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中国西北侏罗纪煤系显微组分生烃潜力、产物地球化学特征及其意义 总被引:8,自引:2,他引:6
从吐哈盆地侏罗纪煤中分离富集了藻类体、孢子体、角质体、镜质体、基质镜质体和丝质体6种主要显微组分,进行了热解及热模拟实验,并对各显微组分热模拟生成的产物热解油进行了碳同位素组成等分析。各显微组分热解生烃潜力及其热解产物热解油的碳同位素组成表明,煤系有机质中藻类体的生油潜力最高,生成的液态烃类的碳同位素组成最轻;孢子体、角质体等陆源富氢组分生烃潜力低于藻类体,生成的液态烃类的碳同位素组成重于藻类体生成的液态烃类,与煤系含油气盆地中原油的碳同位素组成基本一致。这些富氢显微组分应该是煤系有机质中主要的生油显微组分。镜质体和基质镜质体的生油潜力相对较低,其生成的液态烃类的碳同位素组成比一般煤系原油重得多,而且这些组分本身对液态烃具有较强的吸附力,尽管其在煤系有机质中所占的比例很大,仍然难以成为生成液态石油的主要显微组分,只能在高成熟演化阶段成为良好的生气显微组分。丝质体等惰性组分生烃潜力极低,不可能成为生油组分。此外,结合原煤的显微组分组成、生烃潜力和元素分析,提出仅仅以壳质组的含量高低来评价煤的生烃潜力不完全可靠,热解是经济、快速、有效的评价方法。 相似文献
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Stephen A. Bowden Abdalla Y. Mohamed Ayad N. F. Edilbi Yu-Shih Lin Yuki Morono Kai-Uwe Hinrichs Fumio Inagaki 《Basin Research》2020,32(5):804-829
Basin models can simulate geological, geochemical and geophysical processes and potentially also the deep biosphere, starting from a burial curve, assuming a thermal history and utilizing other experimentally obtained data. Here, we apply basin modelling techniques to model cell abundances within the deep coalbed biosphere off Shimokita Peninsula, Japan, drilled during Integrated Ocean Drilling Program Expedition 337. Two approaches were used to simulate the deep coalbed biosphere: (a) In the first approach, the deep biosphere was modelled using a material balance approach that treats the deep biosphere as a carbon reservoir, in which fluxes are governed by temperature-controlled metabolic processes that retain carbon via cell-growth and cell-repair and pass it back via cell-damaging reactions. (b) In the second approach, the deep biosphere was modelled as a microbial community with a temperature-controlled growth ratio and carrying capacity (a limit on the size of the deep biosphere) modulated by diagenetic-processes. In all cases, the biosphere in the coalbeds and adjacent habitat are best modelled as a carbon-limited community undergoing starvation because labile sedimentary organic matter is no longer present and petroleum generation is yet to occur. This state of starvation was represented by the conversion of organic carbon to authigenic carbonate and the formation of kerogen. The potential for the biosphere to be stimulated by the generation of carbon-dioxide from the coal during its transition from brown to sub-bituminous coal was evaluated and a net thickness of 20 m of lignite was found sufficient to support an order of magnitude greater number of cells within a low-total organic carbon (TOC) horizon. By comparison, the stimulation of microbial populations in a coalbed or high-TOC horizon would be harder to detect because the increase in population size would be proportionally very small. 相似文献
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中国省域煤矿事故时空分异特征及影响因素研究 总被引:1,自引:0,他引:1
煤矿事故给国家和人民带来巨大的生命财产损失,科学把握煤矿事故发生的宏观规律及区域煤矿安全的影响因素有助于促进煤矿安全生产。本文尝试采用GIS空间分析方法开展区域煤矿事故的研究,基于空间自相关性、时空演化规律方法研究了2006-2015年中国省域煤矿事故的时空分异特点,并分析了省域煤矿安全的影响因素及相对风险度。主要结论:①中国各省区之间煤矿事故存在明显的空间自相关性,但随着各省区煤矿安全生产形势改善情况的不同,其自相关性在不断下降;②以空间重心转移曲线分析中国煤矿事故发生的时空演化规律,10年间煤矿事故空间重心向东北方向转移。③重特大事故频发的省区由于监管措施的有力执行往往具有较低的煤矿百万吨死亡率;平均煤矿生产能力低的省区具有较高的煤矿百万吨死亡率;④建立基于解释变量的贝叶斯空间模型,以煤炭百万吨死亡率为指标评估中国各省区煤矿事故相对风险度,中国煤矿安全生产相对危险度存在明显的空间分布规律且各省区差异较大,相对危险度较高的省区主要集中在南方地区,包括湖北、福建等,危险度较低的省区主要集中在中东部地区,包括山西、内蒙古等。 相似文献
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夹河煤矿位于徐州市西北部,设计生产能力为140万t/a,新构造活动不强,构造稳定性较好。通过对矿区地震特征、煤储层特征分析,认为区内煤层稳定且储量大,该文以夹河煤矿为例,利用常规解释方法和地震属性参数技术解释了2煤层的煤层厚度,分析了地震属性剖面及煤层厚度图的成图方法,从而找出煤层厚度的变化规律,取得了较好的地质效果,为矿井采掘提供高精度地震勘探资料。 相似文献
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Application of a Bayesian model to infer the contribution of coalbed natural gas produced water to the Powder River,Wyoming and Montana
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The Powder River Basin (PRB) of Wyoming and Montana contains significant coal and coal bed natural gas (CBNG) resources. CBNG extraction requires the production of large volumes of water, much of which is discharged into existing drainages. Compared to surface waters, the CBNG produced water is high in sodium relative to calcium and magnesium, elevating the sodium adsorption ratio (SAR). To mitigate the possible impact this produced water may have on the quality of surface water used for irrigation, the State of Montana passed water anti‐degradation legislation, which could affect CBNG production in Wyoming. In this study, we sought to determine the proportion of CBNG produced water discharged to tributaries that reaches the Powder River by implementing a four end‐member mixing model within a Bayesian statistical framework. The model accounts for the 87Sr/86Sr, δ13CDIC, [Sr] and [DIC] of CBNG produced water and surface water interacting with the three primary lithologies exposed in the PRB. The model estimates the relative contribution of the end members to the river water, while incorporating uncertainty associated with measurement and process error. Model results confirm that both of the tributaries associated with high CBNG activity are mostly composed of CBNG produced water (70–100%). The model indicates that up to 50% of the Powder River is composed of CBNG produced water downstream from the CBNG tributaries, decreasing with distance by dilution from non‐CBNG impacted tributaries from the point sources to ~10–20% at the Montana border. This amount of CBNG produced water does not significantly affect the SAR or electrical conductivity of the Powder River in Montana. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献