长江中下游抛刀岭大型中硫型浅成低温热液金矿床的厘定及其找矿启示

长江中下游是全球重要的斑岩-矽卡岩铜多金属矿床成矿带之一,近年来识别出一些大型明矾石矿床、中小规模高硫型和低硫型金±银矿床,但是否存在中硫型矿化蚀变系统还不清楚.抛刀岭是近年来在长江中下游成矿带新发现的大型独立金矿床,文章通过岩芯编录、短波红外光谱和矿物成分的研究,厘定该矿床矿体主要产于～140 Ma英安斑岩脉中,成矿...     

基于欧洲中心细网格预报资料和观测资料的浙江省春夏降水性质分类指标

利用浙江省2004~2013年3~8月Micaps（气象信息综合分析处理系统）地面填图数据和T-logP数据研究杭州、衢州和台州三市的阵雨和雷雨个例,同时选取能表征雷雨并能区分阵雨与雷雨的气象预报因子:对流有效位能、850 hPa与500 hPa的温差、K指数、地面2 m温度,用临近探空的分析方法和决策树的分类方法初步建立了一个适用于浙江省春夏季降水性质分类指标。利用欧洲中心（ECMWF）细网格预报资料,对历史样本和2016年春、夏季分别作了检验。结果表明:除去有降水预报误差个例后,指标TS（Threat Score）评分超过0.53,雷雨阵雨综合命中率达到71%,空报率阵雨（10%）小于雷雨（43%）,在不同地区和季节稍有区别;同时对浙江省2016年春夏两次典型大范围阵雨雷雨过程进行预报,效果很好。此方法不仅可以依据预报数据在短期内做出精细化降水性质分类预报,在中长期预报上也有表现力。     

Manganese ore deposits in Koira-Noamundi province of Iron Ore Group, north Orissa, India: In the light of geochemical signature

Several small Mn–Fe oxide and Mn-oxide ore bodies associated with Precambrian Iron Ore Group of rocks are located within Koira-Noamundi province of north Orissa, India. These deposits are classified into in situ (stratiform), remobilized (stratabound) and reworked categories based on their field disposition. Volcaniclastic/terrigenous shale in large geographic extension is associated with these ore bodies.The in situ ore bodies are characterised by cryptomelane-, romanechite- and hematite-dominating minerals, low Mn/Fe ratio (1.1) and relatively lower abundance of trace (1500–2500 ppm) constituents. In such type of deposits the stratigraphic conformity of oxides with the tuffaceous shale suggests precipitation of Mn and Fe at a time of decreased volcaniclastic/terrigenous contribution. The minor and trace elements were removed from solution by adsorption rather than by precipitation. Both Mn and Fe oxides when precipitated adsorb trace elements strongly but the partitioning of elements takes place during diagenesis. The inter-elemental relationship reveals that Cu, Co, Ni, Pb and Zn were adsorbed on precipitating hydrous Mn oxides and form manganates. Some of these elements probably get desorbed from Fe oxide because of their inability to substitute for Fe³⁺ in the lattice of its oxide. However, P, V, As and Mo were less partitioned and retained in Fe-oxide phase. Positive correlation between Al₂O₃ and SiO₂, MgO, Na₂O, TiO₂ and some traces like Li, Nb, Sc, Y, Zr, Th and U points to their contribution through volcaniclastic/terrigenous detritus of both mafic and acidic composition.The remobilized ore bodies are developed in a later stage through dissolution, remobilization and reprecipitation of Mn oxides in favorable structural weak planes under supergene environment. Increase in average Mn/Fe ratio (8) and trace content (5000–8500 ppm) by 5–2.5 orders of magnitude, respectively, or more above its abundance in adjoining/underlying protore is characteristic of these deposits. The newly formed Mn ores constituting lithiophorite, cryptomelane/romanechite and goethite get quantitatively enriched in traces like Cu, Co, Ni, Pb and Zn. Positive correlation between Mn, Li, Co and Zn is due to the formation of mineral of lithiophorite–chalcophanite group during redistribution and reconcentration of Mn oxide. P and V, which were present in Fe oxide, also get dissolved and reprecipitate with Fe oxyhydroxide in these ores. Some other elements like Y, Th and U show positive relation with Fe. This is probably due to leaching of these elements during chemical weathering of associated shale and getting re-adsorbed in Fe-oxyhydroxide phase.However, under oxidizing environment selective cations like Ba, K, etc. resorb from Mn-structure, resulting in the development of pyrolusite (Mn/Fe>20). In such transformation, trace metals from pyrolusitic structure expels out, resulting thereby in a considerable reduction in total trace value (<3000 ppm).The reworked ore bodies are allochthonous in nature and developed through a number of stages during terrain evolution and lateritisation. Secondary processes such as reworking of pre-existing crust; solution and remobilization; precipitation and cementation and transport, etc. are responsible for their development. Such deposits are usually very low in Mn/Fe ratio (3) and trace content (<2000 ppm).     

陕西省略阳县徐家沟铜矿床成矿地质特征及控矿因素

徐家沟铜矿床位于勉(县)-略(阳)-阳(平关)铜多金属矿化集中区中部的铜厂矿田西北部,矿体产于中上元古界郭家沟组中的片理化细碧岩带內,已圈定铜矿体13条,多为盲矿体.矿石主要自然类型为黄铁矿化-磁黄铁矿化-片理化细碧岩型,属于火山沉积-构造、岩浆改造型铜矿床.郭家沟组中的细碧岩为铜的主要矿源岩,细碧岩中的近东西向构造片理化带为矿质富集提供了富集通道和空间.铜厂闪长岩体为成矿提供了动力、热源和主要硫源,成矿受上述地层岩性、构造、岩浆岩因素联合控制.     

东秦岭钼矿带内碳酸岩脉型钼（铅）矿床地质 地球化学特征、成矿机制及成矿构造背景

东秦岭钼矿带位于华北板块南缘,NW-NWW向的固始―栾川深断裂带控制着钼矿床的空间分布.黄水庵碳酸岩脉型钼(铅)矿床的确定,为本矿带内已有碳酸岩脉型钼(铅)矿床(黄龙铺地区的大石沟、石家湾和桃园等)增添了又一新成员.本矿带不仅钼金属储量居世界已知单个钼矿带之首,而且碳酸岩脉和花岗斑岩两个成矿体系并存,亦是本区钼矿带的一大特色.业已查明,黄水庵和黄龙铺(大石沟)等碳酸岩脉型钼(铅)矿床的δ~(13)C=-5.3‰～-7.0‰,~(87)Sr/~(86)Sr=0.7049～0.7065.同时,方解石富含轻稀土(LREE/HREE=1.8～2.9).辉钼矿以富含Re(平均为110×10~(-6)～244×10~(-6))为特征.基于含矿碳酸岩脉方解石的Sr、Nd、Pb同位素比值(~(87)Sr/~(86)Sr对~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb对~(206)Pb/~(204)Pb和~(143)Nd/~(144)Nd对~(87)Sr/~(86)Sr)的关系图,我们初步判断本矿带区域陆壳之下可能存在有EMI(富集地幔Ⅰ),这些含矿碳酸岩脉是源于EMI的碱性硅酸盐-碳酸盐熔体-溶液结晶分异的产物,成矿金属Mo、Pb主要来自EMI.根据黄水庵和黄龙铺(大石沟)钼(铅)矿床的成矿年龄(Re-Os年龄分别为209.5 Ma和221 Ma),我们推断,碳酸岩脉型钼(铅)矿床形成于华北和扬子两大板块三叠纪碰撞造山后伸展阶段的晚三叠世时期,而在侏罗纪陆内造山晚期的伸展阶段,形成了晚侏罗-早白垩世的斑岩型和斑岩-矽卡岩型钼矿床(Re-Os年龄介于147～116 Ma).     

酒石酸异构体对EDTA间接滴定法测定矿石中三氧化二铝的影响

应用EDTA间接滴定法测定铝土矿、高岭土、黏土等矿石中的三氧化二铝,试验了不同种类的酒石酸掩蔽钛对三氧化二铝测定结果的影响。建议选择左旋体或右旋体酒石酸作掩蔽剂,尽量不要选择内消旋体酒石酸,更不能选择外消旋体酒石酸。采用酒石酸钾钠作掩蔽剂,三氧化二铝的测定结果良好,方法快速、简便。     

原子荧光光谱法测定铁矿石中的镉

样品经盐酸-硝酸-氢氟酸-高氯酸混合酸溶解,用原子荧光光谱法测定铁矿石中的镉。实验确定了最佳酸度、增感剂镍量、抗坏血酸量和硫脲量,并确定了仪器测定最佳条件,对干扰元素的允许量进行了研究。方法检出限为0.20μg/L,精密度为4.5%,线性范围为0~160μg/L,加标回收率为95.9%~103.7%。方法可应用于铁矿石的快速检测。     

青海玉树东莫扎抓铅锌矿床地质特征及碳氢氧同位素地球化学研究

东莫扎抓铅锌矿床位于青藏高原羌塘地体东北缘,是"三江"北段铅锌铜银多金属成矿带中的典型代表,对该矿床地质特征和成因类型的研究有助于理解区域铅锌铜银多金属成矿规律,对区域找矿具有重要意义.笔者通过详细的矿区地质考察、系统的矿石光薄片显微镜下鉴定和矿石中方解石的碳、氢、氧同位素分析测试,概述了东莫扎抓铅锌矿床的地质特征和成矿流体的碳、氢、氧同位素组成特征.东莫扎抓铅锌矿床矿体呈似层状展布,产状严格受到矿区逆冲断层的控制,赋矿围岩为上三叠统结扎群波里拉组灰岩和下一中二叠统开心岭群尕迪考组灰岩,发育强白云石化和弱硅化,矿物组合简单,主要为闪锌矿+方铅矿+黄铁矿+白云石+方解石+重晶石,矿石结构以皮壳状、草莓状等胶状结构和他形粒状结构为主,矿石构造为浸染状、角砾状、团块状和脉状.矿石中方解石的δ~(13)C_(V-PDB)值、δ~(18)O_(V-SMOW)值分别为δD_(V-SMOW)值分别为-1.8‰～+3.3‰、+6.1‰～+24.6‰和-137‰～-53‰,计算得到成矿流体的δ~(18)O_(流体)值为-0.5‰～+13.8‰.研究结果表明,东莫扎抓铅锌矿床的成矿流体主要来自盆地封存热卤水和大气降水,金属物质可能由区域流体在长距离迁移过程中通过与碳酸盐岩地层相互作用,以及淋滤含矿地层底部的火山岩而得来,成矿过程中伴随着碳酸盐岩的溶解作用,可能存在有机质的参与.据此,笔者将东莫扎抓矿床归为发育在碰撞造山带中受逆冲推覆断裂构造控制的类MVT铅锌矿床,并初步建立了东莫扎抓铅锌矿床的构造控矿模型.     

新疆晚古生代裂谷中同生断裂的控矿问题

新疆晚古生代裂谷中同生断裂具有明显的控矿作用,体现出"三同一体"和多组断裂构造交会的区域构造特征.以构造的不同级别、期次,对矿带、矿田、矿床予以控制,在构造交会和构造复合地段使矿田或矿床就位.由于构造的近等距性发育,从而制约矿田或矿床的近等距分布,更由于裂谷同生断裂的多次开合和地质动力性质转换,形成了多层次、多形式、多矿种、多类型、且具有矿种分带性的综合矿产链.     

黑龙江铁力兴安一带斑岩型钼矿资源潜力预测

黑龙江省铁力市兴安地区发育晚三叠世-早侏罗世的细粒二长花岗斑岩的U-Pb锆石LA-ICPMS年龄为195～201Ma,钼矿(化)体产于斑岩体的顶部或外接触带的中细粒似斑状二长花岗岩中,斑岩体的岩石学、矿化及围岩蚀变、地球化学异常特征,均显示出斑岩型矿床的特征.另外,在花岗质火山-侵入杂岩体中也见钼矿化,其异常模式虽显示出中温火山热液有关的特征,但从区域成矿演化特征来看,可能与晚三叠世-早侏罗世细粒二长花岗斑岩具有统一的构造-岩浆-成矿体系,具"同源不同环境、部位和同位、不同成矿期次"的特征.