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101.
Disequilibrium for Ca during growth of pelitic garnet 总被引:14,自引:1,他引:14
Compositional zoning in hundreds of almandine-rich garnets in amphibolite by facies micaceous quartzites from the Picuris Range, north-central New Mexico USA, indicates that although Mn, Mg and Fe achieve chemical equilibrium at hand-sample scale during garnet growth, Ca does not. Instead, Ca concentrations at the surface of growing garnets appear to depend strongly on kinetic factors that govern the local chemical environment, yielding disequilibrium for Ca at scales larger than the region immediately surrounding an individual porphyroblast. Detailed zoning profiles were obtained for 371 garnet crystals in a small volume of a single sample of garnetiferous quartzite, and core analyses were made of 97 additional crystals. Each analysis was made on a section that passed precisely through the morphological centre of the crystal, located by means of 3-D imagery from computed X-ray tomography. The data reveal strong correlations between crystal size and concentrations of Mn, Mg and Fe (but not Ca) in garnet cores; a relationship between crystal size and isolation; rigorous cross-correlations among concentrations of Mn, Mg and Fe (but not Ca); and systematic variations in Ca concentrations as a function of crystal size and core composition that are anomalous in comparison to the behaviour of the other divalent cations. We interpret these observations as the result of thermally accelerated diffusion-controlled garnet growth, in circumstances that promoted rapid intergranular diffusion and thus rock-wide equilibration of Mn, Mg and Fe, but that prevented equilibration at similar scale for Ca because of its more sluggish intergranular diffusion. The anomalous behaviour of Ca is made evident in these garnets by the presence of sharp spikes in Ca concentration, which are demonstrably not a consequence of any simultaneous rock-wide event, such as a change in pressure, temperature, or some other intensive parameter. Instead, Ca concentrations probably reflect the local extent of reaction in the immediate vicinity of each porphyroblast. To the degree that such kinetic factors introduce departures from chemical equilibrium for Ca, thermobarometric estimates that involve grossular contents of pelitic garnet will be in error. 相似文献
102.
Javier Castro-Larragoitia Utz Kramar Harald Puchelt 《Journal of Geochemical Exploration》1997,58(1):81-91
The Ag---Pb---Zn---Cu---Au mining district of Santa María de La Paz has been extensively exploited for approximately 200 years. Consequences of these activities are several deposits of tailings with high As and heavy metal concentrations, which are completely unstable. The climate is semiarid and as the dumps have no protective cover, material from the dumps is dispersed by strong winds. It is also washed out during seasonally heavy rainfalls. By these processes approximately 100 km2 of surrounding have been contaminated by dump material. The As and heavy metal content of the soils was determined as well as their level in crops (Zea Maize) from agricultural lands in the vicinity of the dumps. In the direction of prevailing winds concentrations up to 1000 ppm Zn, 400 ppm Pb, 16 ppm Cd, 550 ppm Cu and 300 As have been detected in top soils. Using fuzzy cluster analysis the different contamination sources could be identified. Grains of corn from contaminated sites showed no critical concentrations, but leaves which are also used tor fodder, have As-concentrations up to 20 ppm. 相似文献
103.
榴辉岩中铁铝榴石的测定方法研究 总被引:3,自引:1,他引:3
对国内主要矿区铁铝石榴子石纯矿物中铁的价态规律进行了研究。证明其所含Fe均以Fe^2+为主,其质量分数在83-94,并将Fe^2+这特征性成分用于某地榴辉岩中铁铝榴石的间接测定,获得结果与焙烧磁化-磁选法一致且精度好,较磁化法简便,快速。 相似文献
104.
遥感技术获取的可见光、红外及微波信息,可以对化工企业及化学矿山环境污染(水、粉尘、大气、废渣污染等)及环境地质灾害(滑坡、泥石流、地面塌陷等)进行实时动态监测,并可获得较高的社会经济效益,达到地面环保及常规环境地质工作难以达到的效果。特别是对重点大中型化工企业及化学矿山建立环境遥感信息动态监测系统,可以为国家决策部门及时准确地提供环境治理和改造的依据。 相似文献
105.
论湖南柿竹园多金属矿床成岩成矿的化学模式─—与毛景文先生等商榷 总被引:2,自引:0,他引:2
从湖南柿竹园多金属矿床成岩成矿的事实出发,用化学基本定律对其矽卡岩的形成,蚀变及成岩成矿的化学反应方程式进行研讨,建立了比较符合矿床实际与地球化学理论的化学模式。认为地球科学与化学是在相互交叉,相互渗透,相互促进中共同发展的。 相似文献
106.
107.
面向21世纪的煤化工 总被引:8,自引:0,他引:8
煤炭是中国的主要能源和资源,但同时也是主要的污染源。从保护环境、合理利用有限的化石资源的角度和中国的具体国情考虑,应该大力开发温和化高效煤的新工艺,使煤炭资源逐步由能源型利用转化为材料型利用,近年来,我们在煤的溶剂萃取,脱硫降灰机理,煤相关模型化合物反应,煤焦油中稠环芳香族化合物的分离精制,功能性高分子单体合成及一氧化碳高效吸附剂的制备等方面做了大量的研究工作,结合这些研究工作,本文介绍了煤化工的 相似文献
108.
本文剖析了柿竹园钨锡钼铋矿床地勘阶段地质观察粗浅,勘探投入超前,探明储量积压、B+C级储量比例偏大等不合理的勘查工作及其原因。在此基础上,探讨矿区合理的勘探程度,储量比例及由此带来的经济效益。 相似文献
109.
陕西洛川黄土沉积物中稀土元素及其它微量元素的化学淋滤研究 总被引:35,自引:0,他引:35
本文采用化学淋滤的方法对洛川黄土沉积物的酸溶和酸不溶相中稀土元素以及其它微量元素的分布分配特征进行了系统的分析。 相似文献
110.
Chen Jun Wan Hongtao Department of Earth Sciences Nanjing University Nanjing Jiangsuand Lu HuayuKey Lab. of Loess Quaternary Geology Chinese Academy of Sciences Xi an Shaanxi Liu Xinzhu 《《地质学报》英文版》1996,70(3):290-302
The chemical leaching method is used for a systematic analysis of distribution characteristics of acid-soluble and acid-insoluble REE and other trace elements from the Luochuan loess deposits. The study shows that the acid-insoluble phase in loess and palaeosol is a stable component of old aeolian dusts and is characteristic of the provenance; the acid-soluble phase is the unstable component in the weathering pedogenic process and reflects rock-forming features after accumulation of aeolian dusts. The acid-insoluble REE and acid-soluble Sr and Pb can be used as geochemical indicators respectively to trace the provenance characteristics and the weathering pedogenic process. 相似文献