一种修正的SeaWinds散射计圆中数滤波法

利用最大似然法(MLE)对SeaWinds散射计数据反演得出的风矢量一般存在2—4个模糊解,而且第1模糊解构成的风场在轨道外侧区域容易出现块状模糊,所以不能像SASS和NSCAT等散射计那样,以第1模糊解初始化风场后用圆中数滤波法进行模糊去除。文章根据SeaWinds散射计第1模糊解的空间分布特性,对传统圆中数滤波法进行了修正,使之适合SeaWinds散射计的模糊去除,即在缺乏参考数据进行初始化的前提下,能够有效去除块状模糊问题。     

Characterisation of the carbonate content of atmospheric aerosols

A programme of aerosol sampling by dichotomous sampler has been undertaken with analysis of soluble ions plus carbonate. The technique for carbonate involved release of CO₂ by HCl vapour and quantitative measurement of the CO₂ by FTIR spectroscopy. The method is suitable for amounts down to below 10g CO₃ ^2- per filter. The prevailing atmospheric levels in an urban area were found to be below 1g m^-3. Information on the particle size from the dichotomous sampler was supplemented by use of a cascade impactor. Although CaCO₃ is clearly the dominant species initial analyses demonstrated higher carbonate levels than could be accounted for on the basis of the concentrations of calcium and magnesium ions which are the most likely cations in mineral carbonates. Analysis with and without heating to 100°C in a vacuum oven demonstrates the presence of carbonate in volatile form. This could be due to carbon dioxide adsorbed onto particulate matter such as soot.     

辽东早元古代碳酸盐岩的地质地球化学特征

辽东半岛早元古宙坳拉槽内靠近优地槽一侧,分布着一套复杂碳酸盐岩系,其下部和海底拉斑玄武岩呈沉积接触,或薄互层状共存,与火山凝灰岩互层。底部碳酸盐岩主要为钙型,向上过渡为钙镁型碳酸盐,其中含有数层由海底喷气作用形成的硅质岩,上部的硅质条带状碳酸盐岩中含有条带状、条纹状喷气沉积的硫化物。碳酸盐岩系顶部为厚层质纯镁质碳酸盐岩,局部含巨厚层状菱镁矿。岩系中碳酸盐岩、硅质岩、金属硫化物的稀土特征和铁锰指数具有一致性。铅同位素研究表明它们源于下地壳。有证据显示:碳酸盐岩系是在一定水深条件下由沉积作用形成的。这和碳氧同位素碳研究的结果吻合。种种特征表明这套复杂的碳酸盐岩系具有其独特性,可能暗示着一种特殊的碳酸盐岩形成方式。     

胶北地块古元古代花岗伟晶岩脉的锆石SHRIMP ——Pb年代学特征及地质意义

胶辽吉古元古代造山带是近年来国内古老造山带研究的热点地区,胶东半岛的胶北地块位于胶辽吉造山带南部,在胶北地块莱西一带发育了大量的古元古代荆山群变质地层,其中发育大量的花岗伟晶岩（脉）体,本次工作利用SHRIMP UPb测年技术,首次精确测定了花岗伟晶岩的形成时代为~1.84Ga,同时结合前人资料,确定了胶东半岛发育有与1.84Ga伸展作用相关的花岗伟晶岩类。通过与辽西地区所报道的花岗伟晶岩对比,认为二者在古元古代构造演化的过程中具有时空一致性。     

胶北地块古元古代花岗伟晶岩脉的锆石SHRIMP U-Pb年代学特征及地质意义

胶-辽-吉古元古代造山带是近年来国内古老造山带研究的热点地区,胶东半岛的胶北地块位于胶-辽-吉造山带南部,在胶北地块莱西一带发育了大量的古元古代荆山群变质地层,其中发育大量的花岗伟晶岩(脉)体,本次工作利用SHRIMP U-Pb测年技术,首次精确测定了花岗伟晶岩的形成时代为~1.84Ga,同时结合前人资料,确定了胶东半岛发育有与1.84Ga伸展作用相关的花岗伟晶岩类。通过与辽西地区所报道的花岗伟晶岩对比,认为二者在古元古代构造演化的过程中具有时空一致性。     

Biogeochemistry of southern Australian continental slope sediments

Sediment cores from the middle to lower slope of the southern continental margin of Australia between the Great Australian Bight and western Tasmania are compared in terms of marine and terrigenous input signals during the Holocene. The mass accumulation rates of carbonate, organic carbon, biogenic Ba, and Al are corrected for lateral sediment input (focusing), using the inventory of excess ²³⁰Th in the sediment normalised to its known production rate in the water column above each site. The biogenic signal is generally higher in the eastern part of the southern margin probably due to enhanced productivity associated with seasonal upwelling off southeastern South Australia and the proximity of the Subtropical Front, which passes just south of Tasmania. The input of Al, representing the terrigenous signal, is also higher in this region reflecting the close proximity of river runoff from the mountainous catchment of southeastern Australia. The distribution pattern of Mn and authigenic U, together with pore‐water profiles of Mn⁺⁺, indicate diagenetic reactions driven by the oxidation of buried organic carbon in an oxic to suboxic environment. Whereas Mn is reduced at depth and diffuses upwards to become immobilised in a Mn‐rich surface layer, U is derived from seawater and diffuses downward into the sediment, driven by reduction and precipitation at a depth below the reduction zone of Mn. The estimated removal rate of U from seawater by this process is within the range of U removal measured in hemipelagic sediments from other areas, and supports the proposition that hemipelagic sediments are a major sink of U in the global ocean. Unlike Mn, the depth profile of sedimentary Fe appears to be little affected by diagenesis, suggesting that little of the total Fe inventory in the sediment is remobilised and redistributed as soluble Fe.     

Cathodoluminescence study of carbonate cements in the Upper Cambrian conglomerates from the Wonominta Block,northwestern New South Wales

Petrological studies were carried out on the Upper Cambrian conglomerates from the Bilpa and Cupala Creek areas, in the Wonominta Block, northwestern New South Wales. The sediments are post‐orogenic, molasse‐type, shaped in continental and shallow‐marine environments, and deposited in the form of major coarse‐grained deltas. Diagenetic processes caused an extensive lithification of these psephitic deposits. Multistage carbonate cementation is one of the most significant diagenetic changes that occurred. Several generations of carbonate cements have been distinguished based on observations under the polarising microscope, and particularly, using cathodoluminescence analysis. In both areas studied the conglomerates show four types of calcite cements under cathodoluminescence developed in the following order: non‐luminescent (+oscillatory zoned)‐bright orange‐dull orange‐(non‐luminescent). The most likely sequence of carbonate cementation is presented involving eo‐, meso‐ and telo‐ stages of diagenesis. Minor malachite crystallised along with calcite in the telodiagenetic stage.     

A high‐altitude temporary spring in a compartmentalized carbonate aquifer: the role of low‐permeability faults and karst conduits

The aim of this research was to refine the actual conceptual model related to the activation of high‐altitude temporary springs within the carbonate Apennines in southern Italy. The research was carried out through geophysical, hydrogeological, hydrochemical and isotopic investigations at the Acqua dei Faggi experimental site during five hydrologic years. The research demonstrated that, in carbonate aquifers where low‐permeability faults cause the aquifer system to be compartmentalized, high‐altitude temporary springs may be recharged by groundwater. In such settings, neither surface water infiltration in karst systems nor perched temporary aquifers play a role of utmost importance. The rare (once or a few time a year) activation of such springs is due to the fact that groundwater unusually reach the threshold head that allows the spring to flow. The activation of the studied high‐altitude temporary spring also depended on relationships between a low‐permeability fault core and a karst system that locally interrupts the low‐permeability barrier. In fact, when the hydraulic head did not reach the karst system, the concentrated head loss within the fault core did not allow the spring to flow, because the groundwater entirely flowed through the fault towards the downgradient compartment. Copyright © 2009 John Wiley & Sons, Ltd.     

1∶20万岩石化探测量碳酸盐岩分析方法研究——等离子体质谱为主的配套分析方法

研究了碳酸盐岩中基体元素Ｃａ和Ｍｇ对测定痕量元素的影响及消除办法，建立了用等离子体质谱法测定碳酸盐岩石中２６个痕量元素的３个分析流程；并采用Ｘ射线荧光光谱、石墨炉原子吸收光谱、原子荧光光谱等方法配套测定了碳酸盐岩石中１５种主、次量元素。配套方法的检出限、精密度、准确度均符合１∶２０万岩石化探测量碳酸盐岩分析技术指标要求。方法经标样及碳酸盐岩石样品分析验证，其结果与不同实验室、不同方法测定结果相符。     

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