微波消解-电感耦合等离子体质谱法测定超细粒度岩石和土壤样品中的稀土元素

应用电感耦合等离子体质谱法(ICP-MS)分析岩石和土壤样品中稀土元素的含量,取样量可低至数毫克级,但200目样品粒度要求分析取样100mg才能保证代表性,导致ICP-MS灵敏度高、取样量小的优势难以得到充分发挥。本文研究了研磨方式、研磨时间、物料比对超细粒度土壤和岩石样品制备的影响,结果表明采用乙醇作为分散剂进行湿法球磨,200目粒度的土壤、岩石样品分别研磨10min和15min,土壤样品的物料比采用物料7g、研磨球500个、分散剂45mL,岩石样品的物料比选取物料5g、研磨球500个、分散剂45mL,细化程度最佳。在此条件下制备的超细粒度土壤标准物质GBW07404、GBW07447的粒径分布D_(95)可低至7.51μm、7.05μm,超细粒度岩石标准物质GBW07104、GBW07121的D_(95)可低至8.42μm、8.30μm。在硝酸-氢氟酸-过氧化氢酸溶体系中微波消解处理超细粒度岩石标准物质GBW07104,取样量减少至5mg,总用酸量减少至0.25mL,消解时间降低为25min,稀土元素的测定值与认定值基本一致,相对标准偏差在1.64%～5.21%之间。该方法用于分析其他超细粒度标准物质(GBW07404、GBW07447和GBW07121)中的稀土元素,相对误差为0.17%～6.60%,满足《地质矿产实验室测试质量管理规范》的一级标准。     

A continuum model of layered rock masses with non-associative joint plasticity

Layered rock masses can be modelled either as standard, orthotropic continua if the layer bending can be neglected or as Cosserat continua if the influence of layer bending is essential. This paper presents a finite element smeared joint model based on the Cosserat theory. The layers are assumed to be elastic with equal thickness and equal mechanical properties. All the cosserat parameters are expressed through the elastic properties of layers, layer thickness and joint stiffness. Plastic-slip as well as tensile-opening of layer interface (joint) are accounted for in a manner similar to the conventional non-associative plasticity theory. As an application, the behaviour of an excavation in a layered rock mass is examined. The displacement and stress fields given by smeared joint models based on the Cosserat continuum and the conventional anisotropic continuum approaches are compared with those obtained from the discrete joint model. The conventional anisotropic continuum model is found to break-down completely when the effective shear modulus in the direction parallel to layering is low in comparison to the shear modulus of the intact layer, whereas the Cosserat model is found to be capable of accurately reproducing complex load–deflection patterns irrespective of the differences in shear moduli. © 1998 John Wiley & Sons, Ltd.     

The structure,depositional style and accumulation characteristics of continental margin with diachronous breakup in the northern South China Sea

ABSTRACT

A typical diachronous breakup developed in the South China Sea (SCS); the breakup has been unequivocally identified, and gradually decreases in age from NE to SW. To illustrate the influence of a diachronous breakup on hydrocarbon accumulation, we used seismic profiles from CNOOC, and analysed crustal extension characteristics, sedimentary style and source rock accumulation. The main conclusions are as follows: (1) Because of the diachronous breakup in the SCS, various tectonic units developed in different positions on the northern continental margin with different degrees of extension. The Pearl River Mouth Basin (PRMB) is closer to the central sea basin of the SCS and has been affected by regional tension stress for a longer time. Tectonic units of proximal domain, necking zone, and distal margin types developed, and the crust structure thinned from the land towards the sea. The Qiongdongnan Basin (QB) is closer to the Southwest Sub-basin. There are symmetrical proximal domains on the southern and northern sides of the QB, with a necking zone in the central part. It presents as an abandoned passive continental margin. (2) The PRMB exhibited rifted cells first, followed by canyon type extensional faulting and horizontal axial transportation, and then by a longitudinal shelf-slope sedimentary style. But the QB has only rifted cells and canyon type faulting stages, no longitudinal shelf-slope sedimentary stage. The major source rocks in the northern SCS become younger from east to west, and the sedimentary facies change from lacustrine facies to marine-continental transitional facies. (3) The diachronous breakup process ultimately affecting oil and gas migration and accumulation process. The PRMB is dominated by deep-water shelf break accumulation with deep-water fan reservoir bodies. The QB is dominated by canyon type accumulation with channels.     

准噶尔盆地吉木萨尔凹陷二叠系芦草沟组优质烃源岩特征及其生烃机制研究

准噶尔盆地吉木萨尔凹陷芦草沟组发育凝灰物质,凝灰物质在页岩油形成过程中具有的重要作用,其发育层段也是页岩油分布最好的层段,凝灰物质的分布及与有机质生烃关系的研究对于吉木萨尔页岩油油气成藏规律的认识和深入研究具有重要意义。本文通过对吉木萨尔芦草沟组烃源岩精细评价及沉积环境分析,与烃类活动具有成因关系的成岩矿物解剖,探讨了形成优质页岩油源岩的控制因素和生烃机制。烃源岩定性评价结果表明,泥晶白云岩是吉木萨尔凹陷芦草沟组主要生油岩,烃源岩有机质丰度高,有机质类型以Ⅰ型和Ⅱ_1型为主,生烃潜力较好,R_o值分布在0.6%～1.1%,C_(29)αααS/(S+R)值范围在0.3～0.5,显示烃源岩处于成熟阶段;芦草沟组烃源岩中规则甾烷C_(27)、C_(28)、C_(29)分布为C_(27)C_(28)C_(29),结合微观分析认为其生烃母质以藻类和超微生物为主,Ts/Tm值较低,分布在0.05～0.18,具有高含量的β-胡萝卜烷,反映其母质处于半咸水的弱氧化—弱还原的沉积环境之中,而这一时期火山活动提供的凝灰物质对烃源岩的生烃环境及热演化进程都有重要影响,热演化突然增大的层段与有机质成熟的"甜点段"的分布深度一致。凝灰物质与含超微生物及藻类的泥晶白云岩的混合是导致生烃和早期生烃的重要原因,两者混合的不均一性导致页岩油分布与成熟度的不均匀性。     

山西阳泉地区旅游地质资源遥感调查与成果分析

为查清山西省阳泉地区旅游地质资源分布状况,方便当地政府掌握区内旅游地质资源现状,为地质公园开发、保护与发展规划提供决策依据,山西省自然资源厅(原山西省国土资源厅)于2018年开展了“山西省阳泉地区旅游地质资源调查”项目,基于三维可视化遥感影像,采用目视解译方法,并结合已有地质资料和野外调查数据,获取了阳泉旅游地质资源分布信息。在阳泉中东部圈定了一条呈月牙形的旅游地质资源密集分布带,该分布带西起盂县藏山,向南东过平定玉皇洞,终至平定县娘子关,分布在碳酸盐岩区,集山地地貌景观、岩溶地貌景观和泉域地貌景观于一体,是我国北方地区规模较大、较为典型的碳酸盐岩地貌、岩溶地貌和泉域地貌出露区,在区域上连片分布,具有较高的开发潜力。建议在“藏山旅游区—岩溶地貌景区—娘子关旅游区”范围申请建立北方碳酸盐岩景观多成因类型地质公园。     

Deep gold mineralization features of Jiaojia metallogenic belt,Jiaodong gold Province: Based on the breakthrough of 3000 m exploration drilling

Recently, continuous breakthroughs have been made about deep gold prospecting in the Jiaodong gold province area of China. Approximately 5000 t of cumulative gold resources have been explored in Jiaodong, which has thus become an internationally noteworthy gold ore cluster. The gold exploration depth has been increased to about 2000 m from the previous <1000 m. To further explore the mineralization potential of the Jiaodong area at a depth of about 3000 m, the Shandong Institute of Geological Sciences has drilled an exploratory drillhole named “Deep drillhole ZK01” to a depth of 3266 m. Hence, as reported herein, the mineralization characteristics of the Jiaojia metallogenic belt have been successfully documented. ZK01 is, to date, the deepest borehole with an gold intersect in China, and constitutes a significant advance in deep gold prospecting in China. The findings of this study further indicate that the depth interval of 2000 m to 4000 m below the ground surface in the Wuyi Village area incorporates 912 t of inferred gold resources, while the depth interval of 2000 m to 4000 m below the surface across the Jiaodong area possesses about 4000 t of inferred gold resources. The Jiaojia Fault Belt tends to gently dip downward, having dip angles of about 25° and about 20° at vertical depths of 2000 m and 2850 m, respectively. The deep part of the Jiaojia metallogenic belt differs from the shallow and moderately deep parts about fracturing, alteration, mineralization, and tectonic type. The deep zones can generally be categorized from inside outward as cataclastic granite, granitic cataclasite, weakly beresitized granitic cataclasite, beresitized cataclasite, and gouge. These zones exhibit a gradual transitional relation or occur alternately and repeatedly. The mineralization degree of the pyritized cataclastic granite-type ore in the deep part of the Jiaojia metallogenic belt is closely related to the degree of pyrite vein development; that is, the higher the pyrite content, the wider the veins and the higher the gold grade. Compared to the shallow gold ores, the deep-seated gold ores have higher fineness and contain joseite, tetradymite, and native bismuth, suggesting that the deep gold mineralization temperature is higher and that mantle-sourced material may have contributed to this mineralization. ZK01 has also revealed that the deep-seated ore bodies in the Jiaojia metallogenic belt are principally situated above the main fracture plane (gouge) and hosted within the Linglong Granite, contradicting previous findings indicating that the moderately shallow gold ore bodies are usually hosted in the contact zone between the Linglong Granite and Jiaodong Group or meta-gabbro. These new discoveries are particularly significant because they can help correct mineralization prospecting models, determine favorable positions for deep prospecting, and improve metallogenic prediction and resource potential evaluation.     

鲁西峄山花岗岩中粗大钾长石斑晶成因探讨

在鲁西地区新太古代晚期(五台期)峄山花岗岩的黑石查和望子山花岗质岩体的岩石中,钾长石粗大斑晶内有自形程度较高的斜长石等矿物包裹体沿其环带定向排列.根据野外观察及岩石、矿物学特征测试分析,钾长石斑晶属于岩浆结晶形成的原生斑晶,受化学成分及侵位结晶过程中的物理化学条件影响,钾长石的生长速度大于其成核密度,因而形成粗大斑晶.估算岩浆温度＞950℃,钾长石斑晶快速生长时岩浆温度为750℃,过冷度△T≈150℃,基质结晶时岩浆温度为600℃,△T≈300℃.     

元谋地区超基性岩浆型铂钯矿成矿作用探讨

川滇新裂谷作用伴有强烈的岩浆活动,除大量玄武质岩浆喷溢外,在元谋朱布、黑泥坡等地见超基性岩体侵入,赋存有铂钯矿床.文章通过分析黑泥坡、朱布超基性岩体的土壤地球化学特征和岩石地球化学特征,结合元谋地区地质特征,提出了元谋地区超基性岩体铂钯矿床的成矿模式.