CO_2 Density-Raman Shift Relation Derived from Synthetic Inclusions in Fused Silica Capillaries and Its Application

Abstract: The densities of CO2 inclusions in minerals are commonly used to determine the crystallizing conditions of the host minerals. However, conventional microthermometry is difficult to apply for inclusions of small size (< 5–10 μm) or low density. Raman analysis is an alternative method for determining CO2 density, provided that the CO2 density–Raman shift relation is known. This study aims to establish this CO2 density–Raman shift relation by using CO2 inclusions synthesized in fused silica capillaries. By using this newly-developed synthetic technique, we formed pure CO2 inclusions, and their densities were determined by microthermometry. The Raman analysis showed that the relation between CO2 density (D in g/cm3) and the separations (Δ in cm?1) between the two main bands (i.e. Fermi diad bands) in CO2 Raman spectra can be represented by a cubic equation: D (g/cm3)=0.74203(?0.019Δ3+5.90332Δ2?610.79472Δ+21050.30165)?3.54278 (r2=0.99920). Our calculated D value for a given Δ is between those obtained from two previously-reported equations, which were derived from different experimental methods. An example was given in this study to demonstrate that the densities of natural CO2 inclusions that could not be derived from microthermometry could be determined by using our method.     

腾格里沙漠沙丘固定后土壤的斥水性特征研究

土壤斥水性是重要的土壤物理属性,对土壤水文过程和地貌过程有重要的影响。利用毛细上升法研究了腾格里沙漠东南缘沙丘固定后土壤的斥水性特征,分析了不同小地形、不同土壤深度和不同土壤粒径土壤的斥水性差异。结果表明,固沙植被建立后显著地改变了沙丘的土壤斥水性,且随沙丘固定时间增加而呈增强的趋势。丘间地和迎风坡的土壤斥水性大于丘顶和背风坡的斥水性。0~3 cm土层的土壤斥水性显著大于3~6 cm。随着粒径的不断增大,土壤斥水性呈减小趋势,不同粒径段土壤斥水性差异显著;且土壤斥水性与粒径分别为0~0.05 mm、0.05~0.01 mm、0.01~0.15 mm的土壤呈极显著正相关线性关系,与粒径大于0.15 mm的土壤呈显著负相关线性关系。植被区土壤斥水性的增加可能与大气降尘在固定沙丘表面不断沉积、生物土壤结皮形成,尤其是藻类和地衣的形成有关,斥水性的增强将影响到植物种在沙丘上的有效水分利用。     

Comprehensive tests on rising height of capillary water for coarse grained soil

According to the comprehensive tests on the rising height of capillary water for seven kinds of different coarse grained soil by use of the method of standpipe,the relationship between the rising height of capillary water and time was obtained,and the influencing factors and rules were analyzed.The data of the steady rising height of capillary water were obtained,and the regression equation of coarse grained soil on steady height and physical indexes(effective grain d 10 and porosity n) was found.Compared with Hazen’s and other expressions that could estimate the steady height of capillary water of coarse grained soil,the proposed method is satisfactory and the defects of the latter were pointed out.     

锑矿石化学物相分析方法选择性分离条件验证及准确度评估

目前我国矿石化学物相分析方法,除少数方法具有较广泛的适应性外,多数方法均是针对某一具体矿区的样品而制定,在实际应用中无法确认分析结果的准确性和选择性分离流程的适应范围。验证化学物相分析方法的选择性分离流程及方法准确度是该领域必须解决的问题。本文以我国具有代表性的锑矿类型——单锑硫化矿为研究对象,通过岩矿鉴定确定锑的主要矿物相,从试验样品中挑选验证选择分离条件所需的单矿物,在无法获得锑华单矿物的情况下,通过价态分析确定了锑华与锑酸盐混合物中锑华的比例,并通过系列单矿物选择分离对比条件试验和X射线衍射分析,确定了锑华、辉锑矿和锑酸盐等锑物相的选择性分离条件。结果表明:对于硫化锑含量大于35%的样品,锑硫化相的选择浸出时间从传统的30 min调整为40 min,硫化锑的浸出率提高了4%~6%,硫化锑相对于锑酸盐的串相率降低了45%~70%,硫化锑相浸出完全,提高了硫化锑和黄锑矿相分析的准确度。该方法适用于不同地区、不同类型(氧化矿、硫化矿)锑矿石样品的锑化学物相分析。     

孔隙介质毛细滞回简化模型研究

土-水特征曲线的研究是非饱和孔隙介质研究的重要部分。完整的土-水特征曲线包括初始脱湿曲线（IDC）、主吸湿线(MWC)和主脱湿线(MDC)3部分。传统的土-水特征曲线实验需要花费较长的时间和精力。以文献中的试验数据为依据,对非饱和土土-水特征关系和岩石的汞注入抽出试验的滞回现象进行了深入研究,提出一个经验模型来模拟MDC曲线。如果已根据试验得到了孔隙介质的IDC和MWC,此模型只需要一个参数,即可得到增量形式的MDC。通过与试验结果相比较,验证了模型对MDC模拟的有效性。     

粗颗粒间液桥毛细力演化规律的动态计算方法

水力特性是非饱和土力学理论与工程的重要课题之一,土样水力特性的变化过程本质上可反映为土颗粒间毛细力的演化规律。为此,以粗颗粒为研究对象,将其简化为一对不等径球体颗粒,而其间的水分形态可视为形如圆环的液桥,不考虑颗粒重力和浮力的影响。以Young-Laplace方程为基础,先推得计算液桥毛细力的控制方程组,再结合液桥的无量纲体积最大、最小值及其外曲率半径的割线迭代算法提出求解毛细力的动态计算方法,进而研究毛细力与颗粒间距、颗粒半径比和液桥体积的无量纲关系,结果表明：当颗粒间距一定时,液桥的毛细力随其体积和颗粒半径比增大均呈递增趋势;当液桥体积一定时,其抗拉刚度随颗粒间距增大呈递减趋势。最后,利用已有文献中液桥毛细力与颗粒间距的实测关系,验证了该动态计算方法在表征液桥从形成至断裂时毛细力演化规律的有效性。     

新疆库米什盆地硝酸盐类矿床成矿离子迁移规律及成矿模型

为了深入认识库米什盆地硝酸盐矿床成矿离子的空间分布特征、表层沉积物中硝酸盐含量较高的原因,以盆地硝酸盐矿床为研究对象,开展研究区内各类补给水样和沉积物样可溶性盐类物质化学组成的定量分析研究;结合野外地质踏勘工作,探讨研究区硝酸盐矿床成矿离子的迁移规律,初步建立盆地硝酸盐矿床沉积成矿作用模型.结果表明,K+、Na+、NO...     

储层岩石流动电位的电化学影响因素

利用储层岩石的流动电位特性描述油藏的流动特性已引起地球物理领域的关注。依据多孔介质中的双电层模型与毛管电化学理论,建立了渗流场、离子流场和电流场的耦合关系,数值模拟了泥质砂岩储渗特性和电化学因素对流动电位耦合系数的影响。结果表明:当考虑储层岩石中存在浓差极化效应时,流动电位耦合系数的绝对值随溶液浓度、阳离子交换量、孔隙度和渗透率的增大而增大;浓差极化效应对流动电位具有放大作用。     

Nonequilibrium effects in models of three-phase flow in porous media

In this paper we extend to three-phase flow the nonequilibrium formalism proposed by Barenblatt and co-workers for two-phase porous media flow. The underlying idea is to include nonequilibrium effects by introducing a pair of effective water and gas saturations, which are linked to the actual saturations by a local evolution equation. We illustrate and analyze how nonequilibrium effects lead to qualitative and quantitative differences in the solution of the three-phase flow equations.