关于创建华南金融合作区的思考

金融赶超经济发展战略对欠发达国家和地区很重要的现实意义。这一战略要求把金融当作一项系统工程来建设。金融合作则是启动金融工程,实施金融赶超经济发展战略的基础工作。因此,创建包括香港和澳冰两个特别行政区,广东、广西,海南三省区的华南金融合作区对促进本地区经济与金融合作区的总体思路：（１）建立一个以香港－深圳－广州为轴心的金融合作走廊;（２）建立香港与广东、广西、海南之间和广东、广西、相互之间圈层式的次     

Sequential Separation of Uranium,Hafnium and Neodymium from Natural Waters Concentrated by Iron Coprecipitation

A new ion exchange chromatography method is presented for the isolation of high field‐strength elements (HFSE) from freshwater and seawater samples that have undergone iron coprecipitation. Large volumes of water can be condensed through the application of iron coprecipitation, but clean separation of elements from the precipitate proves difficult. The technique described is a five‐column process designed to separate the HFSE, including rare earth elements such as neodymium and hafnium, before removing the iron and isolating uranium. Subsequent isolation of Nd and Hf was achieved using established ion exchange chromatography methods. The efficacy of our chemistry was verified by measurements of analytical reference materials – both reference solutions and seawater samples – subjected to the chemical separation methods described. Elution results indicate high yields (> 90%) determined by concentration measurements of a known reference material added to each column. Measurement results for isotopic compositions of seawater (U, Nd) and reference solutions (NIST SRM 960, U) were identical within uncertainty to previously published values. Compositions were identical between solutions (Spex CLMS3, Spex PLND2) that underwent different iron coprecipitation procedures. Isotopic determinations for reference materials JNdi‐1 and NIST SRM 960 measured with the mass spectrometers used in this study were in agreement with universally accepted values for these materials, and indicate high precision.     

Small‐scale faulting,topographic steps and seismic ruptures in the Alhambra (Granada,southeast Spain

The Alhambra (14th century AD ) in Granada (southeast Spain) is built at the summit of a Pliocene to Lower Pleistocene conglomeratic formation. Tens of small‐scale normal faults crop out along the northern hillslope of the Alhambra, which have a N130–N150°E strike, dipping 65–75° mostly to the southwest. These are closely spaced faults (approximately 5–30 m) with centimetre to several metre displacements. Several topographic steps in this area coincide with hectometre‐ to kilometre‐scale faults with the same kinematics as the small‐scale ones. Some of these faults appear to be active and related to the present seismicity detected in this region, and associated with the cracks and other damage observed in the Alhambra. Several focal mechanisms calculated in this study are in accordance with the dominant NW–SE orientated normal faults. We interpret that the topographic steps of these faults are a consequence of repeated earthquakes during the past 800 ka. The last large earthquake of approximately 5.1 magnitude in this area occurred in 1431, destroying the Alixares Palace, the Arabian fence and part of the Alhambra wall. We consider the seismic risk associated with these faults to be moderate, as the displacement is partitioned into several hectometre‐ to kilometre‐scale faults. Copyright © 2004 John Wiley & Sons, Ltd.     

Solute transport through a deforming porous medium

Solute transport through a porous medium is typically modelled assuming the porous medium is rigid. However, many applications exist where the porous medium is deforming, including, municipal landfill liners, mine tailings dams, and land subsidence. In this paper, mass balance laws are used to derive the flow and transport equations for a deforming porous medium. The equations are derived in both spatial and material co‐ordinate systems. Solute transport through an engineered landfill liner is used as an illustrative example to show the differences between the theory for a rigid porous medium, and small and large deformation analysis of a deforming porous medium. It is found that the large deformation model produces shorter solute breakthrough times, followed by the small deformation model, and then the rigid porous medium model. It is also found that it is important to include spatial and temporal void ratio variations in the large deformation analysis. It is shown that a non‐linear large deformation model may greatly reduce the solute breakthrough time, compared to a standard transport analysis typically employed by environmental engineers. Copyright © 2002 John Wiley & Sons, Ltd.     

四川汶川8.0级地震地下流体异常分析

汶川8.0级地震引起了社会广泛地关注,产生了地震能否预测的疑问以及汶川地震前是否出现了异常的讨论,震后一些学者对前兆资料进行了研究总结,本文在前人研究的基础上仅对地下流体异常进行了分析,认为汶川地震前存在着一些地下流体异常,本文从中期异常、短临异常、同震及震后调整这几个方面对水氡、水位、水温、流量资料进行了分析研究。通过对中期异常的识别及提取,认为采用从属函数方法定量提取异常效果较为理想。     

2008年汶川地震同震滑移特征、最大滑移量及构造意义

2008年汶川地震（M_s8.0）形成了迄今为止空间上分布最为复杂、长度最大的逆冲型同震地表破裂带。沿约275km长的地表破裂带的同震滑移及其最大滑移量的确定,对认识和理解汶川地震地表破裂过程及其变形机制具有重要意义。我们沿地表破裂带进行了详细的滑移特征考察及其同震位移测量,发现沿映秀-北川破裂带分布南北两个滑移峰值区段,南段以深溪沟-虹口破裂段为中心,以逆冲为主伴随右旋走滑运动为特征,最大垂直位移量为6.0～6.7m,北段以北川破裂段为中心,以右旋走滑为主伴随逆冲运动为特征,最大垂直位移量为11～12m,南北两滑移峰值区段所代表的两次地表破裂事件与地震波数据反演结果一致。通过对北川段破裂带的精细地形剖面测量,以及地震前后对比,在北川县曲山镇沙坝村一组获得该破裂段的最大右旋水平位移为12～15m,最大垂直位移为11～12m,这是目前世界上一次地震产生的最大同震垂直位移,最大斜向滑移量为14～17m,为整个汶川地震地表破裂最大滑移量,是汶川地震的宏观震中。北川破裂段高角度的地震断裂、逆冲断裂面的倒转作用以及具最大滑移量的强烈变形作用是北川县城遭受到最强的地表破坏和地质灾害的主要原因。具有走滑量和逆冲量近一致（走滑水平位移/逆冲垂直位移比值为1）的斜向逆冲作用可能是山脉快速隆升的重要机制。     

涂氏磷钙石的形成条件研究

用微束矿物学和激光拉曼光谱等分析测试技术,并结合人工高压实验结果,研究了我国随州陨石冲击熔脉中的白磷钙石高压相变形成涂氏磷钙石的必要条件,并对寺巷口陨石冲击熔脉中的白磷钙石虽与林伍德石、镁铁榴石和玲根石等高压矿物共生,但仅表现为结构损伤而未相变成涂氏磷钙石的原因进行了探讨.研究结果发现,随州陨石中白磷钙石或氯磷灰石的存在是涂氏磷钙石得以形成的物质前提,陨石熔脉中高达24 GPa和2000℃以上的高压高温环境是涂氏磷钙石能够形成的条件保障,而压力释放后熔脉极快的冷却速率是涂氏磷钙石得以淬火并稳定保存的关键.研究还查明,寺巷口陨石冲击熔脉比随州陨石的熔脉要宽1至2个量级,其冷却速率比随州陨石慢得多,因此,熔脉中早先形成的涂氏磷钙石,可能在脉内较高的冲击后温度影响下,慢慢退变质成白磷钙矿.     

蒙脱石,高岭石与碱性驱替剂作用时矿物间的协同效应研究

在７５℃下系统地研究了蒙脱石、高岭石、以及蒙脱石和高岭石的复配矿物与７＃碱性驱替剂（ρＮａ２ＣＯ３＝１５ｇ·Ｌ－１）间的作用,采用分光光度法对反应后反应液中的硅铝元素质量密度进行了测定,并对两种矿物单独存在时的结果和共存时的进行了比较,结果表明因为蒙脱石在碱性驱替剂中容易析出硅元素,而高岭石在碱性驱替剂中容易析出铝元素,当二者共存时会相互抑制。并且,蒙脱石的存在会对高岭石析出铝元素产生很大的抑制作用,而高岭石的存在对蒙脱石析出硅元素的抑制作用较小,证明蒙脱石更容易与碱液反应而对整个反应起到控制作用。协同效应研究还表明,蒙脱石的作用与其质量不成比例,当加入很少的蒙脱石也会控制整个反应。这些研究对化学驱中化学剂损耗预测模型的建立具有重大的意义。     

Origin of rutile needles in star garnet and implications for interpretation of inclusion textures in ultrahigh‐pressure metamorphic rocks

The asterism effect of star garnet has been attributed to the oriented distribution of needle‐like rutile inclusions. Rutile needles occur in garnet from a wide range of metamorphic settings and rock bulk compositions, and their origin has been ascribed to different mechanisms, such as exsolution, and used to interpret petrological and tectonic processes. Results from an optical and transmission electron microscopy of Idaho star garnet indicate a co‐precipitation origin. It was found that rutile needles are predominantly oriented along the <103>_rt//<111>_grt and <001>_rt//<001>_grt directions following multiple crystallographic orientation relationships (CORs); i.e. COR‐1, 2, 2′, 3, 4 and 5 in 6‐ray star garnet, and are oriented solely along the <103>_rt//<111>_grt directions following exclusively COR‐2 in 4‐ray star garnet. The sole presence of COR‐2 <111>_grt needles in the common 4‐ray star garnet, in contrast to the presence of both <111>_grt and <001>_grt needles with multiple CORs in the rare 6‐ray star garnet, suggests that the COR‐2 <111>_grt needle probably is the energetically most favoured variant, as is also supported by the coincidence site lattice considerations. The unique crystallography‐controlled microstructures of 4‐ray star garnet, including the cloudy domains behind the {111}_grt or {100}_grt fronts with abundant inclusions of rutile needle, rutile compound needle and multiple‐phase‐inclusion, as well as the clear domains behind the {110}_grt fronts with only a few above inclusions concentrated exclusively within the linear, <110>_grt‐oriented, continuous tube‐like domains, further suggest that the COR‐2 <111>_grt needles in 4‐ray star garnet most likely have a growth‐in origin, co‐precipitating with garnet at its growth fronts close to thermodynamic equilibrium conditions. The 6‐ray star garnet, on the other hand, most likely formed under far‐from equilibrium conditions, thereby yielding a maximum of 99 crystallographic variants of rutile needles with multiple CORs in a single crystal. In the light of these findings, along with the common occurrences of the sole COR in many inclusion‐host systems owing to the requirement to minimize the energy barrier in an exsolution process, the presence of both <103>_rt//<111>_grt and <001>_rt//<001>_grt needles with multiple CORs in garnet of Sulu eclogite and Erzegebirge quartzofeldspathic rock would therefore cast doubt on the assertion of an exsolution origin of rutile needles in garnet from these ultrahigh‐pressure rocks.     

Coupling of BEM with a large displacement and rotation algorithm

In stability analysis of rock blocks, the deformability of the blocks can conveniently be simulated using the boundary element method (BEM). However, all boundary conditions are given as stresses. Thus, the displacement solution is not unique. In this paper, an algorithm is proposed to remove rigid body motions in the solution of the boundary form of Somigliana identity discretized by the direct BEM formulation. The algorithm is applied to the calculation of the normal stiffness of rock blocks and coupled with BS3D, large displacement and rotation algorithm for the general stability of rock blocks. Copyright © 2010 John Wiley & Sons, Ltd.