镉标准溶液配制结果的不确定度评定

选择氧化镉标准物质,配制成质量浓度为1000μg/mL的镉标准溶液,利用等离子体质谱法对标准溶液进行了定值与稳定性检验。通过对镉标准溶液配制过程不确定因素的描述,以95%概率下的扩展因子2获得标准溶液浓度配制标示值的扩展不确定度。实验数据表明,所配制的标准溶液稳定性可达2年。     

FeSO4对铬污染土的稳定特性及风险评价试验研究

采用硫酸亚铁（FeSO4）对铬污染土进行稳定化处理。选用浸出试验、Cr(VI)残留值试验和形态提取试验,研究了粒径和有机质对铬污染土稳定特性的影响规律。试验结果表明,粒径和有机质对铬污染土稳定特性有较大影响。粒径的减小可显著降低稳定土中Cr(VI)和总Cr的浸出浓度及稳定土中Cr(VI)的含量;当污染土粒径小于2 mm时,Fe(II)/Cr(VI)摩尔比为3,稳定土中Cr(VI)和总Cr的浸出浓度分别为4.68、8.9 mg/L,均低于我国《危险废弃物鉴别标准 浸出毒性鉴别》（GB/T5085.3－2007）的限值。有机质添加量的增加可明显降低稳定土中Cr(VI)和总Cr的浸出浓度及Cr(VI)的含量。当Fe(II)/Cr(VI)摩尔比为3时,有机质的添加量为5%,稳定土中Cr(VI)的含量为28.3 mg/kg,低于我国《土壤环境质量标准》（GB15618－2008）中工业和商业用地限值（30 mg/kg）;当有机质的添加量为10%时,稳定土中Cr(VI)的含量为4.8 mg/kg,低于居住用地限值（5 mg/kg）。形态提取试验结果表明：粒径的减小可降低弱酸提取态的铬含量,增加可还原态的铬含量,而对可氧化态和残渣态的铬含量影响不大;有机质可促使弱酸提取态、可还原态的铬转化为可氧化态的铬,而残渣态的铬变化不大。稳定土中铬从活性态向较稳定态转化,是铬稳定土稳定特性和环境风险变化的根本原因。     

电容去离子化去除地下水中镉的影响因素

以高比表面积活性炭作为吸附剂制备电容电极,研究电容去离子化（CDI）对地下水中镉的吸附性能。分别探讨了镉初始质量浓度、体系供电电压、地下水中常见阳离子种类对CDI去除镉的影响。结果表明,CDI吸附镉符合准二级吸附动力学、满足Langmuir等温吸附方程,CDI对镉的吸附为单分子层吸附。吸附量随镉初始质量浓度的升高而增加;在低质量浓度时,较高的供电电压会提高初始阶段的吸附速率,但对电极的最终吸附量无显著影响;地下水中主要阳离子的存在增加了体系的电导率,从而促进了CDI对镉的吸附,提高了镉的吸附速率和去除率。     

湖北恩施地区土壤-植物系统中Se元素的 地球化学特征

在对恩施地区典型农业活动区——芭蕉、长平和鱼塘坝三地土壤中Se元素含量进行调查的基础上,通过与富Se土壤质量标准进行对比,发现除长平地区外,其余两地分别属于富Se和高Se地区,并通过土壤理化性质、形态分析和土壤中所生长的植物进行比较,初步研究了Se在土壤-植物体系中迁移转化的规律。结果表明：整体来看,鱼塘坝地区属于超富Se地区,植物中Se的含量也最高,长平地区属于非富Se地区,芭蕉地区则属于中等富Se地区;植物对Se的吸收受一定的土壤理化性质的影响,不同类型的植物对Se的吸收富集相差较大;形态分析研究表明,鱼塘坝地区土壤中生物可利用的Se含量较高,而芭蕉地区土壤中残渣态Se的比例较高,表现为Se的生物可利用性低于鱼塘坝地区。     

Effects of Environmental Cadmium on Cadmium Accumulation,Oxidative Response,and Microelements Regulation in the Liver and Kidney of Hexagrammos otakii

The effects of cadmium(Cd)on metal accumulation,microelements contents,and antioxidant responses in Hexagram-mos otakii were studied.The fish were exposed to 0.2,2.5,or 10μg L?1 Cd for 12 or 24 days.Then,the concentration of Cd and mi-croelements(Ca,Fe,Zn,and Se)were determined in the liver and kidney.Moreover,the activities of antioxidant enzymes including superoxide dismutase(SOD),catalase(CAT),and glutathione-S-transferase(GST),and the content of malondialdehyde(MDA)in the liver and kidney were also measured.A continuous accumulation of Cd was observed throughout the experimental period.Cd accumulation was higher in liver than that in the kidney,while Ca and Fe contents were lower in liver than those in the kidney.Cd exposure resulted in a decrease of Ca and Fe concentrations in the kidney,while there was no effect on the liver.Zn and Se remained unaffected with exposure to Cd.Cd exposure induced severe oxidative stress in H.otakii,as indicated by significant induction of the activities of SOD,CAT,and GST,and a simultaneous increase of MDA content.These data show that antioxidant enzymes and mi-croelements contents can be used as potential biomarkers to monitor environmental health in fish.     

Relations between free copper and salinity, dissolved and particulate organic carbon in the Oosterschelde and Westerschelde, Netherlands

In a previous investigation, relatively simple relations were found to estimate free Cu, and hence a good approximation of bio-available Cu, at two sites in estuarine waters of the Dutch Oosterschelde and Westerschelde. In the present study, these relations are validated for the remainder of the two sea arms. In the Westerschelde the relation between the concentration of a dissolved organic ligand (K=10¹³), DOC (dissolved organic carbon) and salinity is valid in a range of salinities at least from 10 up to 25 to 30. This ligand group is primarily riverine and partly estuarine. It is, as far as we know, the strongest ligand for Cu, and its concentration dominantly affects the free Cu ion concentrations, which are around 50 fM. At high salinities, dilution and mineralisation diminish the riverine member of the ligand group too much and the relation with salinity and DOC is no longer valid. In the Oosterschelde the relations between POC (particulate organic carbon) and particulate Cu and between POC and the ratio of particulate and dissolved Cu are valid for the western, central and eastern compartments. Since equilibrium was assumed to exist between dissolved and particulate Cu, free Cu can be calculated from POC and particulate Cu concentrations. Due to the large adsorption capacity of POC, the Oosterschelde is with respect to Cu a very well-buffered system with [Cu²⁺] of 20 fM.     

Succession,palaeoecology, evolution,and speciation of Pennsylvanian non‐marine bivalves,Northern Appalachian Basin,USA

Seventeen horizons of non‐marine bivalves are described within the Appalachian succession from the base of the Pottsville Group of Westphalian A‐B age to the Uniontown coal of Stephanian C age at the top of the Carboniferous System. A new highly variable fauna of Anthraconaia from the roof shales of the Upper Freeport coal near Kempton, west Maryland, dates from late Westphalian D or very early Cantabrian time, on the evidence of non‐marine shells and megafloras. Below this horizon, the Appalachian sequence reveals zones of Anthraconauta phillipsii and Anthraconauta tenuis in the same order as in Britain, whereas faunas of Anthraconaia of these zones are less common and differ from those of Britain. In all horizons above the Upper Freeport coal all non‐marine bivalve faunas consist of stages in the sequences of two natural species, the groups of Anthraconaia prolifera and Anthraconaia puella‐saravana. The first shows evidence of having lived in well‐oxygenated, probably shallow, fresh water conditions of relatively wide extent. The second group lived preferentially in a plant‐rich environment of relatively stagnant fresh water. Both groups are found in horizons associated with coal seams and may be seen together in the same habitats, but diagrams of variation (pictographs) suggest that there was no interbreeding between the two groups in either the Northern Appalachians or in southern Germany where the species split was first recognized. In the northern Spanish coalfields of Guardo‐Valderrueda and Central Asturia, facies evidence suggests how an initial split may have taken place in the same morphological directions and into the same palaeoenvironments as the later split into two species. Appalachian deposition was generally slow and intermittent with frequent palaeosols. There is also evidence of erosion and of small palaeontological breaks in the sequence, especially near the eastern edge of the Northern Appalachian Basin in western Maryland. The amount of accumulated sediment was less than one‐tenth of that of western Europe when basin centre deposition is compared. We found no evidence of a major palaeontological break representing Westphalian D strata overlain by Stephanian C strata. We figure non‐marine bivalve faunas of Stephanian B age in association with the Pittsburgh and the Little Pittsburgh coals. Two new species of non‐marine bivalves are described: Anthraconaia anthraconautiformis sp. nov. and Anthraconaia extrema sp. nov. Copyright © 2003 John Wiley & Sons, Ltd.     

美国罗德河流域地下水中铝形成动力学

In the Rhode River estuarine/watershed area, increased acidity of precipitation from atmospheric acidic deposition has deleterious effects on the freshwater ecosystems. One of the characteristics of an acidic watershed is the mobilization of aluminum from soils to aquatic environment. Increased concentrations of aluminum in surface waters are toxic to living organisms. Detection of long-term changes of acidity and elevated Al concentrations in surface and soil waters is a central issue. In this present paper, the dynamics ofAl speciation in the shallow ground waters from Rhode River watershed 110 (la) were investigated. This research provides a unique, regional analysis of important controls on the transport of Al speciation through the rural watershed of the Chesapeake Bay.     

珠江河口及近海水体中铜的水平和形态分布

对夏季(2002-07)和冬季(2003-01)航次中珠江河口及近海水域样品中金属铜的总含量以及总溶解态、颗粒态、游离态铜含量进行对比分析。结果发现,夏季铜的总浓度水平分布并非完全体现陆源性规律,而是随河口向外海递增。而在冬季,总铜浓度的空间变化呈现和夏季完全相反的趋势,即随河口向外海逐渐降低。说明研究水域中金属铜可能具有其他来源,同时在很大程度上受到夏季沿岸上升流的影响。但是,游离态铜的分布在冬季和夏季却呈现相同的趋势,即自河口向外海逐渐降低。说明铜的形态分布在更大程度上取决于水体的理化性质。     

与高岭石固相平衡的酸性天然地表水中铝形态分布的计算机模拟

基于热力学平衡计算,用计算机模拟研究了与高岭石固相平衡的酸性天然地表水中铝的形态分布,讨论了影响铝莆态分布的各种因素,同三水铝石固相平衡相比,与高岭石固相平衡的酸性天然地表水中,铝的形态分布与溶解硅酸的浓度密度相关,聚合态铝浓度较低,总溶解铝浓度明湿减小约２个数量级,模型被用于实际水样的分析,所得结果与实验值符合较好,最后用Ｍｏｎｔｅ Ｃａｒｌｏ模拟考察了由于平衡常数的选择而带来的不确定性。