余氯对大亚湾海区平鲷和黑鲷幼鱼的毒性研究

用含游离余氯、化合余氯的海水分别对大亚湾平鲷Rhabdosargussarba、黑鲷Sparusmacrocephalus浸毒处理30min和60min。结果表明,两种形态余氛对色的耗氧率有明显抑制作用,游离余氯对平鲷、黑鲷的48hLC50分别为0．19和0．18mg·L－1,48hLC1分别为0．07和0.06mg·L－1;化合余氯的48hLC50分别为0.56和0．60mg·L－1,48hLC1分别为0．21和0．24mg·L-1。游离余氯的毒性大约是化合余筑的6倍。游离余氯、化合余氯安全阈限估算值分别为0．09和0．28mg·L－1,稍高于48hLC1。     

An Investigation of CIO Photchemistry in the Chemically Perturbed Arctic Vortex

A new lightweight in situ instrument designed to measure ClO was flown on a balloon launched into the arctic vortex at dawn on February 3, 1995 at Kiruna, Sweden during the Second European Stratospheric Arctic and Mid-latitude Experiment (SESAME), together with instruments to measure ozone and long-lived tracers. Observations on ascent and descent at different solar zenith angles are compared to results from Lagrangian and box model calculations that assume the airmasses at similar potential temperatures had comparable photochemical histories. Between 20 and 22 km, in a region where ClO was significantly enhanced, a model constrained by currently recommended rate parameters significantly underestimates the abundances of ClO that were observed on ascent at high solar zenith angles, whereas the agreement is much better if a smaller ClO-Cl2O2 equilibrium constant, one inferred from previous ER-2 aircraft observations of ClO in the Arctic during nighttime, is assumed. On ascent, ClO is additionally enhanced in a narrow region between 20 and 21 km. We believe the most plausible explanation for this feature is rapid photolysis of OClO produced by the slow bimolecular reaction ClO + ClO over the 48 hours prior to the observations when the airmass was warmed to 225 K by adiabatic compression while in polar darkness. These results suggest that under special circumstances, OClO can be produced by a reaction other than one involving BrO, and, hence, OClO is not necessarily a universal proxy for BrO abundances in the perturbed polar vortex.     

氧和氯的对角线相似性

通常对角线相似性限于金属和准金属少数几例,该文利用离子极化概念等论证了氧和氯间的对角线相似性,丰富了“对角线相似性”的内容。把它扩展到非金属领域,对典型实例归纳论证。并用它对一些实验事实和现象归纳解释,进而对相关应用进行探讨     

Revisiting William Morris Davis and Walther Penck to Propose a General Model of Slope ‘Evolution’ in Deserts

Based on research from slopes on rhyolite domes of known age formed over a million‐year continuum in eastern California, a classic geomorphic debate is reconsidered and a general model of desert slope development proposed. This study examines steep (～25° to ～35°) boulder‐dominated slopes that include well, varnished, vertically oriented colluvial deposits. Such deposits are common throughout the arid southwestern United States. Basic field and isotopic dating methods are combined with two surface‐dating techniques, cosmogenic chlorine‐36 and rock varnish microlaminae, to produce a detailed slope development history with broad implications for geomorphic theory that includes the unresolved geomorphic debate between Walther Penck and William Morris Davis. Slopes in this study are dominated by the on‐going desert slope processes of debris flows and in‐situ grain disintegration as evidenced by active debris flow features, terminal Pleistocene ages of microlaminae, and chlorine‐36 ages progressively younger than potassium‐argon ages for slope genesis. Results also indicate that slopes retreat in a parallel fashion as postulated by Penck. Furthermore, the deposits do not exhibit significant changes in grain size, shape, or angularity from genesis to ～0.6 Ma but change markedly after that time possibly indicating a geomorphic threshold between ～0.6 and ～1 Ma, or episodic erosional events throughout the mid to late Pleistocene.     

桥面铺装低掺聚丙烯纤维混凝土耐久性试验与分析

试验研究以本地化的材料,针对寒区桥面铺装这一特殊应用领域要求进行低掺聚丙烯纤维混凝土配合比设计及优选。然后对不同掺入量组成的低掺聚丙烯纤维混凝土的冻融循环、冻融-氯盐共同作用下的耐久性试验研究,并对试验结果进行分析评价。     

Effects of a thermal discharge from a nuclear power plant on phytoplankton and periphyton in subtropical coastal waters

Effects of elevated water temperatures and residual chlorine from a thermal discharge at a coastal nuclear power plant on the biomass and productivity of periphyton and phytoplankton were determined in subtropical Taiwan. Phytoplankton chlorophyll a, but not productivity, was significantly lower in the outlet region than in the intake region. Periphyton chlorophyll a was significantly greater in the outlet region than in the intake region. Nevertheless, periphyton productivity was negatively correlated with water temperature in the outlet region. A distinct difference in periphyton community composition was also detected between the two regions. Chlorination experiments showed that a chlorine concentration of 0.2 ppm greatly suppressed phytoplankton productivity, regardless of whether the water temperature was elevated or not. However, periphyton productivity was little influenced by a chlorine concentration of < 0.5 ppm. Our results suggest that phytoplankton productivity was greatly affected by residual chlorine, but periphyton productivity was more affected by elevated water temperatures.     

Production of methyl chloride and methyl bromide in laboratory cultures of marine phytoplankton

Laboratory cultures of three phytoplankton species (Phaeodactylum tricornutum, Phaeocystis sp., Thalassiosira weissflogii) were tested for methyl halide (monohalomethane) production by sparging and cryotrapping coupled with GC-ECD detection. Both axenic and xenic cultures were tested under various nutrient regimens. Production of methyl bromide (CH₃Br) and methyl chloride (CH₃Cl) was observed in all cultures. Methyl iodide (CH₃I) production was also observed but could not be quantified due to Chromatographic interference. No consistent differences in production rates were observed between axenic and xenic cultures or between nutrient regimens. Methyl halide production was not directly dependent on photosynthesis. Within each species, total methyl halide production was most closely correlated with biomass, measured as utilized nitrate (ΔDIN) or Chl a. Among the three species, Phaeocystis sp. had the highest production rates and T. weissflogii the lowest. In all cases, the biomass-normalized production rates were only a fraction of the levels needed for the ocean to constitute a significant global source of either CH₃Cl or CH₃Br. However, it must be noted that these data comprise results from a limited number of species and a limited range of conditions.     

模拟电厂温排水温升和游离余氯对亚心形扁藻生长影响的研究

以亚心形扁藻(Platymonas subcordiformis)为受试藻种,模拟温升和游离余氯条件,研究浮游植物对核电厂温排水的生态响应。结果表明,春秋季温升对其生长影响较小,而在夏季,其生长受到显著抑制。亚心形扁藻对游离余氯非常敏感,0.1 mg/L游离余氯既能抑制其生长,抑制作用随着游离余氯浓度的升高而增强。温升会加剧游离余氯的抑制作用,4℃温升和0.1 mg/L游离余氯联合作用对亚心形扁藻的抑制效果明显增加。由于温升和游离余氯的联合作用,即使在离排口较远的水域,仍然会导致亚心形扁藻数量减少。     

VARIATIONS IN ISOTOPIC COMPOSITIONS OF CHLORINE IN EVAPORATION-CONTROLLED SALT LAKE BRINES OF QAIDAM BASIN，CHINA

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含氯消毒剂在水环境中的次生产物及其致突变性研究

通过 GC/MS法对池塘在用含氯消毒剂消毒前后水体中有机物的鉴定比较 ,发现含氯消毒剂在水环境中的主要次生产物为三氯甲烷 ,其生成量与消毒剂的用量、作用时间、反应温度、p H及光照等有关。这种次生产物具有一定的致突变活性 ,因此在养殖生产中必须严格控制消毒的使用量和使用条件 ,尽可能消除其不利影响