新疆博格达山北麓白杨河剖面页岩地球化学特征及其地质意义

通过博格达山北麓白杨河剖面芦草沟组页岩的地球化学特征的综合研究,讨论了芦草沟组页岩的元素富集特征和沉积环境以及源区物源特征和构造背景。结果表明:1研究区页岩P元素极为富集,这受控于页岩中凝灰质火山灰夹层的广泛发育;2对比于世界页岩微量元素分布,白杨河页岩相对富集Li、B、Pr、Tb、Dy、Ho、Er、Tm和Lu元素,其他元素相对亏损;3白杨河剖面页岩地化参数揭示芦草沟组自下而上气候由温湿向干热转变,进而引起水体由淡水向咸水的转变和还原程度的进一步加强;4物源区遭受低级-中等风化程度,物源类型主要为长英质火成岩,其次为铁镁质火成岩;5物源区大地构造背景以大陆岛弧-活动大陆边缘构造背景为主。     

西藏冈底斯尼木后碰撞花岗岩的岩浆混合作用:显微结构证据

岩浆混合过程中不同熔体之间的相互作用会影响晶体的成核与生长,形成矿物内部复杂的成分变化,以及矿物之间的不平衡结构。尼木二长花岗岩位于冈底斯岩浆岩带中部,是代表性的形成于后碰撞构造演化时期的花岗岩体。本文对其中的斜长石与角闪石颗粒进行了详细的结构和成分分析,揭示了斜长石中的港湾状、浑圆状、筛孔状熔蚀结构以及斜长石成分的突然变化和角闪石包裹黑云母的不平衡结构,并探讨了它们的成因以及相关的岩浆混合作用。分析结果显示,斜长石中突变环带的An含量为37.6~40.6,熔蚀环带的An含量为48.2~59.5,均高于两侧斜长石的An含量(18.4~26.4),表明在形成这些结构时有外来基性岩浆的混合使得岩浆成分发生了突变。样品中的部分黑云母被自形的角闪石包裹,黑云母呈浑圆状并且具有港湾状的熔蚀边,这可能是基性岩浆的混合作用使得岩浆的温度升高导致黑云母发生部分熔融,混合后的岩浆在黑云母周围继续结晶形成角闪石。这些显微结构为揭示冈底斯岩浆岩带的岩浆混合作用提供了新证据。     

山东省重要地质遗迹自然区划研究

地质遗迹区划是地质遗迹资源保护的基础,该文根据山东省重要地质遗迹资源的空间分异和山东省大地构造二级构造单元,划分出3个地质遗迹大区,再以其自然分布规律、遗迹形成时间、空间、成因和地质构造单元的关联性进一步划分出8个地质遗迹区和24个地质遗迹集中区,从而建立了山东省重要地质遗迹自然区划系统,亦为地质遗迹保护提供了可靠的科学依据。     

云南磷铝石谱学特征研究

使用电子探针、X射线粉晶衍射仪、傅里叶变换红外光谱仪、激光拉曼光谱仪、紫外可见分光光度计等仪器,对最近在云南发现的一种达到宝石级别的磷铝石进行了化学成分、矿物组成、红外吸收光谱、拉曼光谱、紫外可见吸收光谱等方面的研究。化学成分分析结果表明,该磷铝石的主要化学成分为P和Al,并含有少量的Fe和V;X射线粉晶衍射结果显示,该磷铝石的矿物成分主要为磷铝石,杂质较少;红外光谱与拉曼光谱分析均检出磷酸根基团的特征峰,红外光谱分析还显示有结晶水与结构水的存在;紫外可见吸收光谱在300和420 nm附近的吸收归属于Fe3+,630 nm附近较宽缓的吸收带由Fe3+和V3+共同产生。并将磷铝石与绿松石进行了谱学方面的对比分析,以便更好地区分两者。     

缅甸与莫桑比克红宝石的元素含量及紫外可见光谱学特征对比研究

采用镜下观察、激光剥蚀电感耦合等离子体质谱、紫外-可见吸收光谱等观察测试方法,对缅甸和莫桑比克红宝石的常规宝石学、包裹体、化学元素含量及紫外光谱特征进行了系统的对比研究。结果表明,缅甸红宝石在紫外荧光灯下呈现较强的红色荧光,内部含有互为60°夹角定向排列的短针状金红石、"糖浆状"构造等特征包裹体,具有低Fe、高V、高Ga的微量元素特征,紫外区吸收截止边小于320 nm,且694 nm处的荧光较强。莫桑比克红宝石在紫外荧光灯下荧光较弱,内部可见双晶面、无序排列的金红石和角闪石晶体等特征包裹体,具有高Fe、低V、低Ga的微量元素特征,紫外区吸收截止边在350 nm附近。上述性质可用作区分缅甸和莫桑比克红宝石的标志性识别特征。     

Geochemical constraints on the distribution of trace elements and volatiles in fluorapatite from the Panasqueira tin-tungsten deposit (Portugal)

A large, euhedral crystal of fluorapatite (ca. 19.5 × 20.0 mm) from the Panasqueira tin-tungsten deposit (Portugal) was investigated in terms of the distribution of trace elements by using several microanalytical techniques. The studied material represents almost pure fluorapatite with minor amounts of other cations (mainly Sr, Mn, REE and Fe), OH and Cl. Particular interest was given to the distribution of rare earth elements with respect to the crystallographic orientation. A broad range of analytical techniques were used, including optical microscopy coupled with cathodoluminescence imaging, electron probe microanalysis (EPMA), laser ablation – inductively coupled plasma mass spectrometry (LA-ICPMS), Raman microspectroscopy, and simultaneous thermal analysis coupled with mass spectrometry. The investigated crystal consists of the main crystal with a distinct core and rim (Ap_2core and Ap_2rim, respectively), which grew on a previous, euhedral crystal (Ap₁). The fluorapatite demonstrates various types of zoning: regular oscillatory, irregular, and internal sectoring, which is also reflected in trace elements concentrations. The rim Ap_2rim has lower concentrations of Mn, Sr and Fe, and significantly higher concentrations of REE compared to the core Ap_2core and older crystal Ap₁. Furthermore, the rim Ap_2rim is strongly depleted in Th, U and Pb. The entire crystal shows elevated Eu contents, expressed as a strong positive anomaly in chondrite-normalized REE patterns. With regards to the volatiles, F concentrations are constant in Ap₁, Ap_2core and Ap_2rim, whereas Cl is below the EPMA detection limit. The Ap_2rim was the only part of the investigated material containing OH and CO₃, which were observed in the Raman spectra. Furthermore, part of the crystal Ap_2core is extensively altered, likely due to fluid-induced metasomatic processes. LA-ICPMS U-Pb dating yielded highly discordant dates due to common Pb content. A lower intercept age of 297 ± 13 Ma (MSWD = 0.13) indicates the age of the fluorapatite crystallization. The overall analytical data constrain growth and post-growth processes, including crystallization of Ap₁ and Ap_2core, which both have typical hydrothermal Sn-W deposit characteristics, whereas Ap_2rim is related to a carbonate stage of the mineralization in the Panasqueira deposit.     

Comparative Study of Acid and Alkaline Stimulants with Granite in an Enhanced Geothermal System

The Enhanced Geothermal System (EGS) is an artificial geothermal system that aims to economically extract heat from hot dry rock (HDR) through the creation of an artificial geothermal reservoir. Chemical stimulation is thought to be an effective method to create fracture networks and open existing fractures in hot dry rocks by injecting chemical agents into the reservoir to dissolve the minerals. Granite is a common type of hot dry rock. In this paper, a series of chemical stimulation experiments were implemented using acid and alkaline agents under high temperature and pressure conditions that mimic the environment of formation. Granite rock samples used in the experiments are collected from the potential EGS reservoir in the Matouying area, Hebei, China. Laboratory experimental results show that the corrosion ratio per unit area of rock is 3.2% in static acid chemical experiments and 0.51% in static alkaline chemical experiments. The permeability of the core is increased by 1.62 times in dynamic acid chemical experiments and 2.45 times in dynamic alkaline chemical experiments. A scanning electron microscope analysis of the core illustrates that secondary minerals, such as chlorite, spherical silica, and montmorillonite, were formed, due to acid-rock interaction with plagioclase being precipitated by alkaline-rock interactions. Masking agents in alkaline chemical agents can slightly reduce the degree of plagioclase formation. A chemical simulation model was built using TOUGHREACT, the mineral dissolution and associated ion concentration variation being reproduced by this reactive transport model.     

不同地质建造类型的生态环境功能特征——以西昌地区为例

地质建造背景可以直接反映该地区的形成演化过程、物质组成和地理条件,直接或间接地影响基岩上的生态环境。小范围内生态环境效应由地质建造直接控制,再由不同的气候条件、人类活动进行改造。土壤中的营养元素基本继承于母岩,而气候条件和人类活动同样会对土壤的物理性质、化学性质形成扰动。以中国地质调查局生态地质调查工程之大凉山区生态地质调查项目为依托,以沉积建造特征、空间分布、大地构造属性等因素为基础,将西昌地区划分为11个地质建造单元。通过详细的野外调查和数据分析,对西昌地区不同地质建造单元进行研究,认为建造单元上的生态地质环境存在明显的差异性,地质建造背景直接制约了成土母质及土壤的物理化学性质,营养元素在成土母质和土壤之间的迁移存在明显的继承性。同时,不同的地质建造单元和不同的地理地貌特征共同决定了不同地质建造单元的生态功能属性。研究成果为下一步开展生态地质调查提供依据和思路。     

泰青威天然气管道临朐段水毁灾害分布特征与风险评价

对泰青威天然气管道临朐段地质灾害发育特征进行调查研究发现,临朐段地质灾害类型主要为水毁灾害,具体可分为坡面水毁、河沟道水毁和台田地水毁。野外地质灾害实地调查临朐段管道沿线共发现地质灾害15处,其中坡面水毁点6处,河沟道水毁点4处,台田地水毁点5处。采用定性与半定量相结合的评价方法对其进行地质灾害风险评价,结果表明: 地质灾害风险等级较高的有1处,占6.66%; 风险等级中等的有4处,占26.67%; 风险等级较低的有10处,占66.67%。根据管道沿线地形地貌、地质灾害发育密度、风险等级等因素,划分地质灾害中易发区61 km,低易发区10 km,管道沿线以地质灾害中易发区为主。最后,针对不同类型、不同风险等级地质灾害提出了相应的防治消减措施,为后期管道安全运营和风险整治决策提供了有效的技术依据。     

新疆哈密大南湖地区层间氧化带特征研究

新疆大南湖地区的层间氧化带发育层位为中侏罗统西山窑组第二、三岩性段砂砾岩,以褐黄色为主;层间氧化带具多层性,埋深31～343 m,厚度2～138 m;层间氧化带分为氧化带、氧化-还原过渡带和原生带;铀矿体主产于氧化-还原过渡带中;新构造运动形成的最终构造格架控制了层间氧化带的发育方向和基本形态,不同粒度且非致密结构的砂砾岩和冲积扇相、辫状河相沉积则决定层间氧化带发育的厚度和规模,由南向北流的承压地下水造成区内层间氧化带前锋线呈向北延伸的趋势.