银额盆地石板泉西石炭系白山组碳酸盐岩地球化学特征及其环境意义

对银额盆地石板泉西石炭系白山组碳酸盐岩进行详细的地球化学分析,探讨各特征元素对古环境、古气候的指示意义。地球化学测试结果显示：除样品CH3外,其余样品主量元素中的Al及微量元素中的Ti、Zr、Th等典型陆源特征元素的含量较低,Y/Ho平均值为45.58,反映研究区白山组碳酸盐岩较少受陆源物质输入的影响;δCe与δEu、w（ΣREE）、（La/Sm）_N未见良好的相关性,也不具备Eu正异常,说明研究区白山组碳酸盐岩受成岩作用和热液作用的影响也较为有限。碳酸盐岩中所含微量元素主要为海水自生成因,能够反映原始沉积环境。根据特征元素对古水深、古盐度、古气候、古氧相和古水温进行研究,显示研究区白山组碳酸盐岩段虽然岩性较为单一,但其地球化学特征可以反映早晚的沉积古环境差异。研究区白山组碳酸盐岩总体经历了1个大的海侵海退旋回,沉积于正常海水,气候潮湿,弱氧化—弱还原环境,古水温为8.51~27.10℃,早期水温低,晚期水温升高。     

方解石与含硅流体的水-岩反应实验及其对“硅化碳酸盐岩”储层成因的启示

近年来的油气勘探表明, 含硅热液是碳酸盐岩层系中一种重要的溶蚀性流体, 查明其与碳酸盐岩的水-岩反应机理是揭示“硅化碳酸盐岩”储层发育机制并实现储层分布预测的基础和关键问题之一。文章采用熔融毛细硅管和水热反应釜为反应腔,开展了200~375℃范围内方解石和含硅流体的水岩反应实验。利用原位拉曼光谱技术在线描述反应过程中体系组成的变化,对于淬火后的固相样品,则采用扫描电镜—能谱分析进行形貌观测和成分鉴定。首先,查明了含硅流体与方解石脱碳反应发生的温度条件。方解石和含硅流体在275℃以上反应形成CO₂,固相为非硅灰石的钙硅酸盐,其结构有待进一步揭示。该结果表明单纯的硅质组分难以在储层温度条件下与灰岩发生反应;其次,提出高盐度、富CO2流体作用是造成灰岩溶蚀的重要因素;最后, CO₂的存在能够促进硅质（含石英）沉淀。在上述实验认识的基础上,结合前人研究结果探讨了塔里木盆地顺托果勒地区“硅化碳酸盐岩”储层的发育机制。含硅热液沿深大断裂上移,途径震旦系—下奥陶统白云岩层系,其中的硅质组分将与白云石反应形成富镁硅酸盐和CO₂。CO₂是重要的酸性组分,有利于鹰山组碳酸盐的溶蚀和孔隙的保存。流体温度和压力的降低以及CO₂的存在促进了石英沉淀,并形成了大量的石英晶间孔隙。     

Plio-Pleistocene sedimentation in coastal grabens,north-east Rhodes,Greece

The stratigraphy of marine Plio-Pleistocene sediments from northeast Rhodes (Dodecanese islands, Greece) is revised in the light of facies mapping and the recognition of three major transgression–regression cycles. Before late Pliocene submergence, metamorphosed Mesozoic limestones formed a high-relief karstic landscape. During subsequent transgressions, subsiding basins with spectacular cliffed and bioeroded margins were infilled by a mosaic of carbonate-dominated sediments, sourced by high rates of carbonate productivity on narrow shelves rimming the basins and their drowning islands. Periods of relative sea-level fall superimposed a complex series of ‘fossil’ coastal geomorphological features such as cliffs, abrasion platforms, surf caves, notches, boulder beaches and palaeokarsts. These created the rugged present day topography of the island's northeast coast. Three main lithostratigraphic units, the Kritika, Rhodes and Lindos Acropolis Formations, are defined. The Rhodes and Lindos Acropolis Formations are subdivided into mappable facies groups rather than members, as the lithofacies are strongly diachronous. The Kritika and Rhodes Formations were each subaerially exposed and partly eroded before re-transgression. Although there is a general pattern of lithological succession, details vary across the study area and some facies groups are restricted in development, indicating differences in tectonic behaviour and palaeo-geomorphology between neighbouring basins. A preliminary process-response model is presented for the sedimentation history of the Rhodes and Lindos Acropolis Formations, using sedimentological, palaeontological, palaeoecological and ichnological data.     

裂缝性碳酸盐岩裂缝的双侧向测井响应特征及解释方法

裂缝评价是裂缝性碳酸盐岩储层评价的关键, 其常规评价方法受到裂缝发育的不均匀性及储层各向异性的影响而存在诸多困难.采用三维数值算法, 利用宏观各向异性地层模型, 研究不同的裂缝参数条件下双侧向测井响应特征, 由此导出一种用于裂缝孔隙度计算的快速算法.分析表明, 裂缝的双侧向响应同裂缝孔隙度与孔隙流体电导率之间存在明显的线性关系, 裂缝的倾角造成双侧向测井曲线幅度差异的变化; 不同倾斜情况下, 将双侧向测井响应近似表示为岩石基岩电阻率、裂缝孔隙度、裂缝流体电导率的函数, 用于裂缝孔隙度的快速计算.实际资料处理表明, 利用双侧向依据该方法确定的裂缝参数同成像测井资料具有良好的对应性.      

利用地震资料反演地层的碳酸盐含量

基于碳酸盐含量与地层速度、密度之间的关系, 在井资料约束下, 使用人工神经网络方法反演高分辨率地震资料所反映的地层碳酸盐含量, 并应用于南海北部陆坡ODP184航次1146和1148孔区, 取得较好效果.方法的关键是从井旁地震道中提取多种属性, 利用逐步回归法, 确定6种与碳酸盐含量相关性最好的地震属性, 分别是平均频率、道积分绝对振幅、主频、时间、道微分瞬时振幅和瞬时频率, 然后进行地层碳酸盐含量反演.反演结果相对于岩心分析的碳酸盐含量的误差大多在±5%之内, 较为精确地揭示了地震地层剖面上碳酸盐含量的分布.      

鲁西枣庄-临沂地区新元古界震碛岩的主要特征

鲁西枣庄—临沂地区新元古界碳酸盐岩系中,发育有由地震造成的同沉积构造现象,如微晶方解石脉、层内变形褶曲、层内微断层和内碎屑碳酸盐岩堆积等。野外实地观察、地质剖面测量和室内分析研究认为它们是由地震产生的强震动,使距震中一定范围的未固结沉积物经震动液化,震动变形形成的震积岩组合。根据其发育规律与组合特征,该地区震碛岩的形成应与古郯庐断裂在新元古代的活动密切相关。可初步确定为含有A、B和C3个震积岩单元的震动液化地震序列。     

渤海湾盆地济阳坳陷潜山油藏分布规律及控制因素

济阳坳陷潜山油藏类型复杂,构造裂缝是油藏的主要储集空间。济阳坳陷潜山储层的分布主要受控于盆地的形成过程,构造运动是控制潜山分布的最主要的因素。潜山储层非均质性强,且不同潜山的储层性质存在较大差异。济阳坳陷潜山油藏的开发特征复杂,稳产阶段短、产能差异大、含水上升快。中生代及以前形成的古地貌早隆潜山是济阳坳陷最有利的潜山油藏勘探目标。      

Adding the missing third and fourth dimensions to trajectory analysis in carbonate systems

We developed a seismic geomorphology-based procedure to enhance traditional trajectory analysis with the ability to visualize and quantify lateral variability along carbonate prograding-margin types (ramps and rimmed shelves) in 3D and 4D. This quantitative approach analysed the shelf break geometric evolution of the Oligo-Miocene carbonate clinoform system in the Browse Basin and delineated the feedback between antecedent topography and carbonate system response as controlling factor on shelf break rugosity. Our geometrical analysis identified a systematic shift in the large-scale average shelf break strike direction over a transect of 10 km from 62° to 55° in the Oligo-Miocene interval of the Browse Basin, which is likely controlled by far-field allogenic forcing from the Timor Trough collision zone. Plotting of 3D shelf break trajectories represents a convenient way to visualize the lateral variability in shelf break evolution. Shelf break trajectories that indicate contemporaneous along-strike progradation and retrogradation correlate with phases of autogenic slope system re-organization and may be a proxy for morphological stability of the shelf break. Shelf break rugosity and shelf break trajectory rugosity are not inherited parameters and antecedent topography does not dictate long-term differential movement of the shelf margin through successive depositional sequences. The autogenic carbonate system response to antecedent topography smooths high-rugosity areas by filling accommodation and maintains a relatively constant shelf break rugosity of ~150 m. Color-coding of the vertical component in the shelf break trajectory captures the creation and filling of accommodation, and highlights areas of the transect that are likely to yield inconsistent 2D sequence stratigraphic interpretations.     

全球主要河流流域碳酸盐岩风化碳汇评估

碳酸盐岩风化吸收的大气CO₂主要以HCO₃ ^-形式连续地经由河流从大陆输送到海洋,成为陆地生态系统的重要碳汇。目前主要河流流域的碳酸盐岩风化碳汇估算存在不确定性,分布格局尚不清晰。基于GEMS-GLORI全球河流数据库提供的全球10万km ²以上主要河流流域多年平均监测数据,利用水化学径流法估算出全球主要河流流域碳酸盐岩对CO₂的吸收速率为0.43±0.15 Pg CO₂ yr ^-1,平均CO₂吸收通量为7.93±2.8 t km ^-2 yr ^-1。CO₂吸收通量在不同气候带下差异显著,热带和暖温带CO₂年吸收速率占全球主要河流流域年吸收速率的62.95%。冷温带CO₂年吸收速率占全球主要河流流域的33.05%,仅次于热带地区。本文划分出全球CO₂吸收通量的9个关键带,关键带的交汇处CO₂吸收通量较高。喀斯特出露流域碳酸盐岩对CO₂吸收通量的均值为8.50 t km ^-2 yr ^-1,约为非喀斯特流域的3倍。全球喀斯特出露流域碳酸盐岩风化碳汇在全球碳循环、水循环及碳收支平衡估算研究方面占据重要地位。