Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate

Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery.     

利用地震属性预测煤层厚度及古河流冲刷带的方法

根据山西宁武煤田某煤矿2#煤层采掘及钻孔揭露情况,发现该井田中部和南部存在古河流冲刷带。通过对比基于优选的4个地震属性的四元一次、四元二次多项式回归模型与BP神经网络预测模型,决定将BP人工神经网络模型预测煤层厚度数据应用于整个测区古河流冲刷带的预判工作。首先利用GeoFrame系统和Landmark公司Poststack模块,提取2#煤层反射波的各类沿层切片,分析并圈定出2#煤层古河流冲刷带的大致范围,在此基础上,利用垂直时间剖面中2#煤层反射波的各种波形特征,进一步判别2#煤层古河流冲刷带解释的可靠性,然后结合BP神经网络预测模型获得的2#煤层厚度变化趋势图,最终解释出2#煤层古河流冲刷带范围:勘探区内2#煤层厚度变化范围0～5.3m,根据其煤层厚度变化趋势,将全区划分出一大二小3个古河流冲刷带。     

新驿煤矿下组煤矿井涌水量预测研究

在系统收集水文地质资料的基础上,运用"大井法"和水文地质比拟法对开采16煤的涌水量进行了预测,利用突水系数法,对八采区16煤底板奥灰突水危险性进行了评价,得出了突水系数分区图。经综合分析对比,采用大井法的预测结果:即开采16煤正常涌水量为482m3/h,最大涌水量为540m3/h;奥灰突水量初期为1 083～10 640m3/h,一般为660～4470m3/h;如对奥灰采取疏排降压方案,疏降排水量预计为770m3/h。此结果可作为矿井回采阶段防治水设计的参考。     

Calcified roasting-acid leaching process of vanadium from low-grade vanadium-containing stone coal

The low-grade vanadium-containing stone coal used in this experiment was collected from Wuxi Coun- try, Chongqing City, China. The experiment focused on the vanadium recovery from roasted residue through opti- mizing the process conditions of an effective and environmentally-friendly technology, named calcified roast- ing-sulfuric acid leaching technology. By single-factor experiments and orthogonal experiments, the effects of roast- ing temperature, roasting time, sulfuric acid concentration and leaching time on the leaching ratio of vanadium were analyzed. The results showed that the leaching ratio of vanadium reached 85.5% under the proper technological con- ditions of roasting temperature=950℃, roasting time=4 h, 40% concentration of sulfuric acid and leaching time=6 h.     

柴达木盆地石炭系烃源岩和煤岩生物标志物特征及其地球化学意义

采自柴达木盆地东北部石炭系烃源岩和煤岩的生物标志化合物研究表明,研究样品的有机质演化已达高成熟阶段,其母质来源以水生生物为主,同时有较丰富的陆源物质输入。除煤岩的沉积古环境较氧化且经历过较强的降解过程外,其余样品的沉积古环境均属于较还原环境,沉积介质为咸水环境,有机质总体丰度高。因此该区石炭系海陆交互相含煤沉积是一套较一般侏罗系为好的烃源岩系,有较好的生烃潜力。     

淮南矿区煤矸石的物质组成特征及资源化评价

本文利用各种测试方法,对淮南谢桥、新庄孜和张集煤矿采集的不同层位来源的240个煤矸石样品的化学成分、矿物成分和微量元素的进行测试与分析,得出了淮南矿区不同煤矿煤矸石的化学成分特征及其中微量元素的含量变化,评价了煤矸石中有害元素的环境影响作用。结合煤矸石基本特征,提出了合理的资源化利用途径,为煤矿开采过程的主要固体废物煤矸石综合利用和资源化、煤矿环境保护提供了参考资料。     

阳城煤矿瓦斯地质规律研究

运用沉积学、构造地质学、煤地质学、数学分析等相关学科和方法,综合分析瓦斯涌出量的地质构造、顶底板岩性、上覆基岩厚度等地质因素,对阳城地区瓦斯含量、涌出量进行量化预测,并作出其全井田瓦斯含量、涌出量的等值线图。研究表明,阳城井田属低瓦斯矿井,瓦斯含量的变化主要与煤层埋深有关,随着煤层上覆基岩厚度以及煤层埋深的增高,瓦斯含量与涌出量在区内由北向南有增高趋势。     

新疆北部古地磁研究

通过和布克赛尔、克拉玛依、玛纳斯—乌鲁木齐地区泥盆纪到白垩纪古地磁研究,主要取得以下结果:(1)首次建立了准噶尔西北缘及南缘石炭纪—白垩纪古地磁极移曲线,由石炭纪到二叠纪的古地磁极位置基本在同一区间,说明该时期这些地区为一个统一的构造单元,而其古地磁极明显与塔里木、哈萨克斯坦、西伯利亚地块存在着差异。(2)该地区侏罗纪及白垩纪古地磁结果与塔里木地块结果一致,侏罗纪乌鲁木齐与和布克赛尔磁偏角相差30°左右,说明和布克赛尔地区相对乌鲁木齐地区逆时针旋转了30°左右,晚古生代以后曾发生过南向移动,而侏罗、白垩纪以来均向北发生了相当规模的北向运动,并发生了相对旋转,目前东、西准噶尔的构造格局可能就是由于局部相对旋转造成的。(3)中国大陆在早二叠世还不是一个联合的整体,而是以相互分离的独立块体分布于45°N—15°S的古特提斯洋中。(4)该地区二叠纪的磁偏角为165°—168°,而塔里木为218°,哈萨克斯坦为229°,说明存在35°—55°的逆时针旋转,这个旋转可能是由于西部推覆构造造成的。如果将西准噶尔超基性岩带顺时针旋转35°—55°后,东准噶尔超基性岩带、西准噶尔超基性岩带和斋桑泊—鲁布佐夫斯克超基性岩带应在同一构造带上。(5)该地区晚古生代古纬度变化不明显,位于30°—45     

毛乌素沙漠地震勘探历程及效果

总结陕西省煤田地质局物探测量队在毛乌素沙漠开展地震勘探攻关的三个阶段及各阶段取得的成果,认为该区虽然表浅层地震地质条件复杂,地震勘探难度较大,但勘探精度基本上可以达到解释5m断层的的精度。并以国家重大产业技术开发专项的依托工程,内蒙古鄂托克前旗新上海庙地区SZT井田三维地震勘探为例,对地震激发、接收技术进行改进,并采取精细静校、地表一致性振幅补偿等处理手段,结合多参数信息,进行资料精细解释。成果表明：依托工程野外原始资料甲级率达到70％以上,获得的三维数据体信噪比高,构造及煤层解释成果可靠、准确。     

山西沁水盆地中,南部现代构造应力场与煤储层物性关系之探讨

山西沁水盆地中、南部下二叠统山西组主煤储层现代构造应力场主应力差增大、煤储层渗透率梯度呈指数形式增长,煤储层压力梯度呈对数增长,这种规律主要受控于现代构造应力场应力方向与煤储层天然裂隙优势发育方向之间的相互关系,这两组方向对于煤储层来说近于平行,对煤储层顶板则表现为近于正交,由此导致主煤储层中天然裂隙处于相对拉张状态,而其顶板天然裂隙处于挤压状态,主应力 越大,相对拉张效应就越显著。基于这种规律和