多巴胺在聚3，4-吡啶二羧酸修饰电极上的电化学行为及其测定

制备了聚3,4-吡啶二羧酸修饰电极,研究了多巴胺在修饰电极上的电化学行为。结果表明聚3,4-吡啶二羧酸聚合物膜对多巴胺的氧化具有明显的催化作用,并且可以消除抗坏血酸对多巴胺测定中的干扰。多巴胺的浓度在2.0×10-6～4.0×10-5mol/L内与其氧化电流呈线性关系,相对标准偏差为3.2%(n=10),检出限为8.0×10-8mol/L。将该修饰电极用于分析模拟样品和注射液样品中的多巴胺,分析结果表明,该修饰电极有望用于实际样品分析。     

微生物降解有机物的碳氢同位素分馏研究进展

微生物降解使有机化合物的稳定碳、氢同位素发生不同程度分馏的研究在有机污染物来源和微生物环境修复等领域取得了长足进展,并对原油和天然气微生物降解研究有借鉴意义。微生物作用下的同位素分馏为动力同位素分馏,导致重同位素在残余物中富集。影响微生物降解有机物同位素分馏的主要因素有微生物的降解代谢途径、辅酶作用、降解类型与程度、同位素质量差异和有机物碳数等。不同的微生物代谢途径代表不同的生物化学反应,造成了同位素分馏的显著差异;辅酶对反应的催化作用使微生物作用造成的同位素分馏更加复杂。低碳数正构烷烃遭受微生物降解程度越高,碳、氢同位素的分馏也越大,同位素变重与降解程度之间有明显的相关性。但对于复杂化合物,由于降解的多级反应,同位素分馏与降解程度间的相关性并不明显。在同样降解程度下,氢同位素分馏大于碳同位素分馏,低碳数正构烷烃的同位素分馏大于高碳数正构烷烃的同位素分馏。     

The experimental study of acoustic emission during creep of rocks

Under normal temperature, the creep experiments with complete samples of Gabbro and Marble rocks are made under uniaxial compression. It is found that at the instantaneous creeping stage, AE activities increase with loading; at the steady creeping stage, large AE signals may appear at lower background of AE action, andm—value which shows the relationship between AE amplitude and frequency keeps stable on the low value or decreases; at the accelerate creeping stage, AE activities increase andm—value decreases quickly or decreases again after recovery. These experimental results are related to the quality of the samples. In this paper, AE activities during three stages of creeping process are connected with the seismic patterns (for exampleb—value, foreshocks). Finally, it is pointed out the possibility that the foreshock—mainshock—aftershock earthquake sequence has been formed by the mechanism of creep fracture of crustal rocks. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,13, 104–112, 1991. This subject is sponsored by the Chinese Joint Seismological Science Foundation.     

油气化探中甲烷碳同位素应用、存在问题与对策研究

阐述了在地表油气化探实践当中甲烷碳同位素对地表土壤烃气成因判别的有效性，但有时也会遇到判断错误的情况。通过对应用实例的分析，指出因忽略了土壤中异常甲烷是一种混合成因甲烷，从而导致判断失误。为全面解决这一问题，提出了同时选送数量相当的背景土壤样品和异常样品进行甲烷同位素测定，然后通过教学方法计算出真实反映来源于油气藏中的甲烷的碳同位素值的对策方案。     

祁连山疏勒河源区冻土退化对土壤微生物生物量碳氮的影响

对青藏高原东北缘祁连山西段疏勒河源区多年冻土区0~50 cm土壤微生物生物量碳氮分布特征及其影响因素进行分析。结果表明:稳定型和极不稳定型多年冻土区0~50 cm土壤中微生物量碳含量范围分别为0.015~0.620 g/kg和0.019~0.411 g/kg,微生物量氮含量范围分别为0.644~12.770 mg/kg和0.207~3.725 mg/kg;土壤微生物量总体呈现出稳定型显著高于极不稳定型多年冻土,表明多年冻土退化（多年冻土由稳定型退化为极不稳定型）对土壤微生物量积累有明显抑制作用。土壤微生物生物量碳占有机碳、微生物生物量氮占全氮的比值在稳定型多年冻土中显著高于极不稳定型,表明多年冻土退化对土壤微生物的矿化能力有明显抑制作用。土壤微生物量及其与土壤养分的比值有显著的剖面变化特征,随土壤深度增加而减小。土壤微生物量碳氮均与土壤温度显著负相关,与地下生物量显著正相关。稳定型多年冻土中,土壤微生物量碳氮与碳氮比正相关、与氧化还原电位负相关;不稳定型多年冻土中,土壤微生物量碳氮与pH正相关。土壤微生物量碳氮与土壤温度和pH在剖面变化上显著相关。逐步回归分析表明驱动微生物生物量碳氮在不同多年冻土类型和土层之间变化的因子是不同的。     

A data collection and analysis system for research on rock fracturing

We have made a data collection and analysis system for recording microcracks in rock to study the three dimensional pattern of fracture and the dynamic properties of rock during pressurization. This system, with 8 channel data detection, records in real-time, from the initial microcracks to the final vibration waveform excited by the master fracture. The detected data are recorded digitally at the hard disk of an IBM computer (or 286, 386 personal computer) as well as transmitted to disk. The sampling rate for each channel is 10 MHz. Collecting every acoustic emission events in the loaded rock sample with 8 channels by this system, mathematically modelling the AE event travel time, and taking the coordinates of the AE event hypocenter and the three components of P wave velocity as unknown parameters, we set up a set of residual equations for joint inversion, so that the three dimensional localization of AE event hypocenters can be completed under variable velocities, which will lay foundations for the research on rock fracture clearly. The Chinese version of this paper appeared in the Chinese edition ofActa Seismological Sinica,13, 489–495, 1991. The design and development of the system, and the experiments are sponsored by the Chinese Joint Seismological Science Foundation.     

大连温带海域潮间带底栖海藻固碳和储碳潜力模拟研究

底栖海藻是海洋生态系统中重要的初级生产力,开展其固碳和储碳机制研究,有利于提高对我国海域海洋固碳和储碳潜力的认识。本文基于海区条件的模拟,开展了大连海域潮间带优势海藻的日固碳量、日呼吸量和日有机碳释放量的测定,结合海区生物量的调查,阐述了3个海藻床潮间带海藻固碳和储碳的季节变化规律。结果显示:在海藻固碳能力方面,绿藻类的固碳能力最强,褐藻类次之,红藻类最低。大连海域潮间带海藻的固碳量、储碳量和有机碳释放量在12月至5月处于较高水平,6月至11月较低,平均每个海藻床潮间带区域年固碳量和年有机碳释放量分别为1.72×105 g/a和2.1×104 g/a。潮间带海藻月固碳量是储碳量的1.7倍。     

Earth System Model FGOALS-s2: Coupling a dynamic global vegetation and terrestrial carbon model with the physical climate system model

Earth System Models （ESMs） are fundamental tools for understanding climate-carbon feedback. An ESM version of the Flexible Global Ocean-Atmosphere-Land System model （FGOALS） was recently developed within the IPCC AR5 Coupled Model Intercomparison Project Phase 5 （CMIP5） modeling framework, and we describe the development of this model through the coupling of a dynamic global vegetation and terrestrial carbon model with FGOALS-s2. The performance of the coupled model is evaluated as follows. The simulated global total terrestrial gross primary production （GPP） is 124.4 PgC yr-I and net pri- mary production （NPP） is 50.9 PgC yr-1. The entire terrestrial carbon pools contain about 2009.9 PgC, comprising 628.2 PgC and 1381.6 PgC in vegetation and soil pools, respectively. Spatially, in the tropics, the seasonal cycle of NPP and net ecosystem production （NEP） exhibits a dipole mode across the equator due to migration of the monsoon rainbelt, while the seasonal cycle is not so significant in Leaf Area Index （LAI）. In the subtropics, especially in the East Asian monsoon region, the seasonal cycle is obvious due to changes in temperature and precipitation from boreal winter to summer. Vegetation productivity in the northern mid-high latitudes is too low, possibly due to low soil moisture there. On the interannual timescale, the terrestrial ecosystem shows a strong response to ENSO. The model- simulated Nifio3.4 index and total terrestrial NEP are both characterized by a broad spectral peak in the range of 2-7 years. Further analysis indicates their correlation coefficient reaches -0.7 when NEP lags the Nifio3.4 index for about 1-2 months.     

山东半岛蓝色经济区土壤有机碳储量及固碳潜力分析

土壤碳储量研究在碳循环和全球变化中具有重要意义,但以往碳储量计算结果受到数据来源的制约。山东省多目标区域地球化学调查采用双层网格化采样和分析,获取了大密度、高精度土壤有机碳数据,为土壤碳库的准确计算奠定了基础。笔者利用这些数据计算了山东半岛蓝色经济区表层（0～20 cm）、中上层（0～100 cm）及全层（0～160 cm）的土壤有机碳（SOC）密度和储量,并对其空间分布特征及固碳潜力进行了研究。结果显示,经济区内3种土壤层次的碳库组成不同,表层SOC储量占总碳（TC）储量的71.67%,随深度增加所占比例逐渐减小,而无机碳(SIC)储量所占比例逐渐增加,全层二者所占比率较为接近:表层SOC储量为132.64 Mt,碳密度为2.06 kg/m²;中上层为458.27 Mt,碳密度为7.11 kg/m²;全层为619.96 Mt,碳密度为9.61 kg/m²。各层SOC密度处于全国偏低水平,且在不同土壤类型、地貌类型、土地利用类型之间有一定差异:褐土土表层SOC密度最高（2.48 kg/m²）,风沙土最低（0.91 kg/m²）;灌溉水田表层SOC密度最高（3.45 kg/m²）,菜地最低（1.61 kg/m²）。表层SOC密度分布总体上呈现为沿海地区低、鲁北平原和胶莱盆地中等、山地丘陵和中低山区偏高的分布格局。从第二次土壤普查和本次多目标调查数据所建立的回归方程分析发现,在今后一定时期内,本区表层土壤总体表现为“碳汇”效应,未来可净增总有机碳（TOC）量60.94 Mt,其中“碳源”量5.07 Mt,“碳汇”量65.97 Mt。     

Methane emission from coal and associated strata samples

Summary This article discusses methods for providing a reliable forecast of the gas-dynamic behaviour of coal seams and adjacent strata. It shows that the ash content of carbonaceous materials determines their sorptive capacity (a universally applicable expression is presented for calculating the methane content of a sample) whilst the rate of methane desorption is a function of the degree of geological disturbance, i.e. the number and distribution of the macropores and fractures in the sample. This effect becomes less important as the sample ash content increases and effectively disappears above a certain value for high permeability materials.The quantity sorption-kinetic characteristic is shown to be a reliable means for quantifying methane emission behaviour. Large variations in coal sorption-kinetic characteristics are shown to occur over short distances as the geological structure of the seam changes, both vertically and horizontally. Consequently, sorption-kinetic characteristics may be used to predict the general level of methane emission from the seam and to quantify the risk of outburst inherent in disturbed areas of coal seams.