Heterogeneous distributions of CO2 may be more important for dissolution and karstification in coastal eogenetic limestone than mixing dissolution

Mixing dissolution, a process whereby mixtures of two waters with different chemical compositions drive undersaturation with respect to carbonate minerals, is commonly considered to form cavernous macroporosity (e.g. flank margin caves and banana holes) in eogenetic karst aquifers. On small islands, macroporosity commonly originates when focused dissolution forms globular chambers lacking entrances to the surface, suggesting that dissolution processes are decoupled from surface hydrology. Mixing dissolution has been thought to be the primary dissolution process because meteoric water would equilibrate rapidly with calcium carbonate as it infiltrates through matrix porosity and because pCO₂ was assumed to be homogeneously distributed within the phreatic zone. Here, we report data from two abandoned well fields in an eogenetic karst aquifer on San Salvador Island, Bahamas, that demonstrate pCO₂ in the phreatic zone is distributed heterogeneously. The pCO₂ varied from less than log ?2.0 to more than log ?1.0 atm over distances of less than 30 m, generating dissolution in the subsurface where water flows from regions of low to high pCO₂ and cementation where water flows from regions of high to low pCO_2. Using simple geochemical models, we show dissolution caused by heterogeneously distributed pCO₂ can dissolve 2.5 to 10 times more calcite than the maximum amount possible by mixing of freshwater and seawater. Dissolution resulting from spatial variability in pCO₂ forms isolated, globular chambers lacking initial entrances to the surface, a morphology that is characteristic of flank margin caves and banana holes, both of which have entrances that form by erosion or collapse after cave formation. Our results indicate that heterogeneous pCO₂, rather than mixing dissolution, may be the dominant mechanism for observed spatial distribution of dissolution, cementation and macroporosity generation in eogenetic karst aquifers and for landscape development in these settings. Copyright © 2015 John Wiley & Sons, Ltd.     

origin of the mud volcano in northern tianshan constrained by geochemical investigation

Mud volcano is a kind of structural geological phenomena under certain hydrogeological environment and can bring plenty of valuable information to the ground when it erupts, therefore, many researchers call it as "Heaven granted well" whose depth can be up to 12km. Mud volcanoes in Xinjiang are distributed in the central-west region of North Tianshan, and five of them are representative, namely, Horgus, Dushanzi, Wenquan, Poplar valley, and Sailetike. We tested the gas, fluid and solid components of these mud volcanoes through investigations and studies of topography and geomorphology, geological and hydrogeological conditions, and mud debris characteristics, and preliminary obtained the origin of these mud volcanoes based on geochemical features. Finally, the paper describes briefly that the continuous enchancement of regional crustal tectonic stress can not only give rise to the seismogenesis and earthquake occurrence, but also break the original cycle of mud volcano to bring about significant activity, therefore, the two have a certain homology relationship.     

微生物沉积碳酸钙固化珊瑚砂的试验研究

向珊瑚砂中注入巴斯德芽孢杆菌菌液、氯化钙和尿素的混合液,利用微生物沉积碳酸钙固化珊瑚砂;并对珊瑚砂固化体进行了渗透、强度及微观结构等试验。试验结果表明,巴斯德芽孢杆菌的活性随时间呈衰减趋势,但衰减速度缓慢,能较好地满足珊瑚砂固化的需要。随着菌液、氯化钙和尿素的混合液注入次数的增加,珊瑚砂柱渗透性逐步降低,最终渗透性降低了1～2个数量级。微生物固化后的珊瑚砂柱应力-应变曲线大致可分为3段,即应力随应变缓慢增加段、快速增加段以及突降段。试样发生压裂脆性破坏,无侧限抗压强度最高达到14 MPa左右。抗压强度随干密度增加而增大,随渗透性降低而增大。微生物固化后珊瑚砂颗粒被生成的碳酸钙完整的包裹,孔隙间极少见生成的碳酸钙,与普通硅砂微生物固化后的微观结构不同,较好地解释了渗透性降低不多的原因。     

Modeling planform evolution of a mud‐dominated meandering river: Quinn River,Nevada, USA

A depth‐averaged linearized meander evolution model was calibrated and tested using the field data collected at the Quinn River in the Black Rock Desert, Nevada. Two approaches used to test the model were: (1) simulating meander evolution and comparing the results with the observed 38 year migration pattern; and (2) fitting the model parameters to present bank asymmetry (the ratio of the maximum bank gradients on opposite sides of the channel). The data required as input were collected in the field during a high flow in May 2011 and from aerial photographs and LiDAR data. Both approaches yielded similar results for the best fit parameter values. The bank asymmetry analysis showed that the bank asymmetry and the velocity perturbation have high correlation at close to zero spatial lag while the maximum correlation between the bank asymmetry and maximum bend curvature is offset by about 25 m. The model sufficiently replicated 38 years of channel migration, with a few locations significantly under‐ or over‐predicted. Inadequacies of the flow model and/or variation in bank properties unaccounted for are most likely the causes for these discrepancies. Flow through the Quinn River was also simulated by a more general 3D model. The downstream pattern of near‐bank shear stresses simulated by the 3D model is nearly identical to those resulting from the linearized flow model. Topographic profiles across interior bends are essentially invariant over a wide range of migration rates, suggesting that the traditional formulation that cut bank erosion processes govern migration rates is appropriate for the Quinn River. Copyright © 2014 John Wiley & Sons, Ltd.     

Diagenetic fluid evolution and water-rock interaction model of carbonate cements in sandstone: An example from the reservoir sandstone of the Fourth Member of the Xujiahe Formation of the Xiaoquan-Fenggu area,Sichuan Province,China

Carbonate cement is the most abundant cement type in the Fourth Member of the Xujiahe Formation in the Xiaoquan-Fenggu area of the West Sichuan Depression. Here we use a systematic analysis of carbonate cement petrology, mineralogy, carbon and oxygen isotope ratios and enclosure homogenization temperatures to study the precipitation mechanism, pore fluid evolution, and distribution of different types of carbonate cement in reservoir sand in the study area. Crystalline calcite has relatively heavy carbon and oxygen isotope ratios(δ13C = 2.14‰, δ18O = -5.77‰), and was precipitated early. It was precipitated directly from supersaturated alkaline fluid under normal temperature and pressure conditions. At the time of precipitation, the fluid oxygen isotope ratio was very light, mainly showing the characteristics of a mixed meteoric water-seawater fluid(δ18O = -3‰), which shows that the fluid during precipitation was influenced by both meteoric water and seawater. The calcite cement that fills in the secondary pores has relatively lighter carbon and oxygen isotope ratios(δ13C = -2.36‰, δ18O = -15.68‰). This cement was precipitated late, mainly during the Middle and Late Jurassic. An important material source for this carbonate cement was the feldspar corrosion process that involved organic matter. The Ca2+, Fe3+ and Mg2+ ions released by the clay mineral transformation process were also important source materials. Because of water-rock interactions during the burial process, the oxygen isotope ratio of the fluid significantly increased during precipitation, by about 3‰. The dolomite cements in calcarenaceous sandstone that was precipitated during the Middle Jurassic have heavier carbon and oxygen isotope ratios, which are similar to those of carbonate debris in the sandstone(δ13C = 1.93‰, δ18O = -6.11‰), demonstrating that the two are from the same source that had a heavier oxygen isotope ratio(δ18O of about 2.2‰). The differences in fluid oxygen isotope ratios during cement precipitation reflect the influences of different water-rock interaction systems or different water-rock interaction strengths. This is the main reason why the sandstone containing many rigid particles(lithic quartz sandstone) has a relatively negative carbon isotope ratio and why the precipitation fluid in calcarenaceous sandstone has a relatively heavier oxygen isotope ratio.     

考虑泥浆套不同形态的顶管管壁摩阻力计算公式

大直径、长距离顶管施工常通过注浆形成泥浆套来减小阻力,泥浆套的形态及其完整性对管壁摩阻力大小有决定性作用,现有摩阻力计算公式一般未考虑不同泥浆套形态对摩阻力的影响,计算结果与实际情况相差较大。根据不同施工状况对顶管外壁泥浆套的可能形态进行了分类及成因分析,提出了判断3种常见泥浆套形态的方法。利用半无限弹性体中柱形圆孔扩张理论探讨了注浆压力对泥浆套厚度的影响,结合非线性流体力学计算泥浆与管壁接触产生的摩阻力,最终采用挖掘面稳定假设,针对3种泥浆套形态提出了摩阻力计算公式。采用该方法对工程案例进行计算,计算结果与实测数据对比表明：现有摩阻力计算公式的计算结果过于保守,所提出的计算公式是合理和有效的。     

济州岛西南泥质区粒度组分变化的古环境应用

利用激光粒度仪对位于东海陆架济州岛西南泥质区的B2孔进行了沉积物粒度分析,根据标准偏差变化检出了B2孔含有4个粒度组分：〉65．6、65．6～10．5、10．5～1．3和〈1．3μm,其中〉65．6μm粗组分含量很低,主要是以底栖有孔虫为主的生源沉积．各组分平均粒径和粒度含量随孔深的变化显示了65．6～10．5μm组分在B2孔含量较高（21％～30％）,变化最明显,是该孔对环境变化最敏感的粒度组分．研究表明该敏感组分的粒度含量和平均粒径变化主要受东亚冬季风的强弱变化制约,其变化恢复的近2ka来东亚冬季风变化和中国东部气候变化序列具有很好的一致性,证明65．6～10．5μm粒度组分可以作为东亚冬季风的替代指标．     

Neoproterozoic Molar-tooth Structure and Constraint of Depositional Facies and Environment in the North China Platform in Jiangsu, Anhui and Liaoning, Eastern China

Molar tooth structure （MTS） represented by complex ptygmatical shapes is widely distributed in the Proterozoic of the world. MTS filled by fine, equant sparry calcite （or dolomite） displays an abrupt contact with hosting rocks, which are mainly composed of carbonaceous micrites and fine-grained carbonates with local silts and stormdominated deposits with graded, cross or wave beddings, numerous erosional surfaces and truncated and fills or guttered bases. Occurrence of MTS suggests a result of the constraint of sedimentary facies, and the storm-base in ramp settings is the maximum depth for the formation of MTS. Vertical succession of MTS-bearing carbonates shows a deposition stacked by high-frequency shallow subtidal and peritidal cycles. An individual cyclic MTS-bearing sequence is characterized by thinning, shallowing and dynamic decreasing-upward, and peritidal caps of purple red iron and organic carbonaceous sediments with more complicated shapes of MTS are common on the top of individual MTS-bearing sequences.     

贵州碳酸盐岩红色风化壳次生石英的裂变径迹测年研究

贵州位于青藏高原东南缘,由于缺乏沉积记录其新生代的地质演化历史还不很明晰,而广泛分布于云贵高原的碳酸盐岩红色风化壳可能蕴涵着重要的地质演化信息.本文对贵州多个原位碳酸盐岩红色风化壳中产出的晶体形态较好的石英进行了裂变径迹方法测年.结果显示,石英的裂变径迹年龄数据呈现出较大的变化范围,从 1 Ma到 25 Ma,且远远地小于其三叠纪和寒武纪的母岩年龄;结合贵州 25 Ma到 1 Ma的区域地质演化历史,裂变径迹年龄值可以排除石英来源于母岩碎屑、成岩过程的次生形成以及火山活动产生的热水沉淀或交代形成的可能性,而只能推断为该晶体形态较好的石英于碳酸盐岩风化作用产生的富硅流体中沉淀形成;各剖面石英的年龄值与新生代的青藏高原夷平期、华南红土期、贵州构造稳定期乃至世界范围内的风化气候期有着良好的对应关系,说明次生石英裂变径迹测年具有很好的可行性和可靠性.     

鲁西隆起区奥陶系碳酸盐岩成岩作用及其对储集性的控制作用

以鲁西隆起区奥陶系碳酸盐岩沉积旋回与不整合面分析为基础, 应用薄片、铸体和阴极发光等室内分析技术, 对其成岩作用、成岩序列、孔隙演化及其特征进行了详细研究。研究区的成岩作用分为两类: 建设性成岩作用和破坏性成岩作用, 前者包括白云石化、压溶、去石膏化、溶蚀和破裂等作用; 后者以重结晶、胶结、压实、硅化和充填作用为主。奥陶系碳酸盐岩经历了多期次和多种类型的成岩作用演化, 与马家沟组相比, 三山子组多经历了一次其沉积后的短期表生和随后的埋藏作用。三山子组白云岩、马家沟组东黄山段、土峪段和阁庄段粉细晶白云岩以及八陡段不整合面以下的溶蚀角砾岩段发育次生孔洞缝系统, 是较为有利的储集层段。