陕西彬县大佛寺D4钻孔勘察地球化学研究

运用烃类勘察地球化学方法，对鄂尔多斯盆地南部彬县大佛寺井田钻遇中休罗统煤层的耽钻孔，进行了垂向剖面多指标的综合地球化学研究。结果表明：剖面中所有岩样中的烃类物质均为热解烃生成初期演化阶段的煤成烃产物，具明显的同一性；由煤层至地表黄土，所有岩样中的烃类呈明显的、规律性垂直向上运移。这证实地下煤层烃类在近地表具有很好的地球化学信息显示，利用勘察地球化学方法找煤／煤层气是可行的。     

内蒙古胜利煤田共生锗矿的成因地球化学初探

用统计和作图的分析方法,对内蒙古胜利煤田中共生锗矿床的锗品位与挥发分、灰分、硫分的关系进行了研究。结果表明煤中锗品位与挥发分呈正相关、与原煤灰分负相关、与洗煤灰分正相关关系;全区煤属中硫煤,锗品位与原煤和洗煤硫分均呈正相关关系,煤的灰分指数较低(3 579);锗分布不均匀,富锗煤矿明显属于断裂坳陷边缘沉积,锗品位可以在煤层的顶部、中部、底部同时或单个部位呈现高值,大多数煤层中部出现锗高品位值,这有别于以往所报道的锗品位只在煤层顶、底部相对富集的研究结论。认为胜利煤田锗主要与有机质结合;锗的有利聚集条件是水动力较弱、地下水位较低、强还原的停滞沼泽环境;泥炭聚集阶段有机质的吸附作用是锗的主要富集机制。     

水化学指标表示裘布依公式的应用

从多矿物溶解化学动力学方程出发,推演并建立了由水化学指标表示的承压二维井流裘布依公式。结合水文地质、水文地球化学特征,列举了水文地质单元内不同区带、各种代表性矿物及相应组分化学指标的基本表达式。以山西省太原西峪煤矿所需解决的水文地质问题为例进行了定量研究与评价,其结果与已有的抽水试验资料接近,为矿井涌水量的评价开辟了一条新的道路。从事实上进一步论证了水化学指标表示裘布依公式的理论概括是正确的。     

京珠高速公路小塘至甘塘段煤系地层路堑高边坡稳定性分析与防治

京珠高速公路粤境小塘至甘塘段20m以上高度的煤系地层路堑边坡共计11处。岩层以全—强风化层为主,厚度20～40m,其物理力学性质大大降低,边坡可能发生平面破坏和圆弧破坏等2种破坏模式。部分地下水水质中SO2-4含量大于200mg l,具有强烈的硫酸盐侵蚀性。边坡防治对策应在详细勘察工程地质、水文地质的基础上,合理选用设置山坡截水沟、平台截水沟、泄水洞、边坡渗沟、排水仰孔等防、排水措施,减少地表水渗入坡体,疏干边坡表层地下水。     

Synthesis of zeolites using fly ash and their application in removing heavy metals from waters

Fly ash is the solid waste of thermal power plants where coal is used as fuel, and its management and utilization have been of environmental concern for decades. Since the technique of synthesizing zeolite from coal fly ash was introduced by Holler[1] (19…     

Architecture of coastal and alluvial deposits in an extensional basin: the Carboniferous Joggins Formation of eastern Canada

Abstract The Joggins Formation was deposited in the Cumberland Basin, which experienced rapid mid‐Carboniferous subsidence on bounding faults. A 600 m measured section of coastal and alluvial plain strata comprises cycles tens to hundreds of metres thick. The cycles commence with coal and fossiliferous limestone/siltstone intervals, interpreted as widespread flooding events. These intervals are overlain by coarsening‐upward successions capped by planar‐based sandstone mounds, up to 100 m in width that represent the progradation of small, river‐generated delta lobes into a standing body of open water developed during transgression. The overlying strata contain sand‐rich heterolithic packages, 1–8 m thick, that are associated with channel bodies 2–3 m thick and 10–50 m wide. Drifted plant debris, Calamites groves and erect lycopsid trees are preserved within these predominantly green‐grey heterolithic sediments, which were deposited on a coastal wetland or deltaic plain traversed by channel systems. The cycles conclude with red siltstones, containing calcareous nodules, that are interbedded with thin sandstones and associated with both single‐storey channel bodies (1–1·5 m thick and 2–3 m wide) and larger, multistorey channels (3–6 m thick) with incised margins. Numerous channel bodies at the same level suggest that multiple‐channel, anastomosed river systems were developed on a well‐drained floodplain. Many minor flooding surfaces divide the strata into parasequences with dominantly progradational and aggradational stacking patterns. Multistorey channel bodies are relatively thin, fine grained and modestly incised, and palaeosols are immature and cumulative. The abundance and prominence of flooding surfaces suggests that base‐level rise was enhanced, whereas the lack of evidence for abrupt basinward stepping of facies belts, coupled with the absence of strong fluvial incision and mature palaeosols, suggests that base‐level fall was suppressed. These architectural features are considered to reflect a tectonic architectural signature, in accordance with the high‐subsidence basinal setting. Evidence for restricted marine influence and variation in floral assemblages suggests modulation by eustatic and climatic effects, although their relative importance is uncertain.     

济宁二号矿孤岛工作面冲击矿压危险及其控制

孤岛工作面及其周围巷道附近应力集中程度高,顶板运动剧烈,再加上地质构造的影响,采深较大时,冲击危险程度就高,很容易引发冲击矿压。《煤矿安全规程》要求孤岛工作面按冲击矿压危险工作面来管理。孤岛工作面冲击矿压危险检测预报及控制的技术是先分析冲击危险程度,确定冲击危险指数,提出早期预报;采用电磁辐射和钻屑法进行及时预报;采用卸压爆破进行处理,并采用电磁辐射和钻屑法检验防治措施的效果。实践证明,这套技术安全、可靠、有效,能够保证工作面的安全高效生产。     

煤层上覆地层含水不均匀性电法探测的可能性

煤田上覆岩层中含水直接对煤层的开采构成威胁，本文先从理论上阐述了电阻率勘探可以探测煤层上覆地层含水不均匀性的可能性，然后用简单的断层型薄层含水模型的CSAMT正演模拟结果展示出：地下900m深处，尽管只有20m厚的的含水岩层，但在电阻率剖面上该薄层的反映具有非常明显的特征，从理论上和数值模拟实例说明，一定深度内一定厚度的薄层含水性的电阻率法探测是可能的。     

Striking liptinitic bark remains peculiar to some Late Permian Chinese coals

An unusual liptinite coal component has been reported in the Chinese literature over the past sixty years. It has been described as a maceral in the Chinese National Standard (1991), but it has not been named internationally. In Chinese literature it is called “barkinite”, on the basis of its morphological features and because it is believed to have originated as bark tissue.“Barkinite” occurs in Late Permian, marine-influenced coals and is best represented in the Changguang, Leping and Shuicheng Basins of southern China.The material originates from plant periderm or the bark of higher plants. However, “bark” contains a variety of substances, including resin and suberin, which are recognised as the precursors of the resinite and suberinite macerals. “Barkinite” is distinguished by (i) its thickness; individual pieces can be more than ten cells thick and several centimetres long and (ii) it fluoresces strongly at 0.6% vitrinite reflectance and loses its fluorescence at about 1.1% vitrinite reflectance.The reporting of “barkinite” from only Chinese coals may be due to its origin from Lepidodendron and Psaronius flora, which was common in the Northern Hemisphere during the Carboniferous, but which was isolated to China by the Late Permian. It is proposed that the remnant flora evolved into unique forms in China by the Late Permian. Lepidodendron and Psaronius remains, coupled with a strongly marine-influenced, peat-forming environment have given rise to “barkinite” and to its restricted distribution.     

Groundwater transformation of a low-sulfur to a high-sulfur coal, the Harlem coal of the northern Appalachian basin

The Harlem coal is postulated to have been deposited in raised-bog settings. It was initially deposited as low-sulfur peat, but groundwater of a later origin altered portions of it to high-sulfur coal. The total sulfur content of 172 samples from 31 locations on a moisture- and ash-free basis have a quadrimodal distribution with two major modes at 0.75% S and 2.0%S. Multiple sampling and analyses at specific mine sites indicate that the addition of sulfur of a later origin occurred either laterally adjacent to sandstone channels or vertically adjacent to faults. Significant sulfur addition also occurred above clay partings at these sites. The original low-sulfur nature is preserved where the coal bed is isolated from descending groundwater by a thick impervious layer. Trace-element analyses show high concentrations of mobile elements such as Na and Mn in the high-sulfur coals.