Preliminary Study on the Chemical Mapping of Individual Fluid Inclusion by Synchrotron X-ray Fluorescence Microprobe

Abstract: Synchrotron X-ray fluorescence analyses on individual hypersaline fluid inclusions were tested to using synchrotron source at Tsukuba (KEK), Japan. The XRF instrumentation at KEK meets the purpose of fluid inclusion analysis, nondestructive, multi–element, ppm detection limits, with micro spatial resolution. In practice, however, the quantitative chemical analysis of fluid inclusion requires further considerable data accumulation. Semi-quantitative distribution of elements (mass number > 25) in single fluid inclusion was obtained.     

Gold Occurrence and Ore Genesis,Yata Micro—Disseminated Gold Deposit,Guizhou,Southwest China

The mode of occurrence of gold in the Yata micro-disseminated gold deposit is ap-proached through chemical phase studies coupled with ore-dressing monitoring and micro-beam analysis.The results showed that gold occurred for the most part as ultra-microscopic particles adsorbed on the surfaces or fracture planes of pyrite and other sulphides.The proportions of gold of different occurrences were estimated solutions containing nanometer-sized gold particles were prepared following the hydrolysis-reduction procedure and the adsorption of nanometer-sized gold on ordinary sulphides and rocks was experimentally determined.It is evident that sulphides are good adsorbents of gold and this is consistent with geological observations.     

蒙古国巴颜乌列盖多兰哈达地区地球化学特征及成矿

蒙古国巴颜乌列盖多兰哈达位于世界著名的铜—金—铅锌—钨金属成矿区—阿尔泰多金属成矿带北西段。区内出露地层主要为泥盆纪火山—沉积岩系。地球化学异常呈环带状分布,与岩体关系密切,该区铅锌矿为受火山通道控制的火山热液型金—铅锌矿床。矿区西部有寻找深部富矿体的前景,矿区南部及矿区东部次火山斑岩体附近,有寻找深部盲矿体的潜力。     

吉林省海沟金矿床的地球化学异常模式

在总结海沟金矿床区域水系沉积物、矿区水系沉积物及矿体的岩石、土壤地球化学异常特征的基础上,建立了海沟金矿床的地球化学异常模式,并依据该模式对区域47个异常进行了研究对比,预测出一处寻找海沟式金矿床的有望异常。     

滇西北地区地磁短周期变化特征研究

利用滇西北地磁台阵8个测点的秒采样观测数据,对短周期事件的地磁三分量变化幅度进行统计,得到不同周期的垂直分量和水平分量变化幅度比值ΔZ/ΔH在观测区的空间分布,由此推测地下存在一条NNW走向的高导带,从地壳延伸至上地幔,且位置随深度不断变化。     

Comparative Study of Acid and Alkaline Stimulants with Granite in an Enhanced Geothermal System

The Enhanced Geothermal System (EGS) is an artificial geothermal system that aims to economically extract heat from hot dry rock (HDR) through the creation of an artificial geothermal reservoir. Chemical stimulation is thought to be an effective method to create fracture networks and open existing fractures in hot dry rocks by injecting chemical agents into the reservoir to dissolve the minerals. Granite is a common type of hot dry rock. In this paper, a series of chemical stimulation experiments were implemented using acid and alkaline agents under high temperature and pressure conditions that mimic the environment of formation. Granite rock samples used in the experiments are collected from the potential EGS reservoir in the Matouying area, Hebei, China. Laboratory experimental results show that the corrosion ratio per unit area of rock is 3.2% in static acid chemical experiments and 0.51% in static alkaline chemical experiments. The permeability of the core is increased by 1.62 times in dynamic acid chemical experiments and 2.45 times in dynamic alkaline chemical experiments. A scanning electron microscope analysis of the core illustrates that secondary minerals, such as chlorite, spherical silica, and montmorillonite, were formed, due to acid-rock interaction with plagioclase being precipitated by alkaline-rock interactions. Masking agents in alkaline chemical agents can slightly reduce the degree of plagioclase formation. A chemical simulation model was built using TOUGHREACT, the mineral dissolution and associated ion concentration variation being reproduced by this reactive transport model.     

山西省王村地区隐伏侵入岩体隆起区地热地质特征

祁县王村地区位于晋中盆地中部东缘,晋中盆地四周为活动断裂所控制,盆地内受不同方向的次级断层切割,形成隆凹起伏的次级构造单元。祁县王村隆起中心部位是一个岩浆岩侵入体。井深350~400m时水温28℃,多年来水温稳定,该区域存在地热异常。为了查明该区域深部地热地质条件,省地勘基金项目立项进行勘查,采用地球化学调查、地球物理勘查、地热钻探、水文测井等工作方法,推测隐伏岩体分布面积57km^2,地热勘探井深2905.65m时,井口水温仅39℃,含水层为岩体,上覆三叠、二叠系砂岩裂隙水,涌水量1064m^3/d,水化学类型为HCO3·Cl-Na型水。同时测温曲线反映,随着井深增加,井深2045.92m以下侵入岩浆岩体地层地温梯度未见明显增高,说明在长期的地壳构造活动中侵入岩浆岩体的大部分热量已散失,因此本区地热资源勘探开发前景有限。侵入岩体上覆砂岩热储层所含低温温水,对养殖业有一定的开发利用价值。     

真空联合堆载预压加固土体的工程地质性质

为解决一些软土不能满足工程建设要求的问题, 必须对其进行加固处理。本文借助室内试验, 对比江门软土加固前后的基本物理性质、物理化学性质和力学性质, 借助扫描电镜( SEM) 对比研究加固前后土体微结构和工程性质的变化。研究表明: 加固后黏粒组含量明显减少, 砂砾组和粉粒组含量明显增加, pH值降低, 阳离子交换量大幅下降, Ca2 + 、CI- 和HCO - 3 含量减小, 其他离子含量变化不明显。加固过程增加了颗粒之间的连结力, 力学性质明显提高。加固前软土的微结构以絮凝状结构为主, 大孔隙较多; 加固后以团粒状结构为主, 粒内和粒间孔隙变小。真空联合堆载预压加固效果明显, 软土工程性质明显提高, 可以满足工程建设的需要。     

热化学硫酸盐还原作用对碳酸盐岩气藏的化学改造——以川东北地区长兴组-飞仙关组气藏为例

目前在川东北地区长兴组—飞仙关组已发现普光、渡口河、铁山坡、罗家寨等多个高含H2S的大、中型气田。通过天然气地球化学特征、流体包裹体盐度和岩心及薄片的镜下详细观察后认为,川东北地区长兴组—飞仙关组的大多数气藏遭受了热化学硫酸盐还原作用(TSR)的化学改造,TSR的改造主要表现在3个方面:1使C2 重烃相对于CH4、12C相对于13C优先被消耗,造成天然气干燥系数变大和碳同位素变重;2由于TSR产生的大量淡水的加入,使气藏的原生地层水被稀释,造成地层水盐度降低;3TSR相关流体(烃类和H2S等)与储层岩石之间的相互作用使储层被溶蚀和硬石膏发生蚀变,造成储层孔隙度增大,从而对改善其物性具有重要意义。     

化学腐蚀下砂岩三轴细观损伤机理及损伤变量分析

利用CT识别技术对化学腐蚀下的砂岩进行了三轴加载全过程的即时扫描试验，得到了在不同级荷载作用下砂岩的压密、微裂纹萌生、扩展和破裂的CT图像和CT数，分析了砂岩损伤演化的细观机理。同时，建立了一个基于化学腐蚀影响和CT数的损伤变量模型。