东山湾表层沉积物5种重金属元素含量分布及其与主要环境因子的关系

根据2011年8月福建东山湾12个站位表层沉积物中5种重金属含量调查,探讨了它们的分布趋势、相互关系、影响因素,并运用潜在生态风险指数法对重金属污染进行风险评价.结果表明,该海域表层沉积物中重金属Cu含量变化范围在5.53～22.40 mg/kg之间,平均值为15.10 mg/kg;Pb含量变化范围在28.9～42.6 mg/kg之间,平均值为35.0 mg/kg;Zn含量变化范围在34.8～133.9 mg/kg之间,平均值为95.9 mg/kg;Cd含量变化范围在0.031～0.078 mg/kg之间,平均值为0.059 mg/kg;Cr含量变化范围在19.2～91.8 mg/kg之间,平均值为62.5 mg/kg.重金属含量的分布呈现湾顶（3、11号站）高、湾外（7号站）低的格局;沉积物中有机质对重金属含量的分布起着重要作用;重金属Cu、Zn和Cr的含量随着沉积物粗颗粒组分（63～2 000μm）含量的增大而降低,成负相关关系（p〈0.05）;Cr的含量随着粘土组分（〈1μm）含量的增大而增大,成正相关关系（p〈0.05）.除了湾顶3号站Cr（含量为91.8 mg/kg）以外,其他重金属元素含量均符合《海洋沉积物质量》一类标准;各元素潜在生态危害系数Ei r大小顺序为Cd〉Pb〉Cu〉Cr〉Zn,所有站位重金属潜在生态危害指数RI均远小于90,属低度生态风险,表明东山湾沉积环境基本良好.     

贡湖水质富营养化综合评价及初步预测

对１９９６年７月贡湖三次调查资料进行的水质和富营养化现状综合评价显示：贡湖水质以Ⅲ－Ⅳ类为主，局部已出发Ｖ类，凯氏氮，非离子氨和总磷为主要污染物；营养型以中营养和中富营养类型分布面积较广。     

多种海洋开发类型的综合效益评估

随着海洋开发活动的不断加剧,各海洋开发类型综合效益的评估与分析对维持海洋社会经济与海洋生态环境的可持续发展具有重大意义,不同海洋开发活动带来不同的社会、经济效益,也产生了海洋资源的损耗,影响了海洋环境和海洋生态服务功能。根据江苏省海洋资源开发活动特点,筛选出江苏海岸带资源开发中常见的4种典型的开发利用类型,选取了能够突出反映海洋开发活动综合效益的经济效益指标、社会效益指标、资源损耗指标、环境成本指标构建海洋开发类型综合效益评估体系。基于层次分析法与熵权法组合权重,运用综合效益指数评价模型分别计算了单一指标效益值、准则层效益值、各研究案例效益值、各用海类型效益值并对以上研究数据之间的相互关系进行了深入分析,探求各用海类型综合效益评估值的关键影响因素。通过实证研究发现4种海洋开发类型的综合效益评估值均介于0.4~0.6之间,处于一般的综合效益状态,综合效益从高到底依次排序:临港工业用海类型为0.551 3、海上风电用海类型为0.492 4、排污倾倒用海类型为0.441、围海养殖用海类型为0.434 3。海洋开发类型综合效益的评估对及时调整海洋开发对策,缓和海洋开发与海洋生态环境的矛盾具有积极意义。     

滨海湿地生态经济的综合评价模型

通过对生态环境指标与社会经济指标两方面的分析,建立了滨海湿地生态经济的综合评价模型,定量计算了滨海湿地开发前总效益(V)、开发后总效益(V′)以及开发利用的限制因子(H)和评价因子(I),并以浙江省上虞市世纪丘围垦工程为例,对模型进行了验证计算,结果表明:(1)开发前后的大气调节、水文调节、污染物净化、提供生物栖息地等生态环境效益指标(Vee)和旅游休闲、科研教育、提供各种产品等经济效益指标(Vse)影响着对滨海湿地开发前后总效益以及开发可行性的判断;(2)当滨海湿地的开发评价因子I>1时〔I=V′/V=(Vee+′Vse)′/(Vee+Vse)〕,海涂开发后的总效益大于开发前的总效益,海涂开发具有可行性,否则为不宜开发;(3)当滨海湿地开发利用的限制因子H小于0.20时,应限制滨海湿地的开发、利用;(4)上虞市世纪丘海涂湿地的H为0.78,I为2.1,可见该海涂开发后,生态环境效益有所降低,但社会经济效益却大幅度地提高了,说明该海涂的开发是具有可行性的。     

CMIP5气候模式下淡水通量变化

基于全球降水气候态计划(GPCP)的降水资料和美国伍兹霍尔海洋研究所(WHOI)的客观分析海气通量(OAFlux)的蒸发数据,对CMIP5的13个耦合模式的淡水通量历史模拟结果进行评估。结果表明:模式能够模拟出淡水通量的气候态空间分布,但普遍存在双热带辐合带(ITCZ)现象,热带海域是模式模拟不确定性最大的区域。模式能较好模拟出纬向平均的淡水通量的分布特征,但量值较实测偏小,且由于模式对1月10°S附近淡水通量的模拟过低,导致年平均的赤道和10°S之间的淡水通量模拟存在明显的偏差。季节尺度上,模式对北半球淡水通量的变化特征有很好的模拟能力,但对南半球的模拟能力不足。年际尺度上,模式普遍能够刻画ENSO引起的淡水通量在太平洋中部同西太平洋以及印尼贯通流反相变化的空间分布特征,但是时间特征模拟很差。从各个方面评估模式的历史模拟结果,多模式集合的结果都要优于单个模式的结果。全球变暖背景下,未来淡水通量变化最显著的区域位于热带和亚热带区域。原本蒸发(降水)占主导的海域,蒸发(降水)更强。不同气候情景下,淡水通量变化的空间形态没有显著变化,但RCP8.5气候情景下模拟的淡水通量变化幅度及模式间变化的一致性均强于RCP4.5的结果。     

Theoretical aspects of cap-rock and fault seals for single- and two-phase hydrocarbon columns

Cap-rock seals can be divided genetically into those that fail by capillary leakage (membrane seals) and those whose capillary entry pressures are so high that seal failure preferentially occurs by fracturing and/or wedging open of faults (hydraulic seals). A given membrane seal can trap a larger oil column than gas column at shallow depths, but below a critical depth (interval), gas is more easily sealed than oil. This critical depth increases with lower API gravity, lower oil GOR and overpressured conditions (for the gas phase). These observations arise from a series of modelling studies of membrane sealing and can be conveniently represented using pressure/ depth (P/D) profiles through sealed hydrocarbon columns. P/D diagrams have been applied to the more complex situation of the membrane sealing of a gas cap underlain by an oil rim; at seal capacity, such a two-phase column will be always greater than if only oil or gas occurs below the seal.These conclusions contrast with those for hydraulic seals where the seal capacity to oil always exceeds that for gas. Moreover, a trapped two-phase column, at hydraulic seal capacity will be less than the maximum-allowed oil-only column, but more than the maximum gas-only column. Unlike membrane seals, hydraulic seal capacity should be directly related to cap-rock thickness, in addition to the magnitude of the minimum effective stress in the sealing layer and the degree of overpressure development in the sequence as a whole.Fault-related seals are effectively analogous to membrane cap-rocks which have been tilted to the angle of the fault plane. Consequently, all of the above conclusions derived for membrane cap-rocks apply to both sealing faults sensu stricto (fault plane itself seals) and juxtaposition faults (hydrocarbon trapped laterally against a juxtaposed sealing unit). The maximum-allowed two-phase column trapped by a sealing fault is greater than for equivalent oil-only and gas-only columns, but less than that predicted for a horizontal membrane cap-rock under similar conditions. Where a two-phase column is present on both sides of a sealing fault (which is at two-phase seal capacity), a deeper oil/water contact (OWC) in one fault block is associated with a deeper gas/oil contact (GOC) compared with the adjacent fault block. If the fault seal is discontinuous in the gas leg, however, the deeper OWC is accompanied by a shallower GOC, whereas a break in the fault seal in the oil leg results in a common OWC in both fault blocks, even though separate GOC's exist. Schematic P/D profiles are provided for each of the above situations from which a series of fundamental equations governing single- and two-phase cap-rock and fault seal capacities can be derived. These relationships may have significant implications for exploration prospect appraisal exercises where more meaningful estimates of differential seal capacities can be made.The membrane sealing theory developed herein assumes that all reservoirs and seals are water-wet and no hydrodynamic flow exists. The conclusions on membrane seal capacity place constraints on the migration efficiency of gas along low-permeabiligy paths at depth where fracturing, wedging open of faults and/or diffusion process may be more important. Contrary to previous assertions, it is speculated that leakage of hydrocarbons through membrane seals occurs in distinct pulses such that the seal is at or near the theoretically calculated seal capacity, once this has been initially attained.Finally, the developed seal theory and P/D profile concepts are applied to a series of development geological problems including the effects of differential depletion, and degree of aquifer support, on sealing fault leakage, and the evaluation of barriers to vertical cross-flow using RFT profiles through depleted reservoirs. It is shown that imbibition processes and dynamic effects related to active cross-flow across such barriers often preclude quantitative analysis and solution of these problems for which simulation studies are usually required.     

南麂列岛附近海域潮间带水环境质量现状评价与分析

利用2003年3月和6月对南麂列岛附近海域潮间带环境质量调查结果,采用环境质量单项评价标准指数法,对该海域潮间带水环境质量现状进行了评价与分析,结果表明:(1)该海域潮间带水质的pH值、溶解氧、化学需氧量和石油类物质均符合一类海水水质标准,春季时无机氮和活性磷酸盐超标较严重,绝大部分海域水质达不到一类海水水质标准,夏季时仅个别站位水质的活性磷酸盐未超标;(2)该海域营养盐结构中N/P值很高,活性磷酸盐是非常敏感的生源要素,它在海水中含量的变化可能会影响整个海域的生态系统。     

富钴结壳资源量评估方法

富钴结壳是一种重要的海底矿产资源,对其进行资源量评估有着十分重要的意义。主要探讨了当前富钴结壳资源量评估的几种主要方法,并对其进行了分析比较。     

基于"一带一路"建设的环渤海地区港口优势评价

港口作为海陆运输的节点,是一个城市和国家的重要门户,对推动经济发展和对外贸易有着不可忽视的作用。基于国家提出的"一带一路"建设,评估环渤海港口的发展优势,逐步实现从沿海、沿江开放向内陆延伸具有重要意义。文章选取环渤海港口中的大连、天津、唐山、丹东、营口、锦州、秦皇岛、黄骅、日照、青岛、威海和烟台共12个港口进行发展优势对比。从港口吞吐量、港口规模范围、港口城市及腹地、港口未来发展4个方面构建环渤海港口优势评价体系。并利用熵权-TOPSIS法进行深入的实证分析。结果表明,环渤海港口群港口发展优势水平悬殊,基本可以分为4个档次。基于此,环渤海各港口应合理准确定位,通过错位发展和协同合作等方式谋求共赢。     

一种建立局域无缝海图深度基准面的方法

根据海洋测绘中垂直基准构建的需求,提出了一种基于主成分-逐步回归分析的建立局域无缝海图深度基准面的方法。在此基础上,利用中国某海区多个验潮站深度基准面值及分潮调和常数振幅,建立了该海区局域无缝深度基准面值回归方程。实例计算表明,该方法所建立的局域海区无缝海图深度基准面值能够达到厘米级精度,可为海图深度基准面体系的重新构建提供技术支持。