超声提取-固相萃取小柱净化-气相色谱法测定土壤中14种有机氯农药

对土壤中14种有机氯农药的超声提取技术和磺化、固相萃取小柱两种净化方法进行系统研究。结果表明,超声提取节省提取时间,提高分析效率;磺化法和固相萃取小柱法都有净化作用,但磺化法使样品中的艾氏剂、狄氏剂和异狄氏剂全部损失;固相萃取小柱净化当丙酮-正己烷淋洗液体积比为1∶9、淋洗液收集8 mL时回收率>90%,干扰最小。方法检出限为0.63~2.59μg/kg,精密度(RSD,n=7)为1.17%~14.66%,基体加标平均回收率为82.78%~106.94%。方法用于生态地球化学调查评价批量土壤样品的实际分析,检测结果满足评价工作需要。     

低渗致密砂岩气田储层损害评价及保护措施

储层孔隙类型、孔隙结构、粘土矿物类型和含量等是造成气层受伤害的潜在因素 ,而外来固相、滤液以及生产或作业压差、生产时间等工程因素也可造成或加重对气层的伤害程度 ,因此 ,低渗致密气田 (藏 )的开发效果在很大程度上依赖于开发技术水平的提高。应用岩心评价实验、时间推移测井、生产测井以及试井等方法 ,评价了河南东濮凹陷白庙、文 2 3等气田低渗致密砂岩储层的敏感性及与外来液的配伍性 ,分析了导致或加重对气层造成伤害的工程因素。在气田开发的全过程中 ,有针对性地制定出对气层进行保护的配套措施 ,减少了对储层的伤害 ,充分发挥了气层的潜力 ,提高了气田的开发效果 ,也为同类气田提供了借鉴。     

上海软粘土微观特性及在土体变形与地面沉降中的作用研究

对上海软粘土的颗粒及集合体成分、孔径分布、微结构、孔隙溶液与阳离子交换性作了分析 ,对固结前后的孔径变化与人工回灌对土体性质可能带来的影响作了探讨 ,从物理化学角度阐述了软粘土微观特性对土体固结变形及地面沉降的影响.     

成都粘土路堑边坡防护研究

成都外环路高速公路东半环超过有20km的路段处在成都粘土分布区，针对成都粘土的易滑性，本文提出了全封闭的浆砌片石护坡，土钉墙，非全封闭的锚杆框架护坡，钢纤维混凝土喷锚全封闭护坡，重力式挡土墙等五种方法处理成都粘土路堑边坡工程，施工实践表明，这些方法行之有效，在该类土的边坡防护中值得推广。     

河套地区土壤矿物组成分析及与各元素的关系

通过对河套地区土壤中矿物组成的分析研究,土壤中矿物组成中砂质成分主要为石英、长石、方解石,黏土矿物组合主要为伊利石、绿泥石和高岭石,此外还有角闪石等少量矿物成分。在砂土、粉砂土中石英、长石含量较高,在黏土质为主的土壤中黏土矿物含量增加。黏土矿物与石英以及长石呈负相关关系,与大多数元素呈明显正相关关系,黏土矿物对各元素具有明显吸附性;石英、长石与各元素含量呈负相关关系,说明其对元素不具有吸附性。     

The composition and age of the Argillite Sequence (sedimentary cover of the continental slope, Sea of Japan)

The Argillite Sequence located at the base of the sedimentary cover on the continental slope of the Sea of Japan was studied by petrographic, palynological, and X-ray diffraction methods. Two spores-pollen complexes were distinguished in it: the Late Oligocene reflecting cooling and the Early Miocene corresponding to initiated warming. The data obtained indicate that the sequence is composed of terrigenous silty-clayey sediments that accumulated in shallow coastal-marine settings. The global sea-level rise at the Early-Middle Miocene transition, combined with the regional tectonic processes, determined the basin deepening, owing to which the argillite sequence was overlain by thick Middle Miocene diatomaceous-clayey sediments. Due to tectonic movement along existing faults in the terminal Late Miocene, the argillite sequence occurring initially at depths of at least 400–500 m was locally exhumed to the basin bottom.     

福建沿海地区土壤元素含量特征与地质背景研究

根据福建沿海深层土壤元素含量的统计分析,表明9大类地质体为背景的土壤元素含量存在差异,与均值对比Ag、Au、Sn、Co、Cu的含量受地质背景影响较小,B、Cr、Ni、Li、As、Sb、Hg、Mo、Bi、Cd、Br、C1、S、CaO、I、Na2O含量则影响明显。     

Characterization of an Area Polluted by Copper and Zinc:the Relation between Soil Texture,Mineralogy and Pollutant Concentration

Abstract: Twenty-four soil samples were collected at three depths from an approximately 2.5 acre contaminated site in southern Piedmont (Italy) and then analyzed. The main soil parameters determined were: pH, Cation Exchange Capacity (CEC), particle size distribution, total organic carbon (TOC) content and retained metal concentration. The mineral phases were identified by X-Ray Powder Diffraction (XRPD). All of the samples contained Zn and Cu resulting from industrial contamination during the last century, and those obtained at depths of 20-40 cm consistently showed the highest levels. To determine which size fraction was most active in the retention process, the samples were separated into four fractions (≤2 mm, ≤63 μm, ≤30 μm and ≤2 μm) and the amount of pollutant measured in each. It was found that metal retention was the highest in the clayey fraction, whose clay minerals were identified by XRPD after K+ and Mg2+ saturation, glycerol treatment and heating to 550°C. The clayey fraction was also the richest in TOC, and a direct correlation between TOC amount and metal retention was observed.     

重庆主城区粉质黏土动力特性研究

采用自振（共振）柱和动三轴试验方法,得到重庆主城区粉质黏土动剪切模量和阻尼比随剪应变变化试验结果,比较分析试验值、文献[1]给出的推荐值和文献[2]给出的规范值的差异,并通过土层反应计算初步给出了这种差异对地表反应谱的影响,结果表明：(1) G/Gmax-γ关系中,规范值在中等应变时给出的G/Gmax比试验值和推荐值低;大应变时,相比较于试验值和推荐值,规范值衰减更快;(2) 相比较于λ-γ关系,G-γ关系经过Gmax归一化后,更具有一致性,粉质黏土阻尼离散性较大;(3) 试验值和推荐值计算的地表反应谱相差较小,但试验值和规范值计算的地表反应谱相差较大,特别是在随着输入地震动强度增大,这种差异性更显著。分析表明,重庆主城区进行土动力计算过程中,当无土动力特性试验资料时,选用规范值具有一定的局限性和风险,相比较于规范值,推荐值在一定程度上更具适用性。     

考虑颗粒抗转动的砂土双轴试验离散元模拟

颗粒间抗转动作用是影响砂土力学行为的重要因素。将蒋明镜等（2005年）提出的考虑颗粒抗转动作用的颗粒接触模型植入PFC2D中,对砂土双轴试验进行了模拟,研究颗粒抗转动作用对砂土力学行为的影响。研究显示：颗粒抗转动对砂土力学行为影响显著。抗转作用越强,砂土强度越高;抗转系数为0.4时,松砂亦出现软化及剪胀现象。抗转动作用对孔隙比及配位数变化趋势影响也很显著。