,东南部煤层的含气量最高,说明该区水文地质条件确实对煤层气成藏起着关键作用。      

水平井开采煤层气藏生产动态计算新数学模型

基于朗格缪尔模型、菲克第二扩散定律和达西定律,综合考虑重力和气体压缩效应的影响,推导出描述煤层气和水渗流规律的基本偏微分方程组(并给出定解条件),且利用有限差分法对该数学模型进行了数值求解。计算结果表明,该模型能够有效模拟煤层气水平井的生产动态。通过对比是否考虑非稳态扩散和气体压缩效应时不同裂隙渗透率下的产气动态可知,忽略非稳态扩散和压缩效应,将人为缩短达到气体峰值产量的时间,增大产气峰值;将降低气体膨胀能,低估气井后期产能。煤岩裂隙渗透率越高,气井产能受渗透率回归效应影响越大,峰值产量的持续时间越短且产量下降速度快。因此在煤层气藏开采过程中,应根据气井的产气动态调整井底流压,建立合理的储层压力系统,以降低渗透率回归效应带来的不利影响。      

煤层气产出过程中气—水两相流与煤岩变形耦合数学模型研究

气－水二相流和煤岩变形耦合作用是煤层气产出过程中一种复杂的物理现象，为准确描述这一现象，本文建立了气－水二相流和煤岩变形的微分方程，并用有限元分别将它们进行离散化，然后讨论了煤岩变形模型和气－水二相流模型进行耦合数值求解的方法。     

中国煤层气有利区带综合评价

煤层气含气区带综合评价是一个多因素、多层次、多目标的决策过程,其评价过程受到诸多因素的影响,需要选择科学、简捷、实用的数学模型来分析处理这些繁杂因素。因此,根据煤层气含气区带综合评价涉及的各种因素建立评价指标体系,并结合层次分析法和灰聚类分析各自的优点,建立煤层气含气区带综合评价模型。应用层次分析法确定各指标的权系数,然后通过灰聚类分析法来进行综合评价,较好地保证了权系数的客观性和准确性,定性、定量地对煤层气含气区带进行综合评价。可以为整个煤层气行业的资源综合评价奠定基础,同时通过评价案例进行了验证。评价结果表明,全国121个煤层气含气区带中,最有利区带是沁水盆地和鄂尔多斯盆地东缘,有利区带为鄂尔多斯盆地南缘、宁武、安阳-鹤壁和松藻地区。     

欠平衡钻井技术在煤层气勘探开发中的应用

分析了当前国内外开发利用煤层气的现状；指出中国煤层气气藏具有低压低渗、难脱附、驱动力不足和构造煤发育等重要特殊性，这种特殊性使常规煤层气开发技术有很大的局限性；提出了适合低压低煤层气藏特点的开发技术系列，包括欠平衡钻井与洞穴完井技术和欠平衡钻多分支水平井与洞穴技术。     

煤层气在煤储层中的扩散及其影响因素

煤层气在煤储层中的扩散是指从煤基质孔隙表面上解吸的煤层气运移到割理系统的主要过程。发生扩散的前提条件是气体浓度差的出现，衡量扩散能力大小的重要参数是扩散系数。前者为由解吸速度、解吸气量和煤层气产量、井孔压力降等因素控制的动态参数，而后者为主要受扩散物质性质、扩散介质特征、扩散系统的温度、压力和孔隙结构形态等因素影响的静态参数。煤层气在煤储层中的扩散量与煤层气浓度差和扩散系数呈正比关系。     

沁南地区煤层气生产潜力研究

本文以沁水盆地南部地区煤层气生产试验井的徘采资料为基础，结合煤田地质勘探和中联公司煤层气勘探所获得的地质、生产资料，阐述了煤层气井的排采机理。并以TL—003井排采试验为例进行详细剖析，运用储层模拟技术，研究、分析影响煤层气产出的主要参数，初步预测了该区煤层气井的生产潜力。     

Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing‐Shenfu Area

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.     

煤层气富集高产的主控因素

对煤岩的生储气能力、煤储层渗透率、煤层气保存条件等影响煤层气高产富集的主控因素进行了分析。煤岩组分和煤变质程度是影响煤层生储气能力的主控因素。煤层的储气能力与温度、压力、灰分及水分含量等亦有关。煤层的渗透率取决于煤层本身的裂隙系统,而裂隙的发育程度又与煤变质程度及构造活动的强弱相关。煤层气的保存则取决于顶底板的封盖能力、构造活动、水动力环境等条件。煤层气成藏条件是煤层气基础地质研究中的核心问题,应加强研究。