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121.
刘家沟位于四川省阿坝州金川县,是一条狭陡型高频泥石流沟,每年雨季,降雨激发泥石流灾害链。本文在野外调查和实地勘测的基础上,分析认为,受汶川MS8.0地震扰动,刘家沟形成流通区单位面积上松散固体物质达98.11×104 m3,在409.8‰的平均纵坡降下,泥石流活动频率明显增强,泥石流沿程放大效应明显,最终形成了降雨+径流侵蚀-滑坡-堰塞体-堰塞体溃决-增大的泥石流-堵河形成堰塞湖-卡撒沟中、下游损害的灾害链。提出采用格宾石笼进行固坡护床,结合拦挡坝拦粗排细的作用,根据保护对象设置防护堤,优化排导槽与主河交汇条件的综合治理措施,可为小流域高频狭陡型泥石流灾害的治理提供参考。  相似文献   
122.
金属矿物的反应动力学与地球化学意义   总被引:8,自引:0,他引:8  
张生 《地学前缘》1999,6(2):351-360
概述了动力学实验的技术方法和金属矿物的反应动力学研究进展。动力学实验使用的三种基本化学反应装置是间歇反应器(BR)、活塞流反应器(PFR)和混合流反应器(MFR),确定速率定律的数学方法包括积分法、微分法和混合法,以微分法中的初始速率法应用最广。目前主要研究了水溶液中黄铁矿氧化、黄铁矿和黄铜矿形成、晶质铀矿和磁铁矿溶解的速率定律和反应机理,发现:(1)酸性溶液中黄铁矿的氧化速率对Fe3+和O2浓度呈分数依赖并受表面反应的控制;(2)低于300℃时黄铁矿不能从溶液中直接成核,而需初始地通过FeS先驱物的硫化生成,FeS与H2S反应形成黄铁矿的速率方程为二级;(3)磁黄铁矿或黄铁矿与Cu2+反应均可形成黄铜矿,前者经历了一系列准稳的Cu Fe硫化物的中间物,后者的速率方程为表观一级并受表面反应的控制;(4)酸性pH时磁铁矿的非线性溶解行为可采用表面反应扩散输运耦合的收缩核模型(SCM)来描述。有关动力学实验成果完善和深化了对矿床中黄铁矿、黄铜矿的形成机理和风化壳中磁铁矿的稳定性等方面的认识。将来的实验研究将向更多的金属矿物和高温高压领域发展。  相似文献   
123.
硼及硼同位素地球化学在地质研究中的应用   总被引:17,自引:0,他引:17  
总结了硼及硼同位素的地球化学特征:(1)硼是易溶元素,主要赋存在地球表层,尤其是海水、海相沉积物及海水交代岩石中。其同位素组成δ11B值按顺序变化,封闭盐湖卤水(>40‰)>海水(395‰)>海相硼矿物(182‰~3173‰)>海相沉积物(139‰~252‰)>海水交代岩石(451‰~1085‰)。大陆水及陆相沉积物硼含量及硼同位素组成变化极大,并多以负值为主。海陆过渡构造带则具有过渡的硼丰度值和硼同位素组成。(2)11B较10B具有更活跃的地球化学性质,因此在水岩作用中具有明显的同位素交换。硅化交代作用中,岩石被硅化交代,释放硼,并优先释放重硼,同位素组成变轻;在脱硅反应中,岩石释放硅吸收硼,并优先吸收重硼,同位素组成变重。在封闭体系中,水溶液淋滤岩石中部分的硼,即可大量富集,并富集11B;在开放体系中,岩石硼被大量淋滤流失,δ11B值明显降低。由于水岩作用的结果,从新鲜海底玄武岩到正常海水,硼同位素值从-295‰到395‰逐渐升高。(3)变质脱水反应中硼被大量排出,并优先排出重硼同位素,进入流体相,因此随着变质程度由低到高,岩石中硼含量及同位素组成δ11B值由高变低。(4)在成矿研究中?  相似文献   
124.
Identifying a good site for groundwater exploration in hard rock terrain is a challenging task. In hard rocks, groundwater occurs in secondary porosity developed due to weathering, fracturing, faulting, etc., which is highly variable within short distance and contributing to near-surface inhomogeneity. In such situations topographic, hydrogeological and geomorphological features provide useful clues for the selection of suitable sites. Initially, based on satellite imagery, topographical, geomorphological and hydrogeological features, an area of about 149 km2 was demarcated as a promising zone for groundwater exploration in the hard rock tract of Seethanagaram Mandal, Vizianagaram District, Andhra Pradesh, India. A total of 50 Vertical Electrical Soundings (VES) were carried out using Wenner electrode configuration. An interactive interpretation of the VES data sharpened the information inferred from geomorphological and hydrogeological reconnaissance. Ten sites were recommended for drilling. Drilling with Down-The-Hole Hammer (DTH) was carried out at the recommended sites down to 50 to 70 m depths. The interpreted VES results matched well with the drilled bore well lithologs. The yields of bore wells vary from 900 to 9000 liters per hour (lph).  相似文献   
125.
The compositional variability of the lithospheric mantle at extensional settings is largely caused by the reactive percolation of uprising melts in the thermal boundary layer and in lithospheric environments.The Alpine-Apennine(A-A)ophiolites are predominantly constituted by mantle peridotites and are widely thought to represent analogs of the oceanic lithosphere formed at ocean/continent transition and slow-to ultraslow-spreading settings.Structural and geochemical studies on the A-A mantle peridotites have revealed that they preserve significant compositional and isotopic heterogeneity at variable scale,reflecting a long-lived multi-stage melt migration,intrusion and melt-rock interaction history,occurred at different lithospheric depths during progressive uplift.The A-A mantle peridotites thus constitute a unique window on mantle dynamics and lithosphere-asthenosphere interactions in very slow spreading environments.In this work,we review field,microstructural and chemical-isotopic evidence on the major stages of melt percolation and melt-rock interaction recorded by the A-A peridotites and discuss their consequences in creating chemical-isotopic heterogeneities at variable scales and enhancing weakening and deformation of the extending mantle.Focus will be on three most important stages:(i)old(pre-Jurassic)pyroxenite emplacement,and the significant isotopic modification induced in the host mantle by pyroxenite-derived melts,(ii)melt-peridotite interactions during Jurassic mantle exhumation,i.e.the open-system reactive porous flow at spinel facies depths causing bulk depletion(origin of reactive harzburgites and dunites),and the shallower melt impregnation which originated plagioclase-rich peridotites and an overall mantle refertilization.We infer that migrating melts largely originated as shallow,variably depleted,melt fractions,and acquired Si-rich composition by reactive dissolution of mantle pyroxenes during upward migration.Such melt-rock reaction processes share significant similarities with those documented in modern oceanic peridotites from slow-to ultraslow-spreading environments and track the progressive exhumation of large mantle sectors at shallow depths in oceanic settings where a thicker thermal boundary layer exists,as a consequence of slow-spreading rate.  相似文献   
126.
苏州澄湖湖底硬粘土粒度特征及成因初探   总被引:4,自引:0,他引:4  
澄湖是太湖平原上的一个浅水湖泊,湖底十分平坦,主要由硬粘土组成,同时发育有NW—SE横穿澄湖的古河道和泥沼洼地。在接近湖泊中心部位的古河道中打钻获得了4 m长的岩芯,并进行了详细的粒度分析。结果表明,该岩芯下部的硬粘土主要由细粉砂、中粉砂和粘土组成,分别占26.7%~38.1%,26.9%~34.3%和19.7%~26.2%,可命名为粘土质粉砂;众数粒径为10~50 μm,平均占57.9%;平均粒径为6.3~6.9。将其与上部的湖泊沉积、镇江下蜀黄土和中国北方各地黄土的粒度比较表明,苏州澄湖湖底的硬粘土原本也是风尘沉积。  相似文献   
127.
This article presents a method for the nonlinear analysis of laterally loaded rigid piles in cohesive soil. The method considers the force and the moment equilibrium to derive the system equations for a rigid pile under a lateral eccentric load. The system equations are then solved using an iteration scheme to obtain the response of the pile. The method considers the nonlinear variation of the ultimate lateral soil resistance with depth and uses a new closed‐form expression proposed in this article to determine the lateral bearing factor. The method also considers the horizontal shear resistance at the pile base, and a bilinear relationship between the shear resistance and the displacement is used. For simplicity, the modulus of horizontal subgrade reaction is assumed to be constant with depth, which is applicable to piles in overconsolidated clay. The nonlinearity of the modulus of horizontal subgrade reaction with pile displacement at ground surface is also considered. The validity of the developed method is demonstrated by comparing its results with those of 3D finite element analysis. The applications of the developed method to analyze five field test piles also show good agreement between the predictions and the experimental results. The developed method offers an alternative approach for simple and effective analysis of laterally loaded rigid piles in cohesive soil. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
128.
A meso‐scale particle model is presented to simulate the expansion of concrete subjected to alkali‐aggregate reaction (AAR) and to analyze the AAR‐induced degradation of the mechanical properties. It is the first attempt to evaluate the deterioration mechanism due to AAR using the discrete‐element method. A three‐phase meso‐scale model for concrete composed of aggregates, mortar and the interface is established with the combination of a pre‐processing approach and the particle flow code, PFC2D. A homogeneous aggregate expansion approach is applied to model the AAR expansion. Uniaxial compression tests are conducted for the AAR‐affected concrete to examine the effects on the mechanical properties. Two specimens with different aggregate sizes are analyzed to consider the effects of aggregate size on AAR. The results show that the meso‐scale particle model is valid to predict the expansion and the internal micro‐cracking patterns caused by AAR. The two different specimens exhibit similar behavior. The Young's modulus and compressive strength are significantly reduced with the increase of AAR expansion. The shape of the stress–strain curves obtained from the compression tests clearly reflects the influence of internal micro‐cracks: an increased nonlinearity before the peak loading and a more gradual softening for more severely affected specimens. Similar macroscopic failure patterns of the specimens under compression are observed in terms of diagonal macroscopic cracks splitting the specimen into several triangular pieces, whereas localized micro‐cracks forming in slightly affected specimens are different from branching and diffusing cracks in severely affected ones, demonstrating different failure mechanisms. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
129.
中国西北地区存在大量的新近纪硬土软岩滑坡灾害,为研究该类滑坡的变形特征,开展两组离心机模型试验模拟滑带劣化引起滑坡变形破坏的全过程,获取模型坡体土压及位移的实时变化曲线。研究表明,当软弱带强度降低时,硬土软岩滑坡的上部滑体呈块体状滑动,在快速运动滑动过程中,滑体呈现块状平移,不会彻底解体、液化;硬土软岩滑坡中前部出现水平应力集中,导致下伏滑带塑性流动变形,诱发其中前部上覆滑体的水平运动,并向滑坡后缘扩展,最终形成多级水平滑动。  相似文献   
130.
在氧化沉淀法去除铁的过程中,氧化反应分别在自然曝气、充气和除钙的条件下进行,对照结果进行分析,得出最佳的除铁配方,同时还着重对氧化反应速率及其影响因素(pH,Eh等)进行了探索性研究,为以后试验提供了一定的依据。  相似文献   
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