Determining the seasonality of groundwater recharge using water isotopes: a case study from the upper North Han River basin,Korea

The stable isotopes of oxygen and hydrogen were used to determine the seasonal contributions of precipitation to groundwater recharge at a forested catchment area in the upper North Han River basin, Korea. A comparison of the stable isotopic signatures of groundwater and precipitation indicates that the precipitations which occurred during both the dry and rainy seasons are the important source of groundwater recharge in this region. A stable isotopic signature shown in the stream waters at the upstream reaches is similar to that of groundwaters, indicating that stream waters are mostly fed by groundwater discharge. Reservoir waters in the downstream flood control dams have lower deuterium excess values or d-values compared with those of the upstream waters, indicating a secondary evaporative enrichment. These results can provide a basis for the effective management of groundwater and stream water resources in the North Han River basin.     

Tracer methods used to verify the hypothesis of Cvijić about the underground connection between Prespa and Ohrid Lake

Prespa Lake and Ohrid Lake constitute a hydraulic system shared between Albania, FYR of Macedonia and Greece. Karst rocks separate both lakes. The elevation of Prespa Lake is about 150 m higher than that of Ohrid Lake. Considering these facts, Cvijić formulated in 1906 the hypothesis that Prespa Lake recharges the St. Naum and Tushemisht springs at Ohrid lakeside. Environmental isotopes demonstrated that Prespa Lake recharges about 37–42 and 52–54% of water emerging in St. Naum, and Tushemisht springs, respectively. An artificial tracer experiment carried out in 2002 physically demonstrated the underground connection between both lakes. This experiment confirmed the supposed underground connection and brought important information about the groundwater velocity, transit time, and karst water conduits development.     

Hydrogeology of the Winnipeg Formation in Manitoba, Canada

The Winnipeg Formation is the basal sedimentary unit throughout much of southern and central Manitoba, Canada, where it forms a regional aquifer over most of its extent. This aquifer is an important source of water in southeastern Manitoba and in Manitoba’s Interlake area, but in most other areas, groundwater within the aquifer is saline. Chemical and isotopic evidence indicate the presence of groundwaters of three different origins: (1) basin brines; (2) modern meteoric recharge; and (3) subglacial recharge that occurred during the late Pleistocene. Hydraulic head and sedimentary facies distributions indicate that the flow system in parts of the area is not in a state of equilibrium and saline waters will encroach on areas currently occupied by freshwater in some areas, while in other areas, freshwater will replace saline water. These features must be considered in groundwater resource management, as groundwater withdrawals will likely hasten these processes.

---

Resumen La Formación Winnipeg es la unidad sedimentaria basal en la mayor parte de Manitoba central, Canadá, donde forma un acuífero regional en la mayor parte de su extensión. Este acuífero es una fuente importante de agua en el Sureste de Manitoba y el área de entrelagos de Manitoba, pero en la mayoría de las otras zonas del acuífero, el agua es salina. Las evidencias químicas e isotópicas indican que existen aguas subterráneas de tres orígenes diferentes: (1) salmueras de cuenca; (2) recarga meteórica actual; y (3) recarga subglacial ocurrida durante el Pleistoceno Superior. Los niveles piezométricos y la distribución de las facies sedimentarias indican que el sistema de flujo no se encuentra en estado de equilibrio en parte del área y las aguas salinas irán invadiendo áreas actualmente ocupadas con aguas dulces, mientras que en otras zonas el agua dulce está reemplazando al agua salina. Estos hechos deben ser considerados en la gestión de las aguas subterráneas como recurso, ya que las extracciones de agua acelerarán probablemente estos procesos.

---

Résumé La Formation de Winnipeg est l’unité sédimentaire de base sur la plus grande partie du Sud et du centre du Manitoba au Canada, où elle forme un aquifère régional sur pratiquement toute son extension. Cet aquifère représente une ressource en eau importante dans le Sud-Est du Manitoba et dans les zones d’entre les lacs, mais salée dans la plus part des autres zones. Les indications isotopiques et chimiques permettent de distinguer trois différentes origines des eaux souterraines: (1) les saumures de bassin; (2) la recharge météoritique moderne; (3) la recharge sub-glaciaire qui est apparue durant le Pléistocène récent. Les charges hydrauliques et la distribution des faciès sédimentaires indiquent que le système d’écoulement dans certaines zones n’est pas dans un état d’équilibre et que les eaux salées empièteront sur des zones d’eau douce, tandis que dans d’autres zones l’eau douce remplacera les eaux salées. Ces aspects doivent être considérés dans la gestion des ressources en eau souterraine, car le prélèvement des eaux souterraines pourrait accentuer ces processus.

     

The effects of organic removal treatment on the integrity of δ<Superscript>18</Superscript>O measurements from biogenic silica

Prior to oxygen isotope analysis of biogenic silica by fluorination techniques, sediments must be cleaned of all organic compounds. Despite the expanding volume of research utilising oxygen isotope ratios in biogenic silica in palaeoclimatology, very little is known about the effects of different standard preparation methods for the removal of organic matter on the isotope values. Here we compare a number of methods for the removal of organic matter in order to assess their effectiveness and influence on subsequent isotope measurements. Not all the methods described here effectively removed organic matter, the best treatments were H₂O₂ and ignition in air at 550°C. Ignition in air at 950°C, and heating in vacuum at 250 and 450°C results in marked alteration of isotope values, whereas use of hydrogen peroxide (H₂O₂), nitric acid (HNO₃) and plasma ashing have little or no effect, within the bounds of analytical error. Ignition in air at 550°C was the most effective technique, and induced no alteration of δ¹⁸O_silica, but practical constraints may limit the application of this method routinely. Our findings indicate that considerable caution is required when preparing sediment for isotope analysis of biogenic silica.     

Four thousand years of atmospheric lead pollution in northern Europe: a summary from Swedish lake sediments

This paper presents a large palaeolimnological study of the pre-industrial and industrial history of atmospheric lead pollution deposition in Sweden. Both lead concentrations and ²⁰⁶Pb/²⁰⁷Pb ratios have been analysed in 31 lakes covering most of Sweden, plus one lake in north-west Russia. Four of the lakes have varved (annually-laminated) sediments. Isotope analysis is a sensitive and effective method to distinguish pollution lead from natural catchment lead and to detect early pollution influence, because the ²⁰⁶Pb/²⁰⁷Pb ratio in unpolluted background sediments in Sweden was > 1.3, while that of lead from pollution, derived from ores and coal, was < 1.2. The sediments show a consistent picture of past temporal changes in atmospheric lead pollution. These changes include: the first traces of pollution 3,500-3,000 yrs ago; a pollution peak in Greek-Roman Times (about 0 AD); lower lead fall-out between 400 and 900 AD; a significant and permanent increase in atmospheric lead fall-out from about 1000 AD; an increase with the Industrial revolution; a major increase following World War II; the maximum peak in the 1970s; and decreasing fall-out over the last decades. The four varved sediments provide high-resolution records of atmospheric pollution. They reveal pollution peaks about 1200 and 1530 AD which match the history of metal production in Europe. According to the varve records the lead pollution level in the late 1990s had decreased beneath the level of the 1530s. The pollution level 1200 AD was about 35% of the 1980s, when lead pollution was still near its all time high. About 50% of the total accumulated atmospheric lead pollution deposition through time was deposited in the pre-industrial period. The sediments also show a consistent picture of the geographic distribution of atmospheric lead deposition over time, with higher deposition in south Sweden and declining levels to the north, which supports the hypothesis that the main sources of pre-industrial atmospheric lead pollution in Sweden were cultural areas in mainland Europe and Great Britain.     

胶南榴辉岩矿物氧同位素平衡及其Sm-Nd年代学制约

对苏鲁地体中的胶南榴辉岩进行了矿物氧同位素分析，并与同一手标本矿物的Sm-Nd内部等时线定年和Nd-Sr同位素分布进行了对比。研究表明，石榴子石与绿辉石之间的氧同位素平衡与否能够对矿物Sm-Nd同位素体系的平衡状况和内部等时线定年结果的有效性给予直接制约。合理的石榴子石＋绿辉石Sm-Nd内部等时线年龄产于两矿物之间达到并在峰变质条件下保持氧同位素平衡的样品中，而两矿物之间处于氧同位素不平衡的样品不能给出正确的Sm-Nd内部等时线年龄。同一矿物在手标本尺度出现显著的O-Nd-Sr同位素不均一性，据此对这些元素在石榴子石和绿辉石中的扩散速率顺序进行了估计，不仅得到了与实验扩散系数相吻合的结果，而且由此估计出在峰变质条件下达到矿物内部同位素均一化所需要的时间应大于10Ma。     

北祁连九个泉玄武岩的形成环境及地幔源区特征：微量元素和Nd同位素地球化学制约

北祁连九个泉蛇绿岩中的玄武岩的MORB，根据其地质产状和地球化学特征又可以分为两部分，剖面下部的玄武岩为N－MORB，上部的玄武岩主要为E－MORB。玄武岩多数具有Nb负异常，从下向上，九个朱武岩的Th,Nb,LREE,Zr等含量及（La/Yb)N,(La/Sm)N,Ce/Zr,Zr/Y,Th/.La,Th/Yb比值逐渐增加，并伴随着Y，Yb,Lu,Sc含量，Zr/Nb和La/Nb比值以及εEd(t)的逐渐减小，不相容元素比值及εNd(t)之间具有很好的相关性，上述特征反映不均一地幔部分熔融过程中N－MORB源区和富集地幔之间的混合作用，微量元素和Nd同位素地球化学特征表明九个泉蛇绿岩形成于弧后盆地中的海山环境，玄武岩的化学成分在垂向上的变化记录了海山生长并逐渐远离扩张脊的动态的地质过程，海山可能是形成蛇绿岩的一种重要环境。     

Use of deuterated water as a conservative artificial groundwater tracer

Conservative tracers are necessary to obtain groundwater transport velocities at the field scale. Deuterated water is an effective tracer for this purpose due to its similarity to water, chemical stability, non-reactivity, ease of handling and sampling, relatively neutral buoyancy, and reasonable price. Reliable detection limits of 0.1 mg deuterium/L may be obtained in field tests. A field example is presented in which deuterated water, bromide, and pentafluorobenzoic acid are used as groundwater tracers. Deuterated water appeared to be transported conservatively, producing almost identical breakthrough curves as that of other soluble tracers. Electronic Publication     

Fault-controlled dolomitization at Swan Hills Simonette oil field (Devonian), deep basin west-central Alberta, Canada

The partly dolomitized Swan Hills Formation (Middle‐Upper Devonian) in the Simonette oil field of west‐central Alberta underwent a complex diagenetic history, which occurred in environments ranging from near surface to deep (>2500 m) burial. Five petrographically and geochemically distinct dolomites that include both cementing and replacive varieties post‐date stylolites in limestones (depths >500 m). These include early planar varieties and later saddle dolomites. Fluid inclusion data from saddle dolomite cements (T_h=137–190 °C) suggest that some precipitated at burial temperatures higher than the temperatures indicated by reflectance data (T_peak=160 °C). Thus, at least some dolomitizing fluids were ‘hydrothermal’. Fluorescence microscopy identified three populations of primary hydrocarbon‐bearing fluid inclusions and confirms that saddle dolomitization overlapped with Upper Cretaceous oil migration. The source of early dolomitizing fluids probably was Devonian or Mississippian seawater that was mixed with a more ⁸⁷Sr‐rich fluid. Fabric‐destructive and fabric‐preserving dolostones are over 35 m thick in the Swan Hills buildup and basal platform adjacent to faults, thinning to less than 10 cm thick in the buildup between 5 and 8 km away from the faults. This ‘plume‐like’ geometry suggests that early and late dolomitization events were fault controlled. Late diagenetic fluids were, in part, derived from the crystalline basement or Palaeozoic siliciclastic aquifers, based on ⁸⁷Sr/⁸⁶Sr values up to 0·7370 from saddle dolomite, calcite and sphalerite cements, and ²⁰⁶Pb/²⁰⁴Pb of 22·86 from galena samples. Flow of dolomitizing and mineralizing fluids occurred during burial greater than 500 m, both vertically along reactivated faults and laterally in the buildup along units that retained primary and/or secondary porosity.