南极与青藏高原冰芯中阳离子对比研究

本文选取南极Ｎｅｌｓｏｎ站、横断山的海螺沟冰川、喜马拉雅山的达索普冰川、西昆仑的古里雅冰川和天山的托木峰冰川为研究对象,以化学成分作为指标,作了模糊聚类分析。结果表明,在不同水平下分类,冰川之间关系程度不同,反应的气候环境也不同。南极与青藏高原冰川中离子浓度存在差异,尤其是Ｎａ＋和Ｃａ２＋的含量差异显著。Ｎｅｌｓｏｎ站的Ｃａ２＋／Ｎａ＋之值比青藏高原各冰芯低许多,其与海水中Ｃａ２＋／Ｎａ＋之值相当。Ｃａ２＋／Ｎａ＋之值体现了冰川离海洋的距离,Ｃａ２＋／Ｎａ＋之值越小,则冰川离海洋越近,反之则越大。     

苏锡常地区浅层地下水rNa/rCl特征及其成因初探

本文从苏锡常地区浅层地下水含水介质及包气带沉积环境的角度,阐明了浅层地下水中Cl-和Na 浓度东高西低的分布特征。根据数据分析,浅层地下水中Na 与Cl-的毫克当量比值rNa/rCl与海侵形成的沉积环境和沉积历史关系密切。地下水淡化历史越长,含水层介质中吸附的Na 与地下水中的Ca2 和Mg2 之间的阳离子交换吸附程度越高,大量的Na 进入地下水中,使得rNa/rCl比值越高。     

一种基于占有率反馈的虚拟网络映射算法

网络虚拟化技术通过对物理资源的抽象,可以有效解决现有互联网架构中存在的网络结构僵化、可扩展性差等问题.虚拟网络映射问题是指将用户发送的所有虚网请求映射到底层物理网络中,同时还要满足虚网请求中对各个资源的限制要求（如节点计算能力、链路带宽等）.从节点负载平衡的角度出发,在基于就近原则的虚网映射算法基础上,引入节点负载平衡的反馈机制,引导各个虚网请求更均匀地映射到底层物理网络中.另外,在k短路径算法机制中引入了当前链路资源占有率作为评价参考标准,这样可以尽可能均匀地分散链路压力.同时,在检验链路资源是否满足虚网请求的过程中,由于优先选中的链路资源占有率低,所以算法映射成功率高,映射耗时更短,虚拟网络映射效率得到了有效提高.     

GIS-based spatial and temporal changes of land occupation caused by mining activities-a study in eastern part of Hubei Province

By using multi-source and multi-temporal high resolution remote sensing data and related techniques of remote sensing and geographic information systems, this paper analyzes the spatial and temporal changes of land occupation caused by mine development in four mining areas of eastern Hubei Province from 2011 to 2014, including Chengchao-Tieshan iron-copper polymetallic deposit area, Daye-Yangxin iron-copper polymetallic deposit area, E-Nan mining area, and Wuxue-Yangxin non-metallic mining area along the Yangtze River. The results show that: In the research area, land occupation of energy mine exploitation is small and in scattered distribution, with coal mine occupying the largest area, showing a downward trend in four years; land occupation of metal mines is large and in centralized distribution, with iron mine and copper mine occupying the largest area, showing a downward trend in four years; non-metallic mines are large and in great quantity, with mines of limestone for building and limestone occupying the largest area, showing a upward trend in four years.     

Influence of Salinity on pH and Aluminum Concentration on the Interaction of Acidic Red Soil with Seawater

Contamination of acidic red soil in the coastal areas of Okinawa Islands is a serious environmental problem. This study was conducted to examine the effects of the salinity on pH and aluminum concentration when the acidic red soil interacts with seawater. Acidic red soil from Gushikawa recreation center was fractionated into bulk soil, coarse sand and silt + clay. Different weights of each fraction were equilibrated with seawater solutions. The pH and concentrations of Al³⁺, Na⁺, K⁺, Ca²⁺ and Mg²⁺ were then analyzed in the extracts. The results showed a decreasing trend of pH with increasing soil to solution ratio while the extracted Al³⁺ revealed an increasing trend. The lowest pH values were 3.85, 4.06, 4.41, 4.66 and their corresponding highest Al³⁺ concentrations were 2.50, 1.01, 0.062 and 0.036 mmolL⁻¹ in the seawater extracts, one-tenth seawater extracts, one-hundredth seawater extracts and one-thousandth seawater solution extracts, respectively. Mostly, the concentrations of Na⁺, Ca²⁺, Mg²⁺ and especially K⁺ decreased with increasing soil weight in the high salinities but showed the opposite trend in the low salinity samples. Potassium concentration decreased by 39%, 53% and 40% in the seawater extracts, one-tenth and one-hundredth seawater extracts but increased by 200% in one-thousandth seawater extracts. The coincidence of the increase in Al³⁺ and H⁺ concentrations, and the decrease of Na⁺, K⁺, Ca²⁺ and Mg²⁺ concentrations in the solutions suggests ion exchange/adsorption, while the increased patterns, particularly at low salinity could be attributed to the dissolution of the species from the soils.     

有机质对S1nm锰矿相金属阳离子交换能力的影响

大洋多金属结核问题长期以来一直受到人们的关注[1～3].大量的研究结果表明,多金属结核中最有经济价值的铜、钴、镍等有价金属元素,主要赋存于仅占整个结核约15%锰矿相中.我们曾对人工合成1 nm锰矿相(synthetic 1nm manganate,以下简称S1nm锰矿相)金属阳离子交换能力作过初步探讨[4,5],研究表明,Cu2+,Co2+,Ni2+,Zn2+等与S1nm锰矿相具有强烈的阳离子交换能力,证明了多金属结核成矿后期的离子交换是铜、钴、镍、锌等有价金属元素进入多金属结核的重要途径之一.     

离子色谱法同时测定铀矿浸出液中的阳离子

对铬铁矿中亚铁的测定方法进行了探讨。首先对已有方法进行了验证和筛选,然后对Li2SO4助熔剂的助溶作用及其反应机理进行了研究,从而推荐了H2SO4-H3PO4-V2O5-V(Ⅳ)-Li2SO4和H2SO4-H3PO4-Ce(SO4)2-Li2SO4两种改进型的溶剂体系用于铬铁矿试样中亚铁的测定,所得结果具有良好的重现性。     

Effects of cation disordering in a natural MgAl2O4 spinel observed by rectangular parallelepiped ultrasonic resonance and Raman measurements

At moderate temperatures, the elastic properties of natural MgAl₂O₄ spinel differ in several significant ways from properties of synthetic spinels. Below 1000 K, the ultrasonic resonant frequencies of an ordered natural spinel change significantly after heat treatment; at higher temperatures, both types of spinels have similar resonant responses. The temperature derivatives of the elastic constants of an ordered spinel also differ from those of disordered spinels at moderate temperatures; again, at higher temperatures, both types of spinels have similar behaviors. The Raman spectra also differ below 1000 K for ordered natural and disordered spinels and are similar at higher temperatures and after cooling to ambient temperature. We associate these changes in ultrasonic resonance and Raman spectra of spinel with cation disordering at high temperature which may be quenched by cooling. We deduce estimates of the inversion parameter from the relative intensities of the two A_1g Raman modes in very good agreement with estimates made from other measurements. We find thatC ₁₁ andC ₁₂ decrease by 4 and 8%, respectively, with 20% inversion in spinel;C ₄₄ is less sensitive to cation order. These results imply that previous measurements of the adiabatic elastic constants of spinels at ambient conditions have been affected by the state of cation disorder of the specimen.     

Seawater Intrusion in the Longkou-Laizhou Area, Shandong

The extensive intrusion (covering an area of 83.7-238.3 km~2 and accounting for 18.6-31.5% of the total area of the plain), the presence of a transitional zone 1.5-6.0 km in width, and the interconnection in distribution between the seawater intrusion district and the region lower than the sea level caused by the strong drop of the groundwater level are major characteristics of the seawater intrusion in the study area. Cation exchange played an important role during the formation of chemical composition of the groundwater in the seawater intrusion district.     

广东交通建设占用耕地的特征及其趋势预测

1990～2000年是广东省交通建设大发展时期和耕地减少的高峰期。通过对这一时段的分析,发现交通建设占用耕地已成为广东省非农建设占用耕地的主要成分和耕地减少的一大因素。在空间分布特征上,利用土地扩展集中指数和扩展强度两个指标进行计算分析,结果是广东省交通占用耕地分布区域不均匀,扩展区域主要集中于清远、广州等市;而占用最为严重的地区是深圳和汕头两市。根据广东交通发展的需要,预测到2030年,全省由于交通建设还需占用土地118295.26hm2。