深厚软土场地基岩地震动反演——以天津波为例

根据天津波地表加速度记录和相应实测场地钻孔资料,采用等效线性化方法模拟土体非线性,进行了深厚软土场地基岩地震动反演,研究了频率截断对深厚软土场地基岩地震动反演的影响,为天津波地表加速度记录提供了相应的基岩地震动输入。研究表明:不同截断频率情况下,反演得到的基岩地震动峰值和反应谱曲线形状均相差悬殊,但反演后再正演所得到的地面运动与原地表记录相比,加速度时程曲线形状和峰值大小、反应谱曲线形状和峰值大小均非常接近;可根据工程需要对地表加速度记录进行不同频率的截断,反演得到所需强度的基岩地震动。     

Geobotanical and biogeochemical reconnaissance of the ultramafics of Central Iran

In Iran, ultramafic rocks cover substantial areas at many locations in the country. These rocks consist predominantly of peridotite which has been serpentinized to some degree. Anarak and Nain are two ultramafic areas in Central Iran comprising about 180 and 270 km², respectively, located in a coloured melange zone. There is little information available regarding the geobotany and biogeochemistry of these areas. They have a dry climate, with low rainfall and high temperatures in summer which encourages mostly annual and perennial herbaceous types of plants. In this paper, we report a reconnaissance study of these two ultramafic areas of Iran. Soil analysis of total elements indicates that typical concentrations of Ni, Cr, Co, Mn, Fe, Mg and Ca are about 1500, 300, 75, 800, 45.000 150.000 and 2000 μg g^− 1, respectively. During this study 176 plant species were collected, belonging to 29 families. The species diversity at Anarak is more than at Nain, possibly due to microclimatic differences and a greater precipitation. The number of plants endemic to ultramafic soils of these two areas is very low. The herb Cleome heratensis (Capparaceae) appears to be an indicator of ultramafics in Central Iran. Populations of this plant cover quite extensive areas during summer and autumn when there is no rainfall. Analysis of the dry matter of the leaves of all plants collected did not reveal any hyperaccumulator of nickel or any other ‘serpentine’ metals. The ultramafic endemic plant C. heratensis contained low concentrations of all metals and thus it possesses exclusion mechanisms to restrict excessive metal uptake. The Mg/Ca ratio for some plants collected is high—up to 4.9. This initial survey suggests that a more complete investigation of the ultramafic areas of Iran would be valuable.     

全二维气相色谱-电子捕获检测器测定复杂基质土壤中24种有机氯和拟除虫菊酯类农药

目前针对环境样品中有机氯和拟除虫菊酯类农药的检测方法主要有气相色谱法和气相色谱-质谱法（GC-MS）,由于气相色谱法采用电子捕获检测器从而具有较高的灵敏度,在污染物的环境行为研究中得到广泛应用,GC-MS法的定性效果好,但检测灵敏度相对偏低。本文研究了2018年土壤详查江苏地区样品中有机氯农药和拟除虫菊酯的残留状况,结果显示,即使经过多次净化仍有20%的样品存在假阳性或基质干扰现象。为了提高定性准确度,同时保证检测灵敏度,实验建立了复杂基质土壤中20种有机氯农药和4种拟除虫菊酯的全二维气相色谱-电子捕获检测器检测方法,最终选择中等极性的TG-35MS为第一色谱柱,非极性的（DB-1）为第二色谱柱,将鲜样与无水硫酸钠混合均匀后,以正己烷-丙酮（1：1,V/V）为提取剂进行索氏提取,采用全二维气相色谱-电子捕获检测器进行检测,外标法定量。各物质的质量浓度均在1.0~500μg/L内与其峰面积呈线性关系,相关系数均大于0.995,检出限为0.02~0.17μg/kg。用标准加入法进行回收实验,测得回收率为80.7%~103.5%,测定值的相对标准偏差（n=6）为1.84%~10.12%。本方法将高灵敏度检测器与全二维色谱相结合,在保证检测灵敏度的同时增加了峰容量,有效去除了基质干扰。相比2018年土壤详查参考方法HJ 835—2017的检出限0.02~0.09mg/kg（全扫模式）,本方法检出限显著降低,且操作简单,可为复杂基质样品中的痕量超痕量检测提供参考。     

Nickel speciation in Sebertia acuminata,a plant growing on a lateritic soil of New Caledonia

Nickel speciation in a nickel hyperaccumulating plant (Sebertia acuminata) and its associated soil of southern New Caledonia was studied using various analytical methods. The soil is formed of iron oxides (goethite, hematite), which contain almost all the nickel. The available nickel is probably linked to the organic matter in the litter. Sebertia acuminata, acts as a nickel pump, and concentrates the metal in its leaves. It partitions nickel and silica; nickel is concentrated in the cells (probably in the vacuoles) as organometallic complexes, whereas silica forms the framework of the cells, and the phytolithes. A thorough study of these plants seems essential in order to define the soil–plant relations, and to propose appropriate ways for ecological restoration. To cite this article: N. Perrier et al., C. R. Geoscience 336 (2004).     

Alluvial soils as subgrade material: Laboratory and statistical evaluation

In India, rural roads are constantly being constructed. To ensure proper design of rural roads, it is desirable to have an appropriate selection of design parameters. The California bearing ratio (CBR) method of pavement design is the most commonly used method employed for the foundation design of rural roads. In the CBR method, the CBR value of the subgrade soil is critical in deciding the overall thickness of the pavement. Additionally, for good drainage, a typical specification for the pavement foundation design requires the value of permeability coefficient of the subgrade material to be specified. Thus, permeability and CBR constitute two important parameters in the design and assessment of long-term performance of the pavement. In this study, laboratory investigation has been carried out on a number of soil samples procured from a roadwork project site. Preliminary tests, such as index tests and particle size distribution tests, useful for soil classification, were followed by light compaction, CBR and variable head permeability tests. Further, observations from the laboratory investigation are statistically analysed to study correlations among various parameters. Because the predominant soil type found in the study area is alluvial, this study also highlights the suitability of alluvial soils as pavement subgrade material.     

基于离散元方法的不同挡墙变位模式下有限土体主动土压力研究

为研究挡墙变位模式以及墙后填土宽度对无黏性有限土体主动土压力的影响,在不同墙后填土宽度条件下分别开展了挡墙平动(T)模式、绕墙底转动(RB)模式以及绕墙顶转动(RT)模式的离散元模拟。根据离散元模拟结果对主动土压力、墙后土体破坏模式以及应力状态进行了分析。研究结果表明:挡墙变位模式和墙后填土宽度的变化使得土体破坏模式和应力状态发生变化,引起主动土压力大小及分布的差异。T与RB模式滑动土楔中内摩擦角调动值会相对初始值增加,且T模式滑动土楔中会出现小主应力拱。RT模式较为特殊,在填土宽度较小时,其应力状态与T模式相似;在填土宽度较大时,滑动土楔上部会出现内摩擦角调动值相对初始值减小的区域,并出现大主应力拱。     

土性指标和地层性质对水泥搅拌桩成桩质量的影响

从水泥土的固化机理出发,结合水泥搅拌桩桩身标准贯入试验和水泥土配合比试验,分析讨论了土性指标、土质条件和地层性质对水泥搅拌桩成桩质量的影响。     

Geochemical Atlas of the Slovak Republic at a scale of 1:1,000,000

The Geochemical Atlas of Slovak Republic (49,036 km²) at a scale of 1 : 1,000,000 was compiled during 1991–1995 together with maps of associated geochemical and ecological features at a scale of 1 :200,000. Investigations were aimed at the evaluation of concentrations and distributions of Al, As, Ba, Be, Ca, Ce, Co, Cd, Cs, Cr, Cu, Fe, Ga, Hg, K, La, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Rb, Sb, Se, Sn, Sr, Th, U, V, W, Y, Zn, Zr in groundwater (16,359 samples), stream sediments (24,422 samples), rocks (3839 samples), soils (9892 samples from 4946 profiles; A and C horizons of each profile were sampled) and forest biomass (the foliage of the forest tree species from 3063 plots was sampled). In groundwater field measurements of temperature, pH, conductivity, dissolved O₂, acidity, alkalinity were done. The evaluation was oriented to the natural radioactivity of the Slovak territory as follows: rocks (K, U, Th, U_tot and dose rate, 15,573 reference spectrometric points), radon risk and water (U_nat, ²²⁶Ra, ²²²Rn; 5271 samples). The main objective of the Geochemical Atlas was to construct single-component maps showing concentrations of chemical elements, compounds and measured parameters in the researched media of Slovakia at a scale of 1 : 1,000.000 and to create interactive databases of chemical composition and/or measured parameters of groundwater, biomass, rocks, soils, stream sediments and natural radioactivity, for the entire territory of the Slovak Republic. The single-component maps are not constructed in the part ‘Rocks’, where all the main rocks types of Slovakia are presented in the ‘Map of lithogeochemical rock types of Slovakia at a scale of 1: 500,000’. The edition of six atlases has been planned. In 1997 the first three atlases will appear (Groundwater, Biomass, Natural Radioactivity). Publishing of last three atlases (Rocks, Soils, Stream Sediments) is planned for 1998. Since the analytical works on stream sediments were finished during 1997, it was not possible to present here the results of that part of the Geochemical Atlas.     

土壤中溶质运移模拟的理论与应用*

可溶性化学物质在土壤中的运移和分布一般可以反映出多孔介质中溶质随着水分运(流)动的规律。文中系统地回顾了近二十年来土壤中溶质运动理论的发展和有关模型的应用概况,以期对地下水污染、海水入侵、水盐运动等溶质运移模拟的理论和应用问题进行较全面的分析;讨论了水动力学弥散、宏观弥散、层状介质中的弥散、多组分溶质运移和非饱和带中溶质运移等问题,以及描述土壤中溶质迁移的主要模型和模拟方法。     

筋土界面参数测试方法合理选择研究

筋土界面相互作用机理和方式随加筋土结构不同以及同一加筋土结构的位置不同而有所区别,相应参数的测试方法也应不同。根据国内外筋土界面参数测试方法的最新研究成果,结合工程实践发展需要和筋土界面相互作用关系特点,建立了筋土界面参数测试方法选择原则,为工程设计和研究工作中合理选择界面参数测试方法提供了科学的参考依据。