Physical behaviour of Cretaceous calcareous nannofossil ooze: Insight from flume studies of disaggregated chalk

Geomorphic features such as drifts, sediment waves and channels have been documented in the Upper Cretaceous of north‐west Europe. These features are interpreted to result from bottom currents and have been used to refine chalk depositional models and quantify palaeocirculation patterns. Chalk was first deposited as calcareous nannofossil ooze and geomorphic features are the result of sediment reworking after deposition. There is limited knowledge on the processes that govern nannofossil ooze mobility, thus forcing uncertainty onto numerical models based on sedimentological observations. This article provides an extensive view of the erosional and depositional behaviour of calcareous nannofossil ooze based on experimental work using annular flumes. A fundamental observation of this study is the significant decrease of nannofossil ooze mobility with decreasing bed porosity. Erosion characteristics, labelled as erosion types, vary with total bed porosity (φ) and applied shear stress (τ₀). High‐porosity ooze (φ >80%) is characterized by constant erosion rates (E_m). At φ <77%, however, erosion characteristics showed greater variance. Surface erosion was typically followed by transitional erosion (with asymptotically decreasing E_m), and stages of erosion with constant, and exponential erosion rates. The estimated erosion thresholds (τ_c) vary from ca 0·05 to 0·08 Pa for the onset of surface erosion and up to ca 0·19 Pa for the onset of constant erosion (φ of 60 to 85%). Variability of deposition thresholds (τ_cd) from ca 0·04 to 0·13 Pa reflects the influence of variable suspended sediment concentration and τ₀ on settling particle size due to the identified potential for chalk ooze aggregation and flocculation. Additionally, deposition thresholds seem to be affected by the size of eroded aggregates whose size correlates with bed porosity. Lastly, slow sediment transport without resuspension occurred in high‐porosity ooze as surface creep, forming low‐relief sedimentary features resembling ripples. This process represents a previously undescribed mode of fine‐grained nannofossil ooze transport.     

Shore platform lowering due to frost shattering during the 2009 winter at mesnil Val,English channel coast,NW France

In 2008–2009, a severe cold snap affected the otherwise temperate mid‐latitude coasts of the English Channel of France. In March 2009, we gathered rock spalling observations at Mesnil Val, NW France, to document the effect of frost on platform lowering in macro‐tidal environments. Six epochs of frost were recorded in 2 months, the two longest lasted 16 and 8 days, with minimum air temperature dropping to –9.5°C. Semi‐diurnal tides flood the entire platform, imposing up to 25 freeze–thaw cycles below –2.5°C, the freezing temperature of seawater. 19 cycles occurred at neap tidal elevation lasting at most 3.5 h. Our integrated observations indicate that these frost cycles were responsible for a platform lowering of about 0.8±0.5 mm during a single winter. No clear spatial trend appears, nor do macroscopic chalk types clearly stand out as being more susceptible to erosion. Assuming that the long‐term platform retreat model preserves a constant slope, frost shattering would then account for 10 to 20% of the expected annual platform erosion rate. Under more contrasted climates, frost is thus likely to be a prominent shaping process for rocky coastal platforms. Copyright © 2015 John Wiley & Sons, Ltd.     

A micromechanical modeling of ductile behavior of a porous chalk: Formulation,identification, and validation

Porosity strongly affects the overall ductile behavior of cohesive geomaterials undergoing plastic deformation. In the present paper, we proposed an original micromechanical approach that suitably couples Drucker–Prager‐type plasticity, evolving porosity under general triaxial loadings. The resulting model has the advantage to be based on a single macroscopic yield function, which also plays the role of plastic potential. It is shown that this yield function is particularly appropriate to account for the pore collapse and plastic shearing mechanisms that govern the mechanical behavior of the studied Lixhe chalk. Finally, the new model is implemented and validated by comparison to triaxial tests data, covering a wide range of confining pressures. Copyright © 2011 John Wiley & Sons, Ltd.     

Dynamics of river–aquifer interactions along a chalk stream: the River Lambourn,UK

This paper describes the spatial and temporal pattern of groundwater flow accretion to the River Lambourn, a 234 km² chalk catchment of the West Berkshire Downs, UK, which has been largely unaffected by groundwater abstraction. Variations in the discharge measured at four fixed gauges in the catchment, coupled with information on the length of flowing channel over the period 1983–2001, are used to describe regional patterns in flow accretion. Mean catchment accretion generally exceeds 0·15 m³ s⁻¹ km⁻¹, but there are significant differences between perennial reaches indicating how the combination of local structural controls and seasonal changes in the drainage net affect flow accretion. Data from current meter surveys were used to determine the spatial variability in flow accretion: 505 paired observations along 12 reaches between 1 and 2·95 km in length indicated a consistent spatial trend in accretion. Accretion was high in upstream and downstream channel reaches, and in middle reaches where dry valleys intersected the main valley. A flow accretion index was developed to describe the relationship of flow accretion in each of the 12 study reaches to catchment discharge. The relationship varied from a strong positive correlation with catchment discharge (two reaches), a weak positive correlation (three reaches), a strong negative correlation (two reaches), to no relationship to catchment discharge (four reaches). The results highlight the need to reconsider the usual assumption of uniform, or uniformly increasing, flow accretion in chalk catchments. Moreover, they emphasize the importance of catchment topography, and illustrate how flow accretion in individual reaches may vary between high and low groundwater levels. Copyright © 2005 John Wiley & Sons, Ltd.     

Le réseau de fracturation,facteur initial de la karstification des craies dans les collines du Perche : l’exemple du site de la Mansonnière (Bellou-sur-Huisne,Orne, France)

Résumé

Le facteur tectonique est reconnu depuis longtemps comme initiateur de la première phase de karstification, mais sans que ceci n’ait jamais été démontré car les témoignages des premières phases sont détruits par le développement de la karstification. Les qualités hydrologiques mixtes de la craie permettent de conserver une grande variété de formes spécifiques, illustrant différents stades d’évolution, depuis l’originel « primokarst » jusqu’au classique drain polyphasé.

Dans les collines du Perche, de très récentes recherches ont mis en évidence des galeries endokarstiques particulières, comblées de sables et d’argiles. Les analyses physiques, chimiques et rayons X ont démontré que ces remplissages résultent non pas d’un processus classique de dépôt fluviatile, mais au contraire d’un processus d’altération soulignant la progression d’un front d’altération dans la craie, jusqu’à la surface piézo- métrique. Les remplissages ne sont pas des dépôts sédimentaires, mais représentent une sorte de « fantôme de roche », résultant d’une transformation in situ de la craie, sans aucun transport de matière solide.

La genèse résulte de la progression de fronts d’altération installés sur le réseau de fissures de la zone d’introduction (de la surface jusqu’au toit de la nappe). À la rencontre de la nappe de la craie, le mélange des eaux produit une activité chimique qui ouvre la fissure originelle. Des galeries comblées, semblables à celles du karst classique, se forment, sans jamais avoir connu de drainage fluviatile. Ces galeries illustrent le premier degré d’une évolution karstique classique, juste avant qu’un flux draine la galerie constituant un nouveau degré de karstification : le conduit drainé. La spécificité de la région du Perche est que la karstification s’y est arrêtée au premier stade, illustrant le « primokarst » modélisé mais jamais décrit jusqu’alors. Les conditions de cette genèse sont acquises lorsque le site offre un réseau de fractures bien développé, une absence de formations superficielles, une perméabilité élevée du sol, une absence de drainage superficiel (pas de perte concentrée), et un encaissant relativement poreux. © Elsevier, Paris     

Statistical and empirical analyses of the triggers of coastal chalk cliff failure

The triggering factors of rock falls remain unknown due to a lack of exhaustive, regular and accurate surveys. Based on an inventory of 331 rock falls collected weekly between 2002 and 2009 from Veules‐les‐Roses to Le Treport (Upper Normandy), the relationships between coastal chalk cliff rock falls (dates and geomorphological features) and external factors commonly agreed as triggering (rainfall, temperature variations, tide and wind) are studied. The combination of multivariate statistical and empirical analyses indicates that (1) ‘cold and dry weather’ and ‘high rainfall and high wind’ are the conditions most likely to trigger rock falls, (2) the main triggering factors of rock falls are effective rainfall (for rock falls mostly between 200 and 1400 m³ or larger than 10 000 m³ and coming from the whole cliff face), freeze/thaw cycles (especially for rock falls smaller than 200 m³ and coming from the foot and top of the cliff face) and marine roughness (rock falls mainly smaller than 200 m³ and coming from the cliff foot). However, the contribution of each factor to triggering is difficult to determine because of combinations of factors (85% of 331 cases), relays of processes and hysteresis phenomena. In view of these first results, it is still presumptuous to predict the location and time of triggering of rock falls. However, the statistical and naturalistic approaches adopted and the observations made in this study are from an original database, and constitute a real starting point for the prediction and prevention of the hazard of coastal chalk cliff rock falls in Upper Normandy. Copyright © 2015 John Wiley & Sons, Ltd.     

Adsorption of polar aromatic hydrocarbons on synthetic calcite

The wettability of hydrocarbon reservoirs depends on how and to what extent the organic compounds are adsorbed onto the surfaces of calcite, quartz and clay. A model system of synthetic calcite, cyclohexane and the three probe molecules: benzoic acid, benzyl alcohol and benzylamine, have been studied by adsorption experiments. The results clearly demonstrate the differences in the adsorption behaviour between probes with different functional groups of varying polarity and acidity. The maximum adsorption decreases in the order: benzoic acid, benzyl alcohol and benzylamine. The order of magnitude of ΔG° for the adsorption process implies the formation of a strong bond between the calcite surface and the adsorbate molecules.     

Laminated–bioturbated cycles in Maastrichtian chalk of the North Sea: oxygenation fluctuations within the Milankovitch frequency band

The Maastrichtian chalk of the southern Central Graben, Danish North Sea, is a homogeneous pure white coccolithic chalk mudstone deposited in a deep epeiric shelf sea, which covered large parts of northern Europe. The sediment displays a pronounced cyclicity marked by decimetre‐thick bioturbated beds alternating with slightly thinner non‐bioturbated, mainly laminated beds. The laminated half‐cycles consist of alternating millimetre‐thick, graded, high‐porosity laminae and non‐graded, low‐porosity laminae. The cyclicity has been interpreted previously as caused by periods of slow background sedimentation and bioturbation interrupted by periods of rapid deposition of laminated beds, with the latter reflecting random and local resedimentation processes. Based on textural and structural analysis, the millimetre‐scale, non‐graded laminae are interpreted as having been deposited directly from pelagic rain of pelleted coccoliths representing the primary production. The graded laminae were deposited from small‐volume, low‐density turbidity currents and suspension clouds. The sedimentation rates of the cyclical chalk are similar to those known elsewhere, and the lamination is interpreted as having been preserved from destruction through bioturbation by anoxic conditions at the seafloor. Bioturbated–laminated cycles are thus formed by slow sedimentation during alternating seafloor redox conditions probably on a Milankovitch scale. A direct implication of this interpretation is that the cycles are areally widespread, probably extending throughout the southern Central Graben area and may be useful for correlation and high‐resolution cyclostratigraphy in the chalk fields of the Danish North sea. If the laminated half‐cycles represent a few rapid resedimentation events, with a high sedimentation rate as suggested by most workers, then the sediment would not be truly cyclic, but would represent event sedimentation within a pelagic background represented by the bioturbated beds. In this case, the cycles would have very limited potential for correlation.     

Investigations on Diffusion Characteristics of Granite and Chalk Rock Mass

Contaminant transport through fractured rock mass is predominated by diffusion. This is due to the continuous interaction of the mobile water present in the fracture network and relatively immobile pore water, which is adsorbed on the surface and in the rock matrix itself. Even though the advective flow through the fracture network is high, besides sorption of rock mass, the diffusive exchange into the rock mass leads to significant retardation of contaminant transport. Hence, for describing contaminant transport in fractured rock mass, more precisely, the effect of retardation attributed to the matrix diffusion must be taken in account. With this in view, a methodology, which can be employed for determination of the diffusion characteristics of the rock mass, has been developed and its details are presented in this paper. Validation of the methodology has been demonstrated with the help of Archie’s law.