青藏高原东部长江流域盆地地表化学剥蚀通量剥蚀速率大气CO2净消耗率研究

2000~2002年期间,笔者对青藏高原东部长江流域溶质载荷分别进行了取样分析并对流域盆地化学剥蚀通量、剥蚀速率和大气CO₂净消耗率进行了计算。结果表明,流域盆地化学剥蚀速率以河源区楚玛尔河最高为2.34×10⁶mol/a/km²,沱沱河最低为1.40×10⁶mol/a/km²,四大支流雅砻江为1.69×10⁶mol/a/km²,金沙江为1.74×10⁶mol/a/km²,大渡河为1.57×10⁶mol/a/km²,岷江为1.88×10⁶mol/a/km²;流域盆地ФCO₂估算结果以大渡河最高为101.81×10³mol/a/km²,楚玛尔河最低为7.55×10³mol/a/km²,金沙江为44.38×10³mol/a/km²,雅砻江为69.64×10³mol/a/km²,岷江为81.90×10³mol/a/km²,沱沱河为21.90×10³mol/a/km²。并对长江流域地表化学剥蚀速率主要控制因素进行了讨论。     

Excel97在多目标地球化学调查分析质量管理中的应用

采用中文版Excel97设计和实现了多目标地球化学调查样品分析质量管理。该系统只要建立好相应的分析数据库，就可自动获得分析报告、报出率、内检样检查、标样检查、标样监控图等监控数据。     

旅游产业生长点的SGGT模式与空间演化——以张家界为例

界定了旅游产业生长点的概念,借鉴“路径依赖”理论重新诠释旅游地产业成长路径,提出具有普遍性SGGT模式,以张家界旅游产业生长点为例,具体分析了SGGT和空间演化过程及其动力机制。结果发现:①历史与现实是武陵源旅游生长点形成的基础,需求与培育是旅游生长点萌发的关键因素,创新与拓展是旅游生长点成长的保证,蜕变促进了旅游生长点成为旅游产业增长极;②张家界国家森林公园、天子山和索溪峪三个旅游生长点,通过“路径创造”,实现了行政管辖权的统一,后被列为世界遗产地,成为张家界旅游产业的核心生长点;③在旅游产业“集聚力”和世界遗产地管控的驱动下,天门山成为张家界新的生长点;④武陵源和天门山两个生长点的形成,是张家界旅游产业集聚和“路径创造”共同作用的结果,也拓展了张家界旅游产业的成长空间。本文有利于为旅游地政府和企业从旅游产业生长点视角理解旅游产业成长路径,更为世界遗产地旅游产业可持续发展提供科学指导。     

长江沿江地区化工产业空间格局演化及影响因素

基于企业数据和空间计量方法,探讨了长江沿江地区2000—2013年化工产业空间格局演化及影响因素。结果表明：化工产业主要分布在上海市和江苏沿江地区;中上游部分地区化工产业呈现明显的增长势头,由3个主要热点区发展到20余个不同规模大小的分布热点,成为化工产业新兴“增长极”;城市主城区化工产业减少而远郊区县增加,分布热点变化也反映了化工产业“郊区化”“园区化”的过程;相对低端基础的行业呈现集聚趋势,其中肥料业集聚明显;相对高端精细的行业呈现扩散趋势,其中合成材料业分散化明显;地区化工产业增长受到环境规制、外商投资、交通区位等因素显著影响,外商投资和交通区位具有显著的促进作用,而环境规制呈现显著的抑制效果。     

岱海的"中世纪暖期"

内蒙古岱海沉积物近2200a来Rb/Sr比值、CaCO3和有机碳含量的变化展现了包括中世纪暖期（MWP）及小冰期（LIA）等典型气候事件在内的环境演化过程,总体表现为暖期的沉积物Rb/Sr比值低,冷期的则高：CaCO3和有机碳含量则相反。这里,以单一流域化学风化记录表明我国北方存在明显的中世纪暖期,发生时间约900－1200aB.P..主要环境特征表现为流域化学风化的显著增强（低Rb/Sr比值）、生物生产力逐步提高（高有机碳）、湖泊水位大幅度抬升的湖泊沉积记录,其间经历的化学风化是近两千年内最强的,并且其发生时间与全球其他地区基本一致。     

Spatial distribution pattern of seafloor hydrothermal vents to the southeastern Kueishan Tao offshore Taiwan Island

Investigations of the diffusion activities both within and outside the seafloor hydrothermal vents, as well as related mineral genesis, have been one of the key focuses of ocean biogeochemistry studies. Many hydrothermal vents are distributed close to the southern Okinawa Trough on the less-than-30-m deep shallow seafloor off Kueishan Tao, northeast of Taiwan Island. Investigations of temperature, pH and Eh at four depths of hydrothermal plume were carried out near Kueishan Tao at the white(24.83°N, 121.96°E) and yellow(24.83°N, 121.96°E) vents. An 87 h of temperature time series observation-undertaken near the white vent showed that tide is the main factor affecting the background environment. Based on the observed data, 3-dimensional sliced diffusion fields were obtained and analyzed. It was concluded that the plume diffused mainly from north to south due to ebb tide. The yellow vent's plume could effect as far as the white vent surface. From the temperature diffusion field, the vortices of the plume were observed. The Eh negative abnormality was a better indicator to search for hydrothermal plumes and locate hydrothermal vents than high temperature and low pH abnormalities.     

坛紫菜(Porphyra haitanensis)化学成分的研究

利用硅胶色谱、Sephadex LH-20凝胶色谱、HPLC等技术,从坛紫菜(Porphyra haitanensis)乙醇提取物首次分离纯化得到了7个化合物,通过质谱(MS)及核磁共振波谱(1H NMR、13C NMR)等现代波谱技术鉴定为：1,8-二羟基-9,10-蒽醌(1)、邻苯二甲酸二正丁酯(2)、邻苯二甲酸二异丁酯(3)、β-谷甾醇(4)、鲨肝醇(5)、(E)-N-2(1,3-二羟基-4-十八烯基)-十六酰胺(6)、胆甾醇(7)。其中,化合物1对金黄色葡萄球菌(Staphyloccocus aureus)的最低抑菌浓度(MIC)为80μg/mL。     

Decline of Pseudodiaptomus hessei (Copepoda, Calanoida) in two water bodies located in the Senegal River hydrosystem (West Africa): Hypotheses and perspectives

Pseudodiaptomus hessei is a key species in many water bodies in the Senegal River hydrosystem but it became rare or completely disappeared from two ecosystems (Lake Guiers and Dakar Bango Reservoir; Senegal, West Africa) after major hydrological changes caused by human action, mainly impoundments on the river in 1985, and the opening of a new estuary mouth in 2003. Kâ et al. [Kâ, S., Pagano, M., Ba, N., Bouvy, M., Leboulanger, C., Arfi, R., Thiaw, O.T., Ndour, E.H.M., Corbin, D., Defaye, D., Cuoc, C., Kouassi, E., 2006. Zooplankton distribution related to environmental factors and phytoplankton in a shallow tropical lake (Lake Guiers, Senegal, West Africa). International Review of Hydrobiology 91(5), 389–405] put forward several hypotheses to explain the reasons for this decline: salinity and chemical changes in the water, predation by a cyclopid predator Mesocyclops ogunnus and/or the inhibiting effects of cyanobacteria and/or diatoms (allelopathy). This study assessed these hypotheses by studying the distribution of P. hessei in 13 stations (including the Dakar Bango reservoir and Lake Guiers) in relation to physical, chemical and biological (phyto- and zooplanktons) factors at each station. We produced a distribution pattern for this species in the Senegal River hydrosystem. Rank correlations and principal component analysis showed that P. hessei was not correlated with conductivity but was positively correlated with pH and alkalinity, suggesting chemical effects. The clear association with two filamentous cyanobacteria (Cylindrospermopsis raciborskii and Anabaena sp.) did not appear to support the hypothesis of cyanobacteria inhibition but blooming conditions were never encountered during the study. Negative correlation with diatoms (especially with Fragilaria sp.) suggested that aldehyde producing diatoms had a negative effect. Negative correlations with cyclopids such as Mesocyclops supported the hypothesis of cyclopid predation to explain the decline of P. hessei. This study proposes several lines of research for future studies to test these hypotheses.     

港口及临港工业围填海规模综合评价研究

针对港口及临港工业围填海的特点,运用多目标决策理论与方法,构建了港口及临港工业围填海规模评价指标体系,包括现状评定和综合影响两类评价因子,包含自然条件、社会经济条件、资源环境影响、效益评估四类评价要素,共计15个评价指标。并根据成本型、效益型和固定型指标的特点提出了各自的标准化方法,采用主客观综合赋权法确定评价因子的权重,采用线性加权和法计算港口及临港工业围填海规模方案的综合得分,以此为依据确定围填海规模的适宜程度和适宜等级。以江苏辐射沙洲半岛式浅滩腰沙为例,运用港口及临港工业围填海规模综合评价方法,确定腰沙海域最佳的港口及临港工业围填海规模为理论基面+3.0 m。提出的研究方法能够为沿海省市港口及临港工业围填海规模评价提供参考和方法借鉴,对于围填海规模决策和围填海总量控制指标的制定具有重要意义。     

海洋红树林植物黄槿内生真菌Aspergillus sydowii EN-198化学成分研究

对采自海南东寨港的海洋红树林植物黄瑾(Hibiscus tiliaceus)叶中分离到的一株内生真菌Aspergillus sydowii EN-198的次生代谢产物进行了研究.利用正相与反相硅胶柱层析、葡聚糖凝胶Sephadex LH-20柱层析以及制备薄层层析(PTLC)等分离手段从其发酵液中分离得到14个化合物,通过一维、二维核磁共振技术、质谱技术等鉴定了所有化合物的结构,分别为:环-(S-脯氨酸-S-苯丙氨酸)(1),环-(S-脯氨酸-S-亮氨酸)(2),环-(S-苯丙氨酸-S-色氨酸)(3),(1S)-1-(4 '-间羟基苯甲酸)-1,1,5,5-二甲基己二醇(4),曲酸(5),N-[2-(4-吲哚)乙基]乙酰胺(6),N-[2-(4-对羟基苯酚)乙基]乙酰胺(7),胸腺嘧啶脱氧核苷(8),尿嘧啶脱氧核苷(9),尿嘧啶核苷(10),过氧化麦角甾醇(11),麦角甾醇(12),(2S,2'R,3R,3 'E,4E,8E)-N-(2’-羟基-3’-十六烯酰基)-9-甲基-4,8-二十碳二烯-1,3-二醇(13)以及1-O-β-D-葡萄糖基-(2S,2'R,3R,3'E,4E,8E)-N-(2’-羟基-3’-十六烯酰基)-9-甲基-4,8-二十碳二烯-1,3-二醇(14);其中化合物1和2为首次从Aspergillus sydowii中分离得到.对所有化合物测试其抑菌活性,发现化合物5与7对金黄色葡萄球菌有较好抑制活性.