25～75℃酸性NaCl溶液中方铅矿的溶解动力学

在25～75℃、pH=0.43～2.45的1mol/LNaCl溶液中进行了方铅矿的溶解动力学实验。发现在远平衡条件下,方铅矿的溶解速率r与氢离子活度犤H+犦呈线性关系,溶解速率方程(速率定律)为:r=k犤H+犦,即对H+而言,溶解反应为一级。其中速率常数k为2.344×10-7mol/m2·s(25℃)、1.380×10-6mol/m2·s(50℃)、7.079×10-6mol/m2·s(75℃)。溶解反应的活化能为43.54kJ/mol,方铅矿的溶解机理为表面化学反应,速率决定步骤为表面配合物的离解。     

三类高强度悬式瓷绝缘子的成分和物相分析

为探讨高原牌70kN和进口120，210kN瓷绝缘子的成分和结构性能，中采用原子吸收光谱（AAS）和X射线衍射（XRD）方法，对三类产品进行了检测。结果表明，有效成分除K2O外，70kN和210kN的SiO2,Al2O3,Fe2O3含量接近，主晶相基本相同，有刚玉，莫来石、石英和长石等；结晶相总量：70kN35%，120kN40%,210kN48%，这表明机械强度愈大，结晶相含量愈高，只需调整70kN原样的部分成分，粒度和工艺，即生产出高等级（如210kN)瓷绝缘子。     

柱撑粘土矿物层间域的性质及其环境意义

柱撑粘土矿物是近年来胺国内外矿物学广泛关注的矿物材料之一。柱撑粘土矿物层间域是一个特殊的化学反应场所。本系统评述了氮氧化物、重金属离子、阴离子、肥料养分及有机污染物等环境污染物在柱撑粘土矿物层间域中的催化还原、吸附、脱附、控释及光催化反应机理，着重阐述了柱撑粘土矿物的层间域性质，讨论了它们的环境化学行为对环境的影响和意义。     

水晶包裹体的类型及成因综述

水晶中的包裹体是在水晶生长过程中被包裹在晶体内的由一相或多相物质组成的封闭系统。水晶中包裹体的形成与生长时的物化条件密切相关 ,而生长过程中的物化环境又直接影响了水晶的结晶习性。     

呼伦西白金矿点外围区化异常查证方法及找矿效果

呼伦西白金矿点外围异常查证工作中,采用围山短水系沉积物测量为主,土壤测量为辅的方法,圈定以金为主的综合异常8处,发现金矿脉4条(III～VI号)、锑矿化带1处,取得了较为明显的地质找矿效果。该方法可供同类地区开展异常查证时参考。     

Gold Occurrence and Ore Genesis,Yata Micro—Disseminated Gold Deposit,Guizhou,Southwest China

The mode of occurrence of gold in the Yata micro-disseminated gold deposit is ap-proached through chemical phase studies coupled with ore-dressing monitoring and micro-beam analysis.The results showed that gold occurred for the most part as ultra-microscopic particles adsorbed on the surfaces or fracture planes of pyrite and other sulphides.The proportions of gold of different occurrences were estimated solutions containing nanometer-sized gold particles were prepared following the hydrolysis-reduction procedure and the adsorption of nanometer-sized gold on ordinary sulphides and rocks was experimentally determined.It is evident that sulphides are good adsorbents of gold and this is consistent with geological observations.     

Gold Mineralization and Occurrence of Sinter in the Hoshino Area, Fukuoka Prefecture, Japan

Abstract. Several epithermal gold deposits occur in the Hoshino area, which is located in the western end of the late Cenozoic Hohi volcanic zone, north‐central Kyushu, Japan. The area is characterized by intermediate to felsic extrusive rocks of Pliocene age. In the Hoshino area, the shallow manifestation of the hydrothermal activity is exposed on the surface. Several outcrops of sinter are still preserved on the top of hydro thermally altered volcanic rocks, and high‐grade gold‐bearing quartz veins occur on the surface at lower levels. The hydrothermal alteration resulted into well‐developed alteration zones. The zonal alteration pattern, primarily of near‐neutral pH type, is characterized by the outer smectite zone of a lower temperature, and the inner mixed layer minerals zone of a higher temperature. Quartz vein‐related or fracture‐controlled alteration, is represented by the occurrence of interstratified illite/smectite and K‐feldspar, suggesting a potassium‐enriched alteration. The mineralization in the Hoshino area is recognized on the surface by the occurrence of gold‐bearing quartz veins distributed mainly in the mixed layer minerals zone. The fracture system related to the gold mineralization is mainly characterized by NW‐SE trend. The alteration pattern and the mineralogical composition of the veins suggest that the mineralizing fluids had near‐neutral pH and the mineralization is of low‐sulfidation‐type. Fluid inclusion data and textures observed in quartz veins indicate that gold precipitated during boiling. The chemical composition of quartz veins shows that high‐grade gold‐bearing quartz veins are characterized by higher content of Al₂O₃, K₂O and Rb. Several outcrops of silica‐sinters are distributed on the top of the mixed layer minerals zone. Although their structures are not very well preserved, because of later silicification, the Hoshino sinters still show characteristic textures identical to those observed in modern sinters, such as the presence of plant fossil incorporated into the sinters, the strongly developed depositional laminations and the columnar structures perpendicular to the depositional surfaces. Quartz is the only silica mineral constituting the Hoshino sinters presently. The conversion of amorphous silica into quartz was probably governed by higher temperatures resulting from later hydrothermal activity. This later hydrothermal activity is reflected by the intense silicification affecting mainly the lower parts of the sinters and also by the presence of quartz veins cutting the sinters. The distribution of sinters in the Hoshino area is very significant. The presence beneath the sinters of concealed high‐grade gold‐bearing quartz veins should be highly considered and exploration work is strongly suggested.     

山西夏县台热水井水氡异常特征与地震的关系初探

为弄清山西夏县中心地震台水氡震前异常的原因 ,对山西夏县中心地震台热水井水氡 1984年以来的观测资料用概率论的数据处理方法进行了处理 ,以负异常的发震原理进行了分析 ,结果表明震前负异常的发震概率为 70 %。     

南北带北段磁性构造特征和地震活动的关系

利用航磁资料研究了南北带北段的磁属性构造，反演了该区居里等温面的埋藏深度，推断了不同深度断裂的分布情况，进南昌讨论了地震与深部背景的关系。     

云南水汞在姚安6.5级地震前的异常特征分析

对2000年1月15日姚安6．5级地震前后云南水汞异常进行分析研究，结果表明：在9个观测台站中，地震前有1个观测台站的水汞出现中期趋势异常，1个台站的水汞出现远震异常，4个台站的水汞出现短期异常，1个台站的水汞出现临震异常。地震前3个月内，水汞短期异常有活跃，平静的过程，在平静中(仅1个台站出现临震异常)发生姚安6．5级地震。姚安地震发生在距出现远震异常的水汞观测台站70km的地方。出现远震异常的水汞观测台站附近，可能是未来强震的发震地区。