Determination of potential hazardous elements in Can coals （Canakkale- Turkey）-I

It is known that the increasing use of coal as an energy source led to the growing environmental and health problems. But comprehensive knowledge of coal quality parameters may help to reduce some of these problems. The Canakkale-Can coalfield is located in the western part of Turkey, whose reserves are estimated at 69.3 billion tons, mainly used in the industry in the neighboring areas, specifically for the Can Thermal Power Plant. The aim of this study is to determine the coal quality parameters and examine the origin and distributions of potentially toxic trace elements in lignite which may produce environmental and health hazards in the area. The coal samples were collected from different parts of the coalfield in Can. Proximate and ultimate analyses, sulfur form analyses, X-ray powder diffraction （XRD）, inductively coupled plasma-mass spectrometry （ICP-MS）, and scanning electron microscopy （SEM） were performed on those samples to determine the geochemical profile of hazardous elements.     

Early Jurassic rift structures associated with the Soapaga and Boyacá faults of the Eastern Cordillera, Colombia: Sedimentological inferences and regional implications

The NW-trending Bucaramanga fault links, at its southern termination, with the Soapaga and Boyacá faults, which by their NW trend define an ample horsetail structure. As a result of their Neogene reactivation as reverse faults, they bound fault-related anticlines that expose the sedimentary fill of two Early Jurassic rift basins. These sediments exhibit the wedge-like geometry of rift fills related to west-facing normal faults. Their structural setting was controlled further by segmentation of the bounding faults at approximately 10 km intervals, in which each segment is separated by a transverse basement high. Isopach contours and different facies associations suggest these transverse anticlines may have separated depocenters of their adjacent subbasins, which were shaped by a slightly different subsidence history and thereby decoupled. The basin fill of the relatively narrow basin associated with the Soapaga fault is dominated by fanglomeratic successions organized in two coarsening-upward cycles. In the larger basin linked to the Boyacá fault, the sedimentary fill consists of two coarsening-upward sequences that, when fully developed, vary from floodplain to alluvial fan deposits. These Early Jurassic rift fills temporally constrain the evolution of the Bucaramanga fault, which accommodated right-lateral displacement during the early Mesozoic rift event.     

Petrofacies, provenance and diagenesis of the dhosa sandstone member (Chari Formation) at Ler, Kachchh sub-basin, Western India

The sandstones of the Dhosa Sandstone Member of Late Callovian and Early Oxfordian age exposed at Ler have been analyzed for their petrofacies, provenance, tectonic setting and diagenetic history. These sandstones are fine to medium grained and poorly- to well sorted. The constituent mineral grains are subangular to subrounded. These sandstones were derived from a mixed provenance including granites, granite–gneisses, low- and high-grade metamorphic and some basic rocks of the Aravalli Range and Nagarparkar Massif. The petrofacies analysis reveals that these sandstones belong to the continental block-, recycled orogen- and rifted continental margin tectonic regime.The imprints of early and deep burial diagenesis of these sandstones include different stages of compaction, cementation, change in crystal boundaries, cement–cement boundaries, chertification and neomorphism. The sequence of cementation includes precipitation of calcite and its subsequent replacement by Fe calcite and silica cements. The typical intermediate burial (2–3 km depth) diagenetic signatures of these sandstones are reflected in the formation of suture and straight-line boundaries, and triple junctions with straight-line boundaries. The depositional environment, relatively low-energy environment that was below storm wave base but subjected to gentle currents, of the Dhosa Sandstone Member controlled the early diagenesis, which in turn influenced the burial diagenesis of these sandstones.     

A sequence stratigraphic model for an intensely bioturbated shallow-marine sandstone: the Bridport Sand Formation, Wessex Basin, UK

The Bridport Sand Formation is an intensely bioturbated sandstone that represents part of a mixed siliciclastic‐carbonate shallow‐marine depositional system. At outcrop and in subsurface cores, conventional facies analysis was combined with ichnofabric analysis to identify facies successions bounded by a hierarchy of key stratigraphic surfaces. The geometry of these surfaces and the lateral relationships between the facies successions that they bound have been constrained locally using 3D seismic data. Facies analysis suggests that the Bridport Sand Formation represents progradation of a low‐energy, siliciclastic shoreface dominated by storm‐event beds reworked by bioturbation. The shoreface sandstones form the upper part of a thick (up to 200 m), steep (2–3°), mud‐dominated slope that extends into the underlying Down Cliff Clay. Clinoform surfaces representing the shoreface‐slope system are grouped into progradational sets. Each set contains clinoform surfaces arranged in a downstepping, offlapping manner that indicates forced‐regressive progradation, which was punctuated by flooding surfaces that are expressed in core and well‐log data. In proximal locations, progradational shoreface sandstones (corresponding to a clinoform set) are truncated by conglomerate lags containing clasts of bored, reworked shoreface sandstones, which are interpreted as marking sequence boundaries. In medial locations, progradational clinoform sets are overlain across an erosion surface by thin (<5 m) bioclastic limestones that record siliciclastic‐sediment starvation during transgression. Near the basin margins, these limestones are locally thick (>10 m) and overlie conglomerate lags at sequence boundaries. Sequence boundaries are thus interpreted as being amalgamated with overlying transgressive surfaces, to form composite erosion surfaces. In distal locations, oolitic ironstones that formed under conditions of extended physical reworking overlie composite sequence boundaries and transgressive surfaces. Over most of the Wessex Basin, clinoform sets (corresponding to high‐frequency sequences) are laterally offset, thus defining a low‐frequency sequence architecture characterized by high net siliciclastic sediment input and low net accommodation. Aggradational stacking of high‐frequency sequences occurs in fault‐bounded depocentres which had higher rates of localized tectonic subsidence.     

复合土钉墙支护技术在某大型软土基坑围护中的应用

根据拟建建筑基坑的工程地质条件、周边环境条件、基坑开挖深度等特点综合考虑，对基坑分段采用超前微型桩支护加土钉墙、放坡加土钉墙2种复合支护方案。实践证明，该工程所采用的多种复合式支护实施方案，技术安全可靠，经济合理。     

长白山锦北雨养泥炭剖面元素富集规律分析

为了揭示长白山锦北泥炭沼泽区泥炭沉积环境和重金属元素的历史变化及其对环境的指示意义,利用荷兰W ardenaar泥炭采样器采取泥炭样品并对样品进行高分辨率切割。用原子吸收分光光度计和等离子体发射光谱仪测定不同深度剖面Ca,Mg,Na,K,A l,Ti,Cu,Zn,Fe,Mn,Pb,Cr,N i和Co的浓度。研究分析了Ca,Mg,Na,K,A l,Ti,Mn,Zn,Cu,Pb,Cr,N i和Co在泥炭剖面的分布趋势并对其进行了相关分析和富集分析,得出Mn,Zn,Cu,Pb,Cr,N i和Co呈显著相关且在泥炭表层明显累积,揭示出泥炭表层重金属元素的大气沉降来源,表明近年来人类重金属消耗量及排放量的增加是大气沉降重金属元素的主要释放源,而且环境中重金属污染有加重的趋势。     

Characterization of water bursting and discharge into underground mines with multilayered groundwater flow systems in the North China coal basin

A conceptual framework for characterization of water bursting and discharge into underground mines with multilayered groundwater flow systems is presented, based on the features of the site conditions and analyses of the water bursting and mine inundation events of the North China coal basin. Comprehensive analyses of the hydrogeological conditions for establishment of the three-dimensional groundwater flow systems of the North China coal basin revealed different vertical hydraulic connection paths or channels. These connections include karst collapse columns, fault or fracture zones, buried weathering zones, and fracture networks in aquitards, within the multilayered groundwater flow systems. Also examined, was the effect of the primary features of the flow system and those different connection paths on water bursting and discharge into the underground coal mines. It was demonstrated that appropriately identifying and adequately understanding the three-dimensional multilayered groundwater flow systems and those various vertical hydraulic connection mechanisms are critical for appropriately preventing water bursting hazards and predicting water discharge into underground mines. A valuable guideline is presented on characterization of water bursting and discharge into underground mines with multilayered groundwater flow systems.

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Resumen Un cadre de travail conceptuel pour la caractérisation du jaillissement et de la vidange des eaux dans les mines à plusieurs niveaux d'écoulement est présenté, basé sur les conditions et l'analyse sur site du jaillissement des eaux et des inondations dans les bassins charbonneux du Nord de la Chine. L'analyse compréhensive des conditions hydrogéologiques des systèmes d'écoulement tridimensionnel de ces bassins, révèle des trajets ou des chenaux qui sont autant de connections hydrauliques verticales. Ces connections comprennent des effondrement karstiques en colonne, des zones de fractures et de failles, des zones d'altération, des réseaux de fractures dans les aquitards, dans le système hydrogéologique multicouche. L'influence des caractéristiques primaires du système d'écoulement et de ces différentes connections sur le jaillissement et la vidange dans les mines, est également examiné. Il a été démontré que l'identification appropriée et la compréhension adéquate du système d'écoulement souterrain multicouche et tridimensionnel, et des mécanismes variés de connection hydraulique verticale est critiquée pour prévenir de manière appropriée les risques de jaillissement et de vidange dans les mines. Des guidelines valorisables sont présentées, pour la caractérisation du jaillissement et de la vidange dans de tels systèmes.

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Résumé Se presenta un marco conceptual para la de caracterización de la despresurización y descarga de agua a minas subterráneas con sistemas de acuíferos de múltiples niveles, el cual se basa en las condiciones del sitio, análisis de la despresurización de agua e inundaciones de minas en la cuenca de carbón del norte de la China.Un análisis comprehensivo de las condiciones hidrogeológicas para el establecimiento de los sistemas de flujo de agua de tri-dimensionales en la cuenca de carbón del norte de la China ha revelado diferentes canales hidráulicos verticales. Estas conexiones incluyen columnas de karst colapsadas, fallas o zonas de fracturas, zonas de regalita hundida y redes de fracturas en zonas de poca permeabilidad dentro de los sistemas de flujo de múltiples niveles.También se investigó el efecto de los rasgos primarios del sistema de flujo y los diferentes canales conectivos sobre la despresurización y descarga de agua a minas subterráneas. Se demostró que el entendimiento e identificación adecuada de los sistemas de acuíferos de múltiples niveles en tres dimensiones es crítico para prevenir apropiadamente la despresurización y descarga de agua a minas subterráneas. Se presentan lineamientos valiosos en relación con la despresurización y descarga de agua a minas subterráneas en sistemas de flujo de múltiple nivel.

     

Preliminary evaluation of hydrochemistry of the Kalambaina Formation, Sokoto Basin, Nigeria

Hydrochemical investigations in the Kalambaina Formation have been initiated to determine potability and suitability of the shallow groundwater for domestic and agricultural uses. This limestone formation is an extensive aquifer supplying water to livestock and domestic wells in its outcrop areas. The aquifer is recharged by rainfall and discharges mainly into the Sokoto–Rima River system and lakes at Kware, Gwadabawa and Kalmalo in Nigeria. Because recharge to the aquifer is mainly from rainfall, the quality of the groundwater is controlled essentially by chemical processes in the vadose zone and locally by human activities. Water samples were taken at 11 sites comprising boreholes, dug wells and a spring and were chemically analysed for their major ion components. Hydrochemical results show water of fairly good quality. It is, however, hard and generally of moderate dissolved solids content. Concentration of the total dissolved solids is between 130 and 2,340 mg/l. Concentrations of ions vary widely but a high concentration of K⁺ is found in places. NO₃⁻ is on the higher side of the World Health Organization (WHO) permissible limits, indicating pollution in such areas. Groundwater chemistry is predominantly of two facies, namely the calcium–magnesium–bicarbonate and calcium–magnesium–sulphate–chloride facies. These facies probably evolved primarily as a result of dissolution of calcium and magnesium carbonates as well as some human/land-use activities.     

Estimating the minimum in-stream flow requirements via wetted perimeter method based on curvature and slope techniques

Under the assumptions of triangular cross section channel and uniform stable flow, an analytical solution of the minimum ecological in-stream flow requirement (MEIFR) is deduced. Based on the analytical solution, the uncertainty of the wetted perimeter method is analyzed by comparing the two techniques for the determination of the critical point on the relationship curve between wetted perimeter, P and discharge, Q. It is clearly shown that the results of MEIFR based on curvature technique (corresponding to the maximum curvature) and slope technique (slope being 1) are significantly different. On the P-Q curve, the slope of the critical point with the maximum curvature is 0.39 and the MEIFR varied prominently with the change of the slope threshold. This indicates that if a certain value of the slope threshold is not available for slope technique, curvature technique may be a better choice. By applying the analytical solution of MEIFR in the losing rivers of the Western Route South-to-North Water Transfer Project in China, the MEIFR value via curvature technique is 2.5%-23.7% of the multi-year average annual discharge, while that for slope technique is 11%-105.7%. General conclusions would rely on the more detailed research for all kinds of cross-sections.