胶州湾沉积物中有机硫来源及成因机制的研究

有机硫是海洋沉积物中重要的硫形态,其中成岩有机硫对有机质保存和微量元素形态具有重要影响。利用化学提取及硫稳定同位素研究了胶州湾沉积物中碱可提取的腐殖酸硫(HA-S)、富里酸硫(FA-S)以及铬不可还原有机硫(non-CROS)的垂直分布、来源及形成机制。结果表明,non-CROS、HA-S以及FA-S的含量范围分别为19.1~52.6、3.35~7.82和27.3~38.6μmol/g,均处于其他许多近海沉积物中含量的低值区,且3者均为海洋生物有机硫和成岩有机硫的混合物。HA-S和nonCROS以海洋生物有机硫为主,其份数分别为65%~68%和67%~77%,而FA-S则以成岩有机硫为主(54%~73%)。相对于生物有机硫,成岩有机硫更易被碱和酸性Cr(Ⅱ)溶液提取,因此腐殖质硫和non-CROS都不能全面反映沉积物中有机硫的组成和来源。黄铁矿和腐殖质中成岩有机硫含量随深度的同步增加表明黄铁矿形成并未明显地竞争性抑制有机质硫化。     

13C/12C比值作为海洋生态系统食物网示踪剂的研究──崂山湾水体生物食物网的营养关系

于1992年9月–1994年5月先后对崂山湾海域作了7个航次调查。由实验室培养试验和现场采样分析两种方法得出食物链一个营养级的¹³C富集度分别为(1.6±0.2)×10^-3和1.7×10^-3,两者几乎一致。由7个季度月的现场采集样品的同位素分析结果表明,从处在食物网底部的浮游植物到最高级的肉食性鱼类之间δ¹³C差值平均为6.9×10^-3,相当于5个营养级;并由各类生物的碳同位素数据分别确定了它们在该食物网中的营养位置,其结果与食性分析方法所得结果基本吻合。同位素示踪方法研究的结果还表明,崂山湾水体生物食物网中碳的来源主要是浮游植物碳。     

碳、氧、锶同位素在羌塘盆地龙尾错地区层序地层研究中的应用

结合野外露头层序地层研究,探讨了羌塘盆地龙尾错地区中上侏罗统地层层序地层划分及其C、O、Sr同位素响应.认为自中侏罗统布曲组(J2b)-上侏罗统雪山组一段(J3xs1)可划分出三个三级层序.其中布曲组-索瓦组二段下部,C、O、Sr同位素在同一层序内呈有规律变化:在TST体系域内δ13C、δ18O、87Sr/86Sr均值较高,在纵向变化曲线上表现为正偏,而在HST体系域内表现为相对的负偏.其纵向上的三次明显正偏与负偏可分别对应于三次海底的停滞与扩张.文章同时分析了个别异常样品的数据特征及其成因.     

全球不同构造环境蛇纹岩全岩和矿物微量元素组成及非传统稳定同位素(Fe-Zn-Cu同位素)特征

蛇纹岩对地球深部和浅部的元素循环以及氧化还原状态调节具有非常重要的作用。蛇纹岩中的流体活动性元素(fluid-mobile element, FME)是揭示地幔岩石水化、脱水以及元素循环的关键。本文系统收集和分析了前人报道的不同构造环境的蛇纹岩矿物化学、全岩微量元素和非传统稳定同位素(Fe、Zn、Cu)的组成特征,试图从多个角度总结蛇纹岩脱水过程的元素迁移规律及流体性质。蛇纹岩主要矿物蛇纹石微量元素含量具有以下主要特征：(1)不同变质程度的蛇纹岩中的蛇纹石既包含轻稀土元素(light rare earth element, LREE)富集,又包含LREE亏损的特征;(2)纤蛇纹石的REE和微量元素分布在利蛇纹石和叶蛇纹石的范围内,利蛇纹石重稀土元素(heavy rare earth element, HREE)整体上略高于叶蛇纹石且更加富集FME;(3)通过中度不相容元素与REE含量相结合,能够较好地区分橄榄石和辉石蛇纹石化所形成的蛇纹石,即辉石形成的蛇纹石富集相容元素(如Sc、Zn、Cr、Y和Ti等)并具有较高的HREE,而橄榄石形成的蛇纹石则表现为平坦且整体较低的REE分布型式。在...     

基于碳、氮稳定同位素的雅浦海沟底栖生物食物来源和营养级初探

为了分析雅浦海沟中底栖生物群落的食物来源和营养级,本研究分析了雅浦海沟真光层中浮游植物和浮游动物、海底沉积物和巨型底栖生物（海绵、海参、海蛇尾、海星、海葵和钩虾）中的碳、氮稳定同位素组成。研究发现雅浦海沟真光层中的浮游植物和浮游动物δ13C值[（-22.8±0.4）‰和（-21.8±0.8）‰]和δ15N值[（5.4±0.4）‰和（6.8±0.2）‰]与巨型底栖生物的δ13C值（-20.1‰~-16.8‰）和δ15N值（11.9‰~17.9‰）的差异超过了一个营养级,表明作为底栖生物的初始食物来源的浮游植物和浮游动物在向下输送的过程中经历了食物链传递和细菌的降解。巨型底栖生物的δ15N和δ13C值之间无显著的相关性,此外不同物种之间营养级也存在明显差异,表现为海绵的营养级相对较高（3.4~4.7）,海参（3.3~3.6）、海蛇尾（3.4~3.5）和海星（3.2~3.7）的营养级较为接近,钩虾（2.9~3.3）和海葵（3.1）的营养级则相对略低,反映了底栖生物不同物种之间食物来源的多样化。     

南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.     

印度尼西亚北苏拉威西红树林生态系统碳库研究

近年来的研究指出红树林在海岸带碳固定和碳储存方面发挥着重要的作用。尽管印度尼西亚的红树林面积在全球占很大的比重,对于该地区红树林的有机碳储量和土壤有机碳来源的认识仍有限。本研究调查了印度尼西亚北苏拉威西海洋型的Wori红树林中生态系统有机碳储量及其空间分布特征,以及土壤有机碳的来源,以期加深该地区红树林“蓝碳”功能的认识。研究结果显示,Wori红树林0-50cm深度土壤中有机碳储量为15.4 kg/m²,占生态系统碳储量的主要部分（65%）。红树植物生物量和生态系统碳储量分别为8.3 kg/m²和23.7 kg/m²。土壤有机碳储量在不同离岸距离的采样站位中未表现出显著的空间分布差异,而生物量碳储量则在外滩最高。¹³C稳定同位素分析结果表明红树林土壤中蓄积的有机碳主要来源于红树林有机质,而潮水中的悬浮有机质和红树林外缘的海草并不构成红树林土壤有机碳的重要来源,它们的贡献者都低于20%。研究结果进一步证实了热带地区海洋型红树林湿地在碳储存以及红树植物对碳固定方面的重要性。     

长坑金银矿床的铅,锶,硫同位素特征与矿化模式

长坑矿床金、银矿石的铅同位素组成具有一定的差异，前者的２０６Ｐｂ／２０４Ｐｂ比值变化大，后者较富２０７Ｐｂ／２０８Ｐｂ。金矿石中的铅为普通铅与放射成因铅混合而成的异常铅，银矿石中的铅则可能为三阶段铅混合的产物，且二者均为壳源。方解石的８７Ｓｒ／８６Ｓｒ比值显示锶来自地壳。金、银矿石硫化物的δ３４Ｓ值分别以分散（平均值为负）和较为集中（平均值为正）为特征，并与铅同位素组成之间存在相关关系。结合金、银的矿化分带现象，提出了铅同位素特征与氧化势不同的流体相互混合的成矿模式。     

Distribution of the organic matter in the channel-levees systems of the Congo mud-rich deep-sea fan (West Africa). Implication for deep offshore petroleum source rocks and global carbon cycle

The quantity and the source of organic matter preserved in the Recent turbiditic channel-levees systems around 4000 m-depth off the Congo River were determined using bulk geochemical approaches (Rock-Eval, elemental and isotopic analyses) as well as molecular and optical analyses on selected samples. These mud-rich sediments contain high amount of organic matter (3% Corg on average), the origin of which is a mixture of terrestrial higher-plant debris and deeply oxidized phytoplanktonic material. Although the relative contribution of continental source versus marine source of the organic matter cannot be precisely quantified, the continental fraction appears significant (at least 70–80%) especially for such depths and distances from the coast. The organic matter distribution appears very homogeneous at different scales, from the single turbiditic event to the entire levee, and changes in accumulation rates have a little impact on the quantity and quality of preserved organic matter.     

Authigenic carbonates from the eastern Black Sea as an archive for shallow gas hydrate dynamics – Results from the combination of CT imaging with mineralogical and stable isotope analyses

Authigenic carbonates associated with cold seeps provide valuable archives of changes in the long-term seepage activity. To investigate the role of shallow-buried hydrates on the seepage strength and fluid composition we analysed methane-derived carbonate precipitates from a high-flux hydrocarbon seepage area (“Batumi seep area”) located on the south-eastern Black Sea slope in ca. 850 m. In a novel approach, we combined computerized X-ray tomography (CT) with mineralogical and isotope geochemical methods to get additional insights into the three-dimensional internal structure of the carbonate build-ups.