Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope (their δ^18O values range from -0.3‰- -0.1‰) and lighter oxygen isotope (their δ^18O values range from -22.1‰- -19.5‰). Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process. 相似文献
Rock-magnetic measurements along with grain size, acid-insoluble residue (AIR), organic carbon (OC), CaCO3 and δ18O of the planktonic foraminifers of the sediments were determined for 15 gravity cores recovered from the western continental margin of India. Magnetic susceptibility (MS) values in the surficial sediments reflect the land-derived input and, in general, are the highest in terrigenous sediment-dominated sections of the cores off Saurashtra–Ratnagiri, followed by the sediments off Indus–Gulf of Kachchh and then Mangalore–Cape Comorin.
The down-core variations in mineral magnetic parameters reveal that the glacial sediments off the Indus are characterized by low MS values/S-ratios associated with high AIR-content, low OC/CaCO3 contents and relatively high δ18O values, while those off SW India are characterized by low MS values/high S-ratio% associated with low AIR content, and relatively high OC, CaCO3 and δ18O values. Conversely, the Early Holocene sediments of all cores are characterized by high MS values/S-ratio% associated with high AIR content, low OC, CaCO3 contents and gradually decreased δ18O values. These results imply that during the Last Glacial Maximum (LGM), the cores off northwestern India received abundant continental supply leading to the predominance of eolian/fluvial sedimentation. In the SW region the influence of hinterland flux is less evident during this period, but convective mixing associated with the NE monsoon resulted in increased productivity. During the early Holocene intense SW monsoon conditions resulted in high precipitation on land, which in turn contributed increased AIR content/MS values in the continental margin sediments. A shallow water core off Kochi further suggests that the intense SW monsoon conditions prevailed until about 5 ka. The late Holocene organic-rich sediments of the SW margin of India were, however, subjected to early diagenesis at different intervals in the cores. Therefore, caution is needed when interpreting regional climatic change from down-core changes in sediment magnetic properties. 相似文献
The genetic analysis of the deep-buried reservoirs of the Lower Paleozoic carbonate rocks in the Tarim basin is a difficult task involving many factors. Firstly, the object of study is carbonate rocks, which have undergone a long term of modification. Secondly, the rocks are deeply buried with depths of 3800-7000 m in the Tarim basin. The primary reservoir properties formed in the deposition have been strongly modified during the deep burial process. Concurrently, the different burial depths in different areas result in diversities of burial temperature, pressure, underground water, hydrochemistry and various physicochemical changes, which further lead to differences in the diagenetic type, diagenetic property, diagenetic degree and their impacts on the reservoir properties. The Lower Paleozoic Cambrian and Ordovician carbonate reservoirs in the Tarim basin can be grouped into four types, i.e., paleo-weathered-crust reservoirs, reef reservoirs, buried karst reservoirs and dolomite reservoirs. This paper 相似文献