二次创业与南方海相碳酸盐岩油气勘探的发现与展望

本文概述了中国南方碳酸盐岩地区的油气勘探经历和认识过程.在刘光鼎院士提出的"油气资源二次创业"理论方法指导下,我国在海相碳酸盐岩地区开展的地球物理勘探工作取得了重要成果.海相碳酸盐岩地区具有更复杂的地质构造和演化过程,该类地区寻找油气是世界性难题,传统勘探手段已不适用.本文给出了该类地区进行地球物理勘探的新思路、新方法、新技术,并以举世瞻目的普光大气田的发现说明了新方法的合理性和优势.文章最后给出在南方海相碳酸盐岩地区进行油气地球物理勘探的发展远景.     

Theoretical analyses of acidization dissolution front instability in fluid‐saturated carbonate rocks

This paper presents an instability theory that can be used to understand the fundamental behavior of an acidization dissolution front when it propagates in fluid‐saturated carbonate rocks. The proposed theory includes two fundamental concepts, namely the intrinsic time and length of an acidization dissolution system, and a theoretical criterion that involves the comparison of the Zhao number and its critical value of the acidization dissolution system. The intrinsic time is used to determine the time scale at which the acidization dissolution front is formed, while the intrinsic length is used to determine the length scale at which the instability of the acidization dissolution front can be initiated. Under the assumption that the acidization dissolution reaction is a fast process, the critical Zhao number, which is used to assess the instability likelihood of an acidization dissolution front propagating in fluid‐saturated carbonate rocks, has been derived in a strictly mathematical manner. Based on the proposed instability theory of a propagating acidization dissolution front, it has been theoretically recognized that: (i) the increase of the mineral dissolution ratio can stabilize the acidization dissolution front in fluid‐saturated carbonate rocks; (ii) the increase of the final porosity of the carbonate rock can destabilize the acidization dissolution front, while the increase of the initial porosity can stabilize the acidization dissolution front in fluid‐saturated carbonate rocks; (iii) the increase of the mineral dissolution ratio can cause an increase in the dimensionless propagation speed of the acidization dissolution front; (iv) the increase of the initial porosity can enable the acidization dissolution front to propagate faster, while the increase of the final porosity can enable the acidization dissolution front to propagate slower in the acidization dissolution system. Copyright © 2012 John Wiley & Sons, Ltd.     

我国首次发现的纤碳铀矿

本文报道的纤碳铀矿产于湖南某花岗岩型铀矿床氧化带中。纤碳铀矿是一种铀酰碳酸盐矿物,在中国是首次发现。本文作了系统的矿物研究并与国外资料作了对比。     

Bauxite development in the North Apuseni mountains, western Romania

The stratigraphic and palaeogeomorphologic conditions of bauxite formation in the North Apuseni mountains are related to the geotectonic evolution of western Romania during the Late Jurassic and Early Cretaceous. Bauxitization, accumulation and preservation of the bauxites were directly associated with karst development in the area under study. The petrographic and mineralogic nature of the bauxite deposits reveal superimposed aliagenetic, catagenic and, locally, metamorphic features. A comparative analysis of the principal chemical components of the different bauxite-bearing zones of the North Apuseni mountains are used to show similar development.     

Organic geochemical studies of a recent Inner Great Barrier Reef sediment—I. Assessment of input sources

The concentration of solvent-extractable (SE) and bound hydrocarbons, ketones, alcohols, sterols, monocarboxylic acids, hydroxyacids and α,ω-dicarboxylic acids of a surface sample (0–2.5 cm) from a recent carbonate tropical sediment taken at 60ft (18m) depth north-west of the Low Isles, North Queensland, are reported in detail. n-Alkanes are a minor constituent in the SE and bound hydrocarbon fractions with the major component being unresolved complex hydrocarbon material which is not an anthropogenic input. 6,10,14-Trimethylpentadecan-2-one derived from chlorophyll, as well as phytol, were identified as major components of the ketone and alcohol constituents. No chlorophyll pigments or pigmented degradation products were present, implying degradation before incorporation into the sediment. This conclusion is consistent with evidence for higher-plant input in which all sensitive lipids have been degraded before incorporation. SE and bound fractions have been studied in detail and show considerable differences probably arising from the importance of viable biomass in the SE fraction. Inputs to the sediment are determined as higher plants, algae, bacteria, fungi and meiofauna in descending order of importance.     

Infrared estimates of aliphatic kerogen carbon in sedimentary rocks

An infrared routine has been developed to estimate the aliphatic portion of kerogen carbon in sedimentary rocks. The procedure does not require isolation of the organic matter and is based on a computer-assisted determination of global band areas in the region of the aliphatic carbon-hydrogen stretching vibrations around 2900cm⁻¹. From these integrated absorptions the amount of aliphatic carbon C_al (mg of aliphatic carbon per gram of solvent-extracted rock) is calculated by means of a calibration with model rocks. Carbonate overtones which interfere in the case of limestones are eliminated by comparison to a CaCO₃ standard.The method has been applied to rocks containing kerogens of different types and maturities at TOC levels of 0.5 to 12%. The aliphatic carbon concentrations range from 0.5 to 60mg·g⁻¹ and correlate reasonably well with the residual genetic potentials of the rocks as measured by S₂ values from Rock-Eval pyrolysis. The ratio S₂/C_al is found to decrease with burial depth reflecting a maturity enhanced conversion of aliphatic carbon to fixed aromatic carbon under Rock-Eval conditions.     

非渠化海相碳酸盐岩滩储集地质体的构型研究

１９８５年Ｍｉａｌｌ创立于河流沉积体系的构型单元分析方法可通过旋回性分级特征运用于非渠化海相碳酸盐岩滩沉积体中，并且在构型界面和构型 与河流沉积体的划分可进行对比，所获得的非均质性储层地质模型表明，沉积体最小的均一性单元是由二级界面所限定的较小规模中层型，该构型规模以上的非均质性特征受构型界面级次和构型单元多样性的控制。     

Fossil worm tubes from the presumed cold-seep carbonates of the Miocene Hayama Group, Central Miura Peninsula, Japan

Abstract Fossil worm tubes were collected from the Hayama Group, Miura Peninsula, Japan, together with abundant fossils of Calyptogena-Acharax clams. The fossil worm tubes were well preserved and coated with milky white amorphous silica. Most of the tubes were 1-3 mm in diameter, and up to 10 cm in length. Worm tubes were found in siltstone and limestone, and formed network-like assemblages. Elemental mapping on the tube cross-sections revealed the localization of sulfur, zinc and iron at the worm tubes, which suggests that sulfur-related metabolism and deposition occurred in association with the worm tubes. High resolution analysis revealed the localization of zinc-sulfur (sphalerite, ZnS) on the tubes, while iron-sulfur (pyrite, FeS₂) was localized at the center of the tubes. The spatially separate sphaleritization and pyritization imply that epiphytic and endosymbiotic microorganisms perform different sulfur metabolisms, such as sulfate-reduction and sulfide-oxidation.     

断陷湖盆碳酸盐与陆源碎屑混合沉积——以东营凹陷金家地区古近系沙河街组第四段上亚段为例

混合沉积是一种特殊的沉积类型,研究程度较低。金家地区处于东营凹陷的斜坡带,该区古近系沙河街组第四段上亚段发育了碳酸盐与陆源碎屑的混合沉积,研究认为该混合沉积为古湖泊内的混合沉积,可划分为混积砂滩亚相、混积砂坝亚相及半深湖混积亚相,混合沉积物既包括同层混合沉积物（灰质砂岩、砂质灰岩、泥质灰岩等）,又包括互层混合沉积物（砂岩与颗粒灰岩互层沉积等）,研究区的混合沉积受当时构造运动、碎屑物质供给量、湖平面的变化等诸多因素控制。