Patterns and controls of surface sediment distribution: west-central Florida inner shelf

The west-central Florida inner shelf represents a transition between the quartz-dominated barrier-island system and the carbonate-dominated mid-outer shelf. Surface sediments exhibit a complex distribution pattern that can be attributed to multiple sediment sources and the ineffectiveness of physical processes for large-scale sediment redistribution. The west Florida shelf is the submerged extension of the Florida carbonate platform, consisting of a limestone karst surface veneered with a thin unconsolidated sediment cover. A total of 498 surface sediment samples were collected on the inner shelf and analyzed for texture and composition. Results show that sediment consists of a combination of fine quartz sand and coarse, biogenic carbonate sand and gravel, with variable but subordinate amounts of black, phosphorite-rich sand. The carbonate component consists primarily of molluskan fragments. The distribution is patchy and discontinuous with no discernible pattern, and the transition between sediment types is generally abrupt. Quartz-rich sediment dominates the inner 15 km north of the entrance into Tampa Bay, but south of the Bay is common only along the inner 3 km. Elsewhere, carbonate-rich sediment is the predominate sediment type, except where there is little sediment cover, in which cases black, phosphorite-rich sand dominates. Sediment sources are likely within, or around the periphery of the basin. Fine quartz sand is likely reworked from coastal units deposited during Pleistocene sea-level high stands. Carbonate sand and gravel is produced by marine organisms within the depositional basin. The black, phosphorite-rich sand likely originates from the bioerosion and reworking of the underlying strata that irregularly crop out within the study area. The distribution pattern contains elements of both storm- and tide-dominated siliciclastic shelves, but it is dictated primarily by the sediment source, similar to some carbonate systems. Other systems with similar sediment attributes include cool-water carbonate, sediment-starved, and mixed carbonate/siliciclastic systems. This study suggests a possible genetic link among the three systems.     

黄、东海海域水团发育对底质沉积物分布的影响

通过对黄、东海海域底质沉积物中的细粒级粘土矿物组合特征和全粒级碳酸盐含量分析、对比上覆水团和悬浮体资料，探讨研究区水团发育消长对底质沉积物分布的影响作用。结果表明研究区可以划分为长江冲淡水影响的长江型物质沉积区；黄海水影响的黄河型物质沉积区和黑潮水以及东海次表层水影响的残留型物质沉积区。而水团发育消长可直接影响下伏底质的分布特征。黄河型物质沉积区与残留型物质沉积区的分界相应于黄海冷水向东南扩展与黑潮次中层混合水向陆架爬升互为消长的长期综合平衡位置，而黄海冷水向东南的扩展范围代表着黄河物质在陆架向东南扩展沉积的最大范围．     

四元体系Na~ ∥Cl~-,CO_3~(2-),B_4O_7~(2-)-H_2O 273K介稳相平衡研究

采用等温蒸发法研究简单四元体系Na ∥Cl-,CO32-,B4O72--H2O273K时的介稳相平衡,并测定该体系273K平衡液相中各组分的溶解度及密度,该体系的介稳相图和密度组成图显示:该四元体系在273K时的相图由3条溶解度单变量线、3个结晶区及1个共饱和点组成。体系属简单共饱型,无复盐或固溶体形成,3个结晶区分别对应单盐Na2CO3·10H2O,NaCl和Na2B4O7·10H2O。共饱点E处于Na2CO3·10H2O,NaCl及Na2B4O7·10H2O3盐共饱和,所对应的平衡液相组成为w(Na2CO3)=6.81%,w(NaCl)=21.69%,w(Na2B4O7)=0.65%,w(H2O)=70.85%。研究体系在273K下,Na2CO3·10H2O是碳酸钠盐的唯一析出形式,且硼酸钠对碳酸钠有盐析作用。     

Carbon and oxygen isotopic composition of car- bonate cements of different phases in terrigenous siliciclastic reservoirs and significance for their origin： A case study from sandstones of the Triassic Yanchang Formation, southwestern Ordos Basin, China

Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope （their δ^18O values range from -0.3‰- -0.1‰） and lighter oxygen isotope （their δ^18O values range from -22.1‰- -19.5‰）. Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process.     

川西南周公山及邻区下二叠统碳酸盐岩成岩作用对储集性的影响

川西南周公山及邻区下二叠统的中-低孔、中-低渗碳酸盐岩储层的储集空间以次生成因的溶孔、溶洞和构造裂缝为主.研究认为,多世代方解石胶结、化学充填作用以及埋藏期的压实(溶)作用是孔隙很难得到保存的主要原因;同生-准同生期的混合水云化作用和表生期、埋藏期的流体溶蚀作用则产生了大量的次生溶孔、洞,使储层的孔渗性得到明显的改善;构造破裂作用可以产生新的储集空间,还影响各储集体之间及单一储集体内部空隙的连通.成岩相分为混合水云化-溶蚀-破裂相、溶蚀-胶结相和胶结-压实-压溶相.各种成岩作用的叠加形成了现今下二叠统油气储层的分布格局.     

Application of Spectral Decomposition to Detection of Fracture-Cavity Carbonate Reservoir Beds in the Tahe Oiifieid, Tarim Basin, NW China

Ordovician fracture-cavity carbonate reservoir beds are the major type of producing formations in the Tahe oilfield, Tarim Basin. The seismic responses of these beds clearly changes depending on the different distance of the fracture-cavity reservoir bed from the top of the section. The seismic reflection becomes weak or is absent when the fracture-cavity reservoir beds are less than 20 ms below the top Ordovician. The effect on top Ordovician reflection became weaker with deeper burial of fracture-cavity reservoir beds but the developed deep fracture-cavity reservoir beds caused stronger reflection in the interior of the Ordovician. This interior reflection can be divided into strong long-axis, irregular and bead string reflections, and was present 80 ms below the top Ordovician. Aimed at understanding reflection characteristics, the spectral decomposition technique, which uses frequency to ＂tune-in＂ bed thickness, was used to predict Ordovician fracture-cavity carbonate formations in the Tahe oilfield. Through finely adjusting the processing parameters of spectral decomposition, it was found that the slice at 30 Hz of the tuned data cube can best represent reservoir bed development. Two large N-S-trending strong reflection belts in the mid-western part of the study area along wells TK440- TK427-TK417B and in the eastern part along wells TK404-TK409 were observed distinctly on the 30 Hz slice and 4-D time-frequency data cube carving. A small N-S trending reflection belt in the southern part along wells T403-TK446B was also clearly identified. The predicted reservoir bed development area coincides with the fracture-cavities connection area confirmed by drilling pressure testing results. Deep karst cavities occur basically in three reservoir bed-development belts identified by the Ordovician interior strong reflection. Spectral decomposition proved to be a useful technique in identifying fracture-cavity reservoir beds.     

中伊朗盆地Garmsar区块Qom组沉积微相及储层特征研究

伊朗Garmsar区块Qom组形成于碳酸盐岩台地沉积环境,岩性以生物屑灰岩、含砂生物屑灰岩、泥晶灰岩为主,是典型的裂缝~孔隙型储层。利用区内野外实测剖面资料和露头岩样测试资料,对Qom组沉积相进行标识及类型划分,并对Qom组沉积微相及其平面展布特征进行分析,指出了该区域开阔台地相~高能红藻滩微相和局限台地相~泻湖夹台内滩微相是研究区储层发育的有利部位。F段中部的粒内溶孔较为发育,而溶缝主要出现在C1、C3亚段,整个Qom组构造微裂缝不甚发育。但储层孔渗条件比较差,属于中~低孔、低渗~特低渗储层,且存在严重的不均一性。为此,从沉积相与储层特征角度研究认为,中伊朗盆地Garmsar区块Qom组油气勘探存在一定的风险。     

含盐量对松嫩平原碳酸盐渍土抗剪强度的影响

松嫩平原分布着大量的碳酸盐渍土,其不良的工程性质给穿越其中的道路质量造成不同程度的影响。由于盐渍土所含易溶盐成分主要为碳酸氢钠,该研究通过向碳酸盐渍土内加入碳酸氢钠制备不同含盐量的盐渍土,进行室内直剪试验。试验表明：随着含盐量的增加土的粘聚力减小,内摩擦角有先减小后变大的趋势;随着含水量的增加,土的含盐量越高,土的粘聚力减小越明显。易溶盐在土中的状态形式是影响其抗剪强度参数变化的一个重要原因。     

碳酸盐型磷矿的反浮选工艺研究

针对某碳酸盐型磷矿,采用反浮选工艺流程进行试验研究,获得了低镁优质磷精矿。反浮选工艺具有药剂种类少,分选效率高,选矿技术指标先进,操作控制容易等优点,是选别碳酸盐型磷矿的先进浮选工艺。     

苏北盆地泰州组砂岩成岩序列和储集层质量主控因素分析?

基于53口井310余块储集层砂岩样品的分析研究,指出泰州组储集层存在着压实(压溶)、胶结和溶蚀等成岩作用,但在不同位置成岩作用的表现有所不同。海安凹陷以胶结和溶蚀作用为主,压实与压溶作用不太明显;高邮凹陷的压实程度较海安凹陷强烈。压实作用使得高邮凹陷泰州组储集层孔隙度在2 400～2 800 m处于10%左右,而海安凹陷为10%～20%。海安凹陷和高邮凹陷泰州组储集层目前处于中成岩阶段A期。储集层质量主要受原始沉积环境和成岩作用的综合影响。压实作用和胶结作用均可降低孔隙,但当碳酸盐胶结物含量小于15％时,胶结作用对储集层质量影响较小。碳酸盐胶结物和长石颗粒溶蚀形成了大量的粒间溶孔。海安凹陷有利储集层主要分布在西北部和东部三角洲前缘砂体和滑塌浊积扇砂体中,高邮凹陷有利储集层主要分布在南部扇三角洲前缘砂体中。