内蒙古大苏计和曹四夭大型钼矿床的发现及意义

大苏计矿床和曹四夭矿床是近几年在内蒙古中部地区找到的2处大型特大型钼矿床,产出规模分别达到20万吨和200万吨.钼矿化主要在太古宙变质岩及中生代石英斑岩、正长斑岩和花岗斑岩体内呈浸染状、网脉状和脉状产出,并且构成筒状、倒扣“碗状”和囊状矿体.两处矿床无论在产出环境和地质特征上,还是在矿物种属、元素组合和热液蚀变方面,均与美国克莱麦克斯钼矿床和黑龙江岔路口钼矿床较为相似,是中生代构造-岩浆活动的产物,属古大陆碰撞造山后伸展环境产出的斑岩型矿床.文章所提出的地壳4个演化阶段和3个成矿期次的成矿模式对于提高大苏计和曹四夭钼矿床理论研究水平,推动低山丘陵覆盖区大型隐伏钼矿床的找矿勘查工作深入进行,均具有重要意义.     

古溶洞控矿构造在青藏高原中部的发现及意义——以茶曲帕查铅锌矿床为例

青藏高原中部茶曲帕查矿区铅锌矿化与张性碳酸盐岩角砾伴生。钻孔资料揭示,该套角砾岩在平面上、垂向上分布无规律,露头表现为杂乱堆垛,角砾空隙间常充填泥质物,与泥质物接触部位发育同沉积变形,说明角砾为古溶洞内坍塌形成。茶曲帕查矿区古溶洞内含有坍塌灰岩角砾和泥质充填物,分别发育不同形式的铅锌矿化。溶洞的形成很可能与地下水对碳酸盐岩的溶蚀有关,坍塌发生在早中新世,与五道梁组沉积同时发生。古溶洞成矿作用在青藏高原中部的提出,对认识该区矿床成因、区域铅锌找矿模式等方面均具有重要意义。     

双误差回归模型在ICP-MS测定饮用水中锶的不确定度评定的简化应用

在计算电感耦合等离子体质谱法测定饮用水中锶的浓度(x)时,由于标准系列配制和仪器检测过程中信号(y)漂移产生的不确定度会传递给最终的计算结果。普通的一次或多次线性拟合结果不能真实地反映对于x、y值都含误差的数据拟合情况。文章对标准曲线进行了双误差回归计算,从双误差回归线性方程推导出校准曲线拟合过程产生不确定度的计算公式,建立了方法检出限与曲线拟合参数(x、y、曲线截距和斜率)及其相关不确定度之间的关系式,依据误差连续传递公式及不确定度分量计算公式简化了合成不确定度的表达式。从合成不确定度计算公式中可得出,水样中锶含量的浓度越低,其对应的不确定度越大;标准系列配制过程不细致、仪器灵敏度低,方法检出限越差,与实际测试情况符合。     

Zircon ages and Hf isotopic compositions of Permian and Triassic A-type granites from central Inner Mongolia and their significance for late Palaeozoic and early Mesozoic evolution of the Central Asian Orogenic Belt

ABSTRACT

This work presents zircon ages and Hf-in-zircon isotopic data for Permian and Triassic A-type granitoids and reviews the evolution of central Inner Mongolia, China, during the early Permian and Late Triassic. SHRIMP U–Pb dating of zircons of peralkaline granites yielded ²⁰⁶Pb/²³⁸U ages of 294 ± 4 Ma and 293 ± 9 Ma that reflect the time of Permian magmatism. Zircon ages were also obtained for Late Triassic granites (226 ± 4 Ma, 224 ± 4 Ma). Our results, in combination with published zircon ages and geochemical data, document distinct magmatic episodes in central Inner Mongolia.

The Permian peralkaline granites show typical geochemical features of A-type granites, which also have highly positive zircon ε_Hf(t) values (+4.9 – +17.1), indicating a significant contribution of an isotopically depleted source, likely formed from mantle-derived magmas. Late Triassic A-type granitoids, however, in central Inner Mongolia show large variations and mostly positive in zircon ε_Hf(t) values (?1.3 – +13.5), suggesting derivation from a mixture of crust and mantle or metasomatized lithospheric mantle with crustal contamination. The geochemical characteristics of the Permian peralkaline granites and Late Triassic A-type granitoids are consistent with a post-collisional setting and were likely related to asthenosphere upwelling during the evolution of the Northern Block and Central Asian Orogenic Belt (CAOB).     

Review Section

ABSTRACT

The petrology, geochronology, and geochemistry of the early Permian volcanic rocks from Houtoumiao area, south Xiwuqi County in central Inner Mongolia of China, are studied to elucidate the early Permian tectonic setting of the region. The volcanic rocks, which are interbedded with sandstone, feature both mafic and felsic compositions and show a bimodal nature. Zircon U–Pb dating reveals that the volcanic rocks formed at 274–278 Ma, similar to the ages of bimodal magmatism in neighbouring areas. The mafic rocks are composed of tholeiitic basalt, basaltic andesite, basaltic trachyandesite, and trachyandesite. They are rich in Th, U, and LILEs, depleted in HFSEs Nb, Ta, and Ti, and have positive ε_Nd(t) values (+3.6 to +7.9). Geochemical analyses indicate that the mafic rocks originated from metasomatized lithospheric mantle. The felsic volcanic rocks are mainly rhyolite, with minor trachyte and dacite. They have different evolutionary tendencies of major elements, chondrite-normalized REE patterns, and isotopic compositions from the mafic volcanic rocks, which preclude formation by fractional crystallization of mafic melts. The ε_Nd(t) values of the felsic rocks are similar to those of the Carboniferous Baolidao arc rocks in the region. It is suggested that Permian felsic melts originated from the partial melting of Carboniferous juvenile arc-related rocks. By comparison with typical Cenozoic bimodal volcanism associated with several tectonic settings, including rift, post-collisional setting, back-arc basin, and the Basin and Range, USA, the bimodal volcanic rocks in central Inner Mongolia display similar petrological and geochemical characteristics to the rocks from back-arc basin and the Basin and Range, USA. Based on the analysis of regional geological data, it is inferred that the early Permian bimodal volcanic rocks in the study area formed on an extensional continental margin of the Siberian palaeoplate after late Carboniferous subduction–accretion.     

The nature of the Palaeozoic oceanic basin at the southwestern margin of Gondwana and implications for the origin of the Chilenia terrane (Pichilemu region,central Chile)

The Coastal Accretionary Complex of central Chile constitutes the product of early Carboniferous to Late Triassic subduction at the rear of Chilenia, a continental terrane likely derived from Laurentia and accreted to southwestern margin of Gondwana during the Mid to Late Devonian. The complex contains basaltic metavolcanic sequences of the subducted oceanic lithosphere accreted to the active margin. In this paper, we address the tectonic setting of these rocks by means of a geochemical study in the coastal area of Pichilemu region, central Chile. The accreted fragments of oceanic crust occupy different structural levels, exhibit variable metamorphic grade, and have geochemical fingerprints that reveal a compositional heterogeneity of the subducted oceanic crust. The amphibolites have N to E-MORB compositions. Greenschist units include N-MORB and E-MORB transitional to OIB, and blueschists and greenschists interleaved within a single metavolcanosedimentary sequence have OIB signatures. Neodymium isotopic systematics indicate depleted and enriched mantle sources, whereas strontium isotopic systematics indicate seawater/rock interaction. The variety of rocks suggests formation in an oceanic setting characterized by shallow and deep mantle sources, such as plume-influenced ridge. Based on the geological, petrological, geochemical, and isotopic characteristics, we propose that the metavolcanic protoliths of the Pichilemu region formed relatively close to the western margin of the Chilenia terrane during the initial stage (late Cambrian–Early Devonian) of seafloor development and drifting of this continental block. Geochemical similarities with oceanic units accreted to the active margin south of the Pichilemu region indicate a regional pattern of the oceanic crust subducted under the Palaeozoic Chilean margin between, at least, 34°S and 39°S latitude, strongly supporting the activity of a mantle plume. This, in turn, can be correlated with the location of the Pacific plume generation zone in early Palaeozoic era, corroborating a Laurentian origin for the Chilenia terrane.     

川中东北部地区须家河组储层发育主控因素分析

川中东北地区须家河组储层虽然在整体上属于低孔～低渗储层,但在局部仍然发育孔渗相对较好的优质储层。这里通过对沉积作用、成岩作用,以及破裂作用如何影响储层发育程度等方面进行研究,探讨并分析了须家河组优质储层的形成条件与影响因素。研究区须家河组砂岩属辫状河三角洲沉积体系,以发育水上、水下分流河道为显著特征。储层经历了较为复杂的成岩演化过程,受多种成岩作用综合影响。研究认为:沉积相是研究区须家河组优质储层形成的基本条件,岩性是优质储层形成的物质基础,成岩作用是优质储层形成最重要的控制因素,而裂缝是优质储层形成的关键。     

中祁连西段巴嘎德尔基岩体LA-ICP-MS锆石U-Pb年龄及地质意义

巴嘎德尔基岩体位于中祁连山西段的野马南山地区,主要由钾长花岗岩和二长花岗岩组成.LA-ICP-MS锆石U-Pb测年表明,巴嘎德尔基岩体侵位年龄为462.9±1.4Ma.该岩体地球化学方面表现出强过铝、高K、K/Na,低Mg、Fe、Ca的主量元素特征,并富集K、Rb、Ba、Th,亏损Zr、Hf、Y、Yb等微量元素,轻稀土富集,弱的Eu负异常.在微量元素判别图解上,所有岩石投影点均落入同碰撞区域.结合区域地质背景,认为巴嘎德尔基岩体是加里东造山作用晚期陆陆碰撞的产物.     

对电感耦合等离子体质谱法测定的地下水中Ag元素不确定度的评定

采用不确定度连续传递模型,对电感耦合等离子体质谱法测定的地下水中Ag元素的不确定度进行评定。采用双误差回归的方式对标准曲线进行拟合,通过计算出各分量的不确定度,合成得到测量结果的总不确定度。当实际样品中Ag的含量较低时,其曲线拟合产生的不确定度影响较大,甚至成为主导因素。     

对电感耦合等离子体质谱法测定的地下水中 Tl元素不确定度的评定

采用不确定度连续传递模型,对电感耦合等离子体质谱法测定的地下水中Tl元素的不确定度进行评定。采用双误差回归的方式对标准曲线进行拟合,通过计算出各分量的不确定度,合成得到测量结果的总不确定度,但是并没有考虑前处理过程中产生的不确定度。结果表明,当实际样品中Tl的含量较低时,其曲线拟合产生的不确定度贡献影响较大,甚至成为主导因素,而当Tl的含量较高时曲线拟合产生的不确定度贡献率变得很小。