地质成分数据统计分析

地质学研究中遇到大量成分数据,其各行之和相同,因而组分相关性中含由闭合效应引起的伪相关,而且不服从正态分布,给统计分析带来了很大困难．分析了前人提出的一些识别成分数据中伪相关的方法的缺欠,提出对数比变换作为成分数据统计分析的基本步骤的依据、优越性及存在问题;指出闭合造成的信息损失包括基的相关结构的信息,是任何方法都找不回来的．今后应着重分析有哪些信息还保留在成分数据中,并有针对性地寻找萃取这些信息的方法．     

长江三角洲海岸剖面闭合深度的研究：Bruun法则及其应用的基本问题

本文对Ｂｒｕｕｎ法则 应用的前提－海岸剖面的基本问题进行了深入探讨,提出长江三角洲海岸不发育经典理论中砂质海岸那种较为严格的均衡剖面。     

Third-Order Moments for Shear Driven Boundary Layer

A new third-order model for shear driven boundary layer is presented and tested against large-eddy simulation (LES) data. Numerical solutions are obtained using mean flow components and second-order moments as input. The calculated vertical profiles of the variances and turbulent kinetic energy fluxes and those provided by a LES experiment are compared and discussed     

New Approaches in Two-equation Turbulence Modelling for Atmospheric Applications

The turbulence closure in atmospheric boundary-layer modelling utilizing Reynolds Averaged Navier–Stokes (RANS) equations at mesoscale as well as at local scale is lacking today a common approach. The standard kɛ model, although it has been successful for local scale problems especially in neutral conditions, is deficient for mesoscale flows without modifications. The k–ɛ model is re-examined and a new general approach in developing two-equation turbulence models is proposed with the aim of improving their reliability and consequently their range of applicability. This exercise has led to the replacement of the ɛ-transport equation by the transport equation for the turbulence inverse length scale (wavenumber). The present version of the model is restricted to neutrally stratified flows but applicable to both local scale and mesoscale flows. The model capabilities are demonstrated by application to a series of one-dimensional planetary boundary-layer problems and a two-dimensional flow over a square obstacle. For those applications, the present model gave considerably better results than the standard k–ɛ model.     

齐次湍流动能输运方程封闭模型在浅海动力学中的应用

该文对已建立的齐次湍流动能输运方程封闭模型 (HKE)封闭的浅海动力学模型进行了检验。湍流混合强度的垂直分布会影流速剖面 ,在风海流、狭长渠道稳态风潮及渠道振荡流流场等的模拟中 ,HKE封闭均取得满意效果 ,结果表明 HKE封闭在正压浅海动力学中是有效的 ,可避免混合长理论的缺陷 ,并未过多增加计算量。振荡流的湍流粘性系数的时间分布特性是时变的 ,其变化频率为振荡频率的两倍 ,且在流速变化最大时湍流混合最强。对应于浅海潮波系统 ,平潮和停潮时局地混合最弱 ,因而最适宜水质采样 ,反之 ,涨急和落急时刻湍流混合最强。但当取湍动能的Schmidt数 σk>10时 ,湍粘性系数的振幅仅为其平均值的 15 % ,因此可以认为在 15 %误差内振荡流的粘性系数可用一个时间平均值来代表     

华北地区区域水准大气折光影响分析

大气折光对水准测量的影响是目前最重要且很难消除的误差之一。由折光影响产生的系统闭合差可能超过随机观测误差,那么在沿相同水准路线作重复观测的情况下,就可能会出现同符号闭合差。针对这一问题,该文提出了分析闭合环统计性质,从而提取出大气折光可能影响大的测段的方法。为了定量分析大气折光对水准观测结果的影响,提出不测温差的大气折光改正方法,对提取出的测段进行折光影响模拟。结果表明,大气折光对部分测环的水准环闭合差有系统性偏离影响,部分测段大气折光影响与地形存在明显的相关性。     

Tectonic Framework of Late Paleozoic Intrusions in Xingxingxia: Implications for Final Closure of South Tianshan Ocean in East Tianshan

This work carried out systematic geological field investigation, petrography observation, zircon geochronology and whole rock geochemistry on Late Paleozoic intrusions in the Xingxingxia region near the Xinjiang-Gansu provincial boundary, western China, aiming to constrain the Late Paleozoic tectonic framework of the Xingxingxia region and the final closure time of South Tianshan Ocean in the East Tianshan. The Xingxingxia area is located in the east part of the Tianshan orogen, and adjacent to the north of the Tarim Basin. The Late Paleozoic magma activities in the Xingxingxia region can be mainly divided into three stages. The first stage includes intrusive magma activities under a collision setting between Late Ordovician to the Late Devonian. The second stage is intrusive magma activities under a subduction setting during(304±3)–(278±3) Ma, and the third stage involves intrusive magma activities under a collision and post-collision setting during(268±5)–(259.9±2.6) Ma. The final suture zone of South Tianshan Ocean should be between the Central Tianshan Block and South Tianshan accretionary complex. Based on previous work, both the first stage magma activities(i.e., intrusive magmatic activities between the Late Ordovician to Late Devonian) and the Hongliuhe ophiolitic complex indicate a close event between Central Tianshan Block and South Tianshan Accretionary Complex. The 304±3 Ma dioritic metamorphic gneiss of the XingX ingxia complex and the 278±3 Ma diorite are all island arc calc-alkaline rocks, the 289±3 Ma gabbro is island arc tholeiitic gabbro formed by magma from metasomatic enrichment mantle. All these results indicate that the second stage of magmatic activities is under a subduction setting. The third stage magma activities i.e. the granitic magma activities of(268±5)–(259.9±2.6) Ma occurred at a transitional setting from compressional to post-collision extensional tectonic setting. Thus, around(268±5)–(260±3) Ma, the final closure of the South Tianshan Ocean occurred and the Tianshan orogen shifted into the intracontinental evolution stage. During and after the closure process, a wide range of metamorphism and large dextral strike-slip faults developed.     

Mobility of arsenic and environmentally significant elements in mine tailings following liming

Remediation of a legacy tin-tailings site in northeast Tasmania, Australia was carried out by statutory authorities. This study evaluated the fate of As and other deleterious trace metals Cd, Cu, Fe and Zn (among others) following the application of lime and fertiliser. Arsenic concentrations in the tailings ranged from 86 mg/kg to 0.26 wt%. Surface application of lime resulted in a 100-fold reduction in dissolved As concentrations in on-site surface waters; from an average of 196 µg/L prior to lime addition, to between 2.0 and 7.4 µg/L post-amendment. The concentration of other deleterious elements, however, varied between dry and wet cycles. The concentrations of Cd, Cu and Zn in surface waters were high and similar to pre-remediation levels during dry conditions (0.4, 13.5 and 6.1 mg/L, respectively), and only below freshwater ecosystem protection values during wet conditions. Bioaccumulation of Cd was observed in the naturally occurring coloniser, Juncus pallidus, with 4–5 times more Cd in the above-ground biomass relative to the tailings. Ferric arsenate (scorodite) was the dominant source of As identified in the tailings mineralogy. Hydrous ferric oxides and Fe-bearing cassiterite were also identified as hosting As. The pH increase in the surface lime-amended tailings was inferred to result in precipitation of observed hydrous ferric oxides, hematite and goethite, providing high-surface area for adsorption of arsenate onto positively charged surfaces. Jarosite was observed in both the surface lime-amended and subsurface non-amended tailings and suggests a continued supply of acidity to the pore waters despite the application of lime. Leaching experiments showed that As was more mobile in the lime-dosed tailings than in subsurface non-amended tailings, likely owing to desorption in alkaline pH conditions. By contrast, the mobility of Cd, Cu and Zn in the surface lime-amended tailings was reduced by at least two orders of magnitude compared with subsurface non-amended tailings. Evaluation of the applied rehabilitation strategy highlights the limits of a single chemical remediation approach to a polymetallic (including metalloids) waste with complex mineralogy and large seasonal fluctuations. Rehabilitation of metalliferous mine sites requires a complete understanding of all environmentally significant elements and their pathways into local receptors.     

δ13C-δ18O Covariance: An Effective Indicator of Hydrological Closure for Lakes?

The correlation between the δ^13C and δ^13C-δ^18O in primary carbonates is affected by several factors such as hydrological balance, total CO2 concentrations, climatic condition and lake productivity. The influence of these factors on the δ^13C-δ^18O correlation may be different on different time scales. In this paper, two different-type lakes in southwestern China, Lake Erhai and Lake Chenghai, are selected to investigate the influence of climatic pattern on the δ^13C-δ^18O correlation and to evaluate the reliability of the δ^13C-δ^18O covariance as an indicator of hydrological closure. The results show that there exists good correlation between the δ^13C and δ^18O in Lake Erhai （overflowing open lake） and in Lake Chenghai （closed lake）. This suggests that the δ^13C-δ^18O covariance may be not an effective indicator of hydrological closure for lakes, especially on short time scales. On the one hand, a hydrologically open lake may display covariant δ^13C and δ^18O as a result of climatic influence. The particular alternate warm-dry and cold-wet climatic pattern in southwestern China may be the principal cause of the δ^13C-δ^18O covariance in Lake Erhai and Lake Chenghai. On the other hand, a hydrologically closed lake unnecessarily displays covariant trends between δ^13C and δ^18O because of the buffering effect of high CO2 concentration on the δ^13C shift in hyper-alkaline lakes. We should be prudent when we use the covariance between δ^13C and δ^18O to judge the hydrological closure of lake.