塔里木盆地白垩系巴什基奇克组陆相砂岩中碳酸盐岩碎屑特征及其地质意义

从储层的微观特征入手,通过各种实验分析认为:塔里木盆地库车坳陷—塔北隆起白垩系巴什基奇克组砂岩中的碳酸盐岩碎屑有五大特征,明显区别于胶结物:粒度粗,一般比其周围的原生孔隙大,磨圆好（个别有晚期压溶现象）,轮廓清晰;在砂岩中分布相对均匀,非斑块状;碎屑中存在古生物的化石且多为粉细晶;胶结物（铁方解石、铁白云石）多附着在碎屑边缘呈加大边出现,染色有明显变化;灰岩、云岩碎屑在阴极射线下发桔黄色光。碳酸盐岩碎屑的分布具有近源粒度粗、含量低、分选差、磨圆差、均质差;远源粒度细、含量高、分选好、磨圆好、均质好;浅埋粒形好、深埋压溶强的特征。物源区发育的古老碳酸盐岩地层,干旱、炎热、近咸化的古气候、古水体环境,近源快速堆积的古地理环境是碳酸盐岩碎屑的主要成因。碳酸盐岩碎屑的识别和量化具有重要的地质意义:其减孔效应明显低于胶结物,可有效解释高含量碳酸盐高物性砂岩成因,其分布是界定沉积物源区的有效证据。     

Evaluation of oxygen isotopes in carbonate as an indicator of lake evolution in arid areas: The modern Qinghai Lake, Qinghai–Tibet Plateau

The oxygen isotopic composition of carbonate in lakes has been used as a useful indicator in Palaeolimnological research, and has made some important contributions to our understanding of lacustrine systems. For modern lakes in arid or cold areas, however, there are few data available to test the effect of lake salinity and temperature on the oxygen isotopic composition of various carbonate sources such as ostracod, bulk carbonate, and fine-grained carbonate (< 60 μm). Here we examined the oxygen isotopic composition of ostracods, bulk carbonate, and fine-grained carbonates, as well as that of coexisting water from Lake Qinghai and the smaller surrounding lakes and ponds on the Qinghai–Tibet Plateau. Our investigation highlights three key effects. First, the oxygen isotopic composition of ostracods, bulk carbonate, and fine-grained carbonate in the lakes and ponds shows a clear response to lake water δ¹⁸O values, and these vary with water salinity. The relationship between lake water δ¹⁸O and salinity is not only dominated by the evaporation/freshwater input ratios, but is also controlled by the distance to the mouth of the major rivers supplying to the lake. Second, the ostracod, bulk carbonate, and fine-grained carbonate show similar isotopic change trends in the study area, and oxygen isotopic differences between ostracods and authigenic carbonate may be explained by the different water temperatures and very small ‘vital offsets’ of ostracods. Finally, the effect of water depth on temperature leads to increasing δ¹⁸O values in carbonates as water depth increases, both in benthic ostracods living on the lake bottom, as well as in bulk carbonate precipitated at the water surface.For arid, high-altitude Lake Qinghai, our results suggest that variations in the δ¹⁸O values of carbonate in Lake Qinghai are mainly controlled by the oxygen-isotope ratio of the lake water changing with water salinity. As a secondary effect, increasing water depth leads to cooler bottom and surface water, which may result in more positive δ¹⁸O values of ostracod and bulk carbonate.     

北京十三陵地区中—新元古界碳酸盐岩Pb—Pb年龄研究

对北京十三陵地区中一新元古界碳酸盐岩进行了系统地采样和207pb/204pb-206Pb/204Pb年龄测定.共测定了63个样品(大部分样品采取两种溶解方式),得到中元古界雾迷山组第三段的207Pb/204pb-206Pb/204pb等时线年龄为1373±92Ma(95%置信度误差,下同,MSWD＝4.7),杨庄组为1488±55Ma(MSWD＝14),高于庄组第三段为1608±74Ma(MSWD＝8.1).这些年龄数据与目前已有地质记录相吻合.串岭沟组的碳酸盐相的206Pb/204Pb-207Pb/204Pb未构成等时线,但全岩的206Pb/204pb-207Pb/204Pb比碳酸盐相具有更明显的线性趋势,其原因尚待进一步研究.另外,根据同一个样品用稀盐酸溶解和用氢氟酸加硝酸混合酸溶解的铅同位素比值的接近的现象,显示碳酸盐岩中的硅质没有陆源的特征,是沉积盆地中的产物.     

鄂尔多斯盆地奥陶系海相碳酸盐岩生烃性能与中部长庆气田气源成因研究

用激光 -荧光显微镜等有机岩石学方法 ,挑选样品中有明显生、排烃现象的碳酸盐岩 ,再以测定的这类碳酸盐岩的有机碳含量为依据 ,确定本区高成熟碳酸盐气源岩残余有机碳的下限指标用 0 .13%～ 0 .14 %比较合理。根据碳酸盐岩储层孔隙中充填沥青和皮膜状残余沥青的分布和含量 ,论证了陕参 1井等奥陶系碳酸盐岩地层在地质历史中 ,存在若干油气有效储层。采用连续升温 ,步进取样的热模拟实验方法 ,揭示了本区煤与碳酸盐岩干酪根随热演化作用增强 ,烃类气体产物的干燥系数增大 ,δ1 3C1 、δ1 3C2 明显变重的规律 ,并根据样品实验结果推算 ,本区石炭系—二叠系煤最大生气阶段的δ1 3C1 应为 - 2 7‰～ - 2 8‰ ,碳酸盐岩最大生气阶段的δ1 3C1 应为- 31.7‰～ - 33‰。在气源成因判识中 ,根据主生气期阶段对天然气成藏储聚的贡献最大、甲烷碳同位素较重以及长庆气田风化壳气藏天然气δ1 3C1 重值区并不与石炭系—二叠系煤的镜质组反射率高值区匹配的现象等进行气源判识 ,认为长庆奥陶系风化壳气藏 ,具有下古生界海相碳酸盐岩气与上古生界石炭系—二叠系煤成气的混源成因     

Understanding carbonate factories through palaeoecological and sedimentological signals – Tribute to Luis Pomar

The carbonate factories, their controlling factors and their palaeoecological and sedimentological signals recorded in sedimentary successions are key elements for understanding the evolution of carbonate platform systems. Luis Pomar has dedicated most of his academic life to the study of carbonate rocks and carbonate factories. The idea for this special issue to celebrate Pomar’s career arose during a session at the 34^th International Association of Sedimentologists meeting held in Rome, entitled ‘Understanding carbonate factories through palaeoecological and geochemical signals’. The proposal encountered great response among participants, and additional contributions followed an email invitation to other specialists. This issue contains a variety of papers on carbonate sedimentology and carbonate factories. Here, an introduction that contextualizes the papers and key concepts discussed in this thematic issue is provided. It reviews Luis Pomar’s major achievements in carbonate sedimentology and discusses the evolution of the concept of the carbonate factory and the series of palaeoecological and sedimentological signals used to characterize the wide spectrum of carbonate depositional systems found in the natural world.     

碳酸盐岩地区电磁波场的特性分析

形成岩溶的高阻碳酸盐岩对电磁波的吸收较弱，而且成层沉积的特定环境使碳酸盐岩地区岩石的各向异性现象较明显，由于地空界面的存在及岩溶洞壁两侧介质电性差异明显，界面清晰，又使电磁波出现强烈的反射及散射现象，从理论上对碳酸盐岩地区电磁波传播的特有现象进行了研究和分析，并给出结论。     

黄河口总碱度保守与非保守行为探讨

为了阐明黄河口TAlk（总碱度）的行为特征及主要影响因素,根据2004年4月黄河口TAlk实测数据,结合其它化学要素的同步观测资料对其进行了初步探讨.研究结果表明： 黄河口水体在S〈24的区域范围内TAlk呈现出非保守行为,其中 S〈5时TAlk非保守表现为净TAlk的“亏损”, 即水体TAlk低于理论混合TAlk,是由于水体中DIC的沉淀作用引起;在盐度为8～24之间,TAlk非保守表现为净TAlk的“增加”,即水体TAlk高于理论混合TAlk,主要是由于水体中颗粒碳酸盐溶解引起;水体中的CO2参与了颗粒碳酸盐的溶解,并且很可能是影响水体中碳酸盐溶解的主要因素.     

塔里木盆地古城地区下奥陶统碳酸盐岩碳氧同位素特征

下奥陶统碳酸盐岩储层是塔里木盆地古城地区的主要产气层。为了探讨研究区下奥陶统碳酸盐岩碳同位素变化的原因,对取自塔中地区古城7、古城8、古城9和古城12等4口井的51块碳酸盐岩样品进行了分析,结果显示,δ13C值为-2.26‰~1.55‰,δ18O值为-10.57‰~-4.69‰,Mn/Sr也小于2~3的范围。结果表明,研究区碳酸盐岩样品基本保持了碳氧同位素的原始组成。δ13C值与海平面变化存在正相关关系,证明研究区早奥陶世晚期存在一海退期。     

内蒙岱海湖岩芯碳酸盐含量变化与气候环境演化

内蒙岱海是位于东南季风区的西北边缘的内陆封闭湖泊,对气候变化十分敏感。本文根据对岱海湖泊岩芯的碳酸盐含量分析,结合湖泊沉积岩性特征、介形类化石以及其年代学研究,初步讨论了岱海距今近千年的气候环境演化过程,结果表明：９３０ａＢＰ—６７０ａＢＰ气候以温湿为主,６７０ａＢＰ—５４０ａＢＰ,气候以冷偏湿为主;５４０ａＢｐ—４９０ａＢ．Ｐ．湖泊急剧退缩,以冷偏干气候为主;４９０ａＢｐ—２７０ａＢＰ以凉干气候为主;２７０ａＢＰ－１５０温干气候;１５０年以来,湖区有效降水有所增加的温偏湿气候为主。     

纳米碳酸钙材料的工业合成与应用

该文对目前工业上生产纳米碳酸钙的方法作了较为详细的综述。对一步碳化法、两步碳化法、多段喷雾碳化法、旋转填充床碳化反应器碳化技术制备链形、纺锤形、球形、立方形等不同形状的纳米碳酸钙材料的方法进行了比较和总结